Oxygen diffusion and consumption in low-sulphide tailings covers
Acid-generating tailings can be reclaimed using oxygen barrier covers in humid climates, such as in Quebec. A single-layer low-sulphide tailings cover is an attractive alternative to traditional water covers to maximize the impoundment’s storage capacity. Low-sulphide tailings can serve as a moisture-retaining material to limit oxygen diffusion, and their residual sulphides can consume the diffusive oxygen that still gets through the cover. A laboratory experiment using instrumented columns was initiated to confirm the efficiency of a low-sulphide tailings monolayer cover placed over acid-generating tailings to reduce the oxygen flux reaching the reactive tailings. Oxygen concentration profiles were measured over the thickness of the cover and oxygen fluxes were calculated to evaluate the effect of three parameters on these fluxes: water table level, cover sulphide content, and cover thickness. Oxygen fluxes at the bottom of the low-sulphide tailings cover layer, calculated using oxygen gradient and estimated effective diffusion coefficient and predicted using Vadose/W, were lower than 1.5 mol·m−2·year−1. These results suggest that a low-sulphide tailings cover with an elevated water table can reduce oxygen migration and potentially limit acid mine drainage generation.