scholarly journals Influence of elastic scattering on the measurement of core-level binding energy dispersion in X-ray photoemission spectroscopy

2011 ◽  
Vol 81 (4) ◽  
pp. 399-403
Author(s):  
E. F. Schwier ◽  
C. Monney ◽  
N. Mariotti ◽  
Z. Vydrovà ◽  
M. García-Fernández ◽  
...  
Keyword(s):  
Elastic Scattering ◽  
Binding Energy ◽  
Core Level ◽  
Photoemission Spectroscopy ◽  
Energy Dispersion ◽  
X Ray ◽  
Core Level Binding Energy

scholarly journals Effect of electron correlation in the decomposition of core level binding energy shifts into initial and final state contributions

2019 ◽  
Vol 21 (18) ◽  
pp. 9399-9406 ◽  
Author(s):  
Marc Figueras ◽  
Carmen Sousa ◽  
Francesc Illas
Keyword(s):  
Binding Energy ◽  
Electron Correlation ◽  
Photoelectron Spectroscopy ◽  
Core Level ◽  
Final State ◽  
X Ray ◽  
Core Level Binding Energy

The influence of electron correlation into the decomposition of core level binding energy shifts, measured by X-ray photoelectron spectroscopy (XPS), into initial and final effects is analysed for a series of molecules where these effects are noticeable.

SUPERSTRUCTURE FORMATION AND X-RAY PHOTOEMISSION PROPERTIES OF THE TlTiOPO4 SURFACE

2004 ◽  
Vol 11 (02) ◽  
pp. 191-198 ◽  
Author(s):  
V. V. ATUCHIN ◽  
L. D. POKROVSKY ◽  
V. G. KESLER ◽  
N. YU. MAKLAKOVA ◽  
V. I. VORONKOVA ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Binding Energy ◽  
Electron Diffraction ◽  
Band Structure ◽  
High Energy ◽  
Photoemission Spectroscopy ◽  
High Energy Electron ◽  
Valence Band Structure ◽  
X Ray ◽  
Core Level Binding Energy

X-ray photoemission spectroscopy (XPS) measurements have been executed for TlTiOPO 4 to elucidate the general features in the electronic structure of the KTiOPO 4 family compounds. The peculiarities of the valence band structure have been discussed for the crystals. The persistence of core level binding energy differences O 1s–P 2p and O 1s–Ti 2p 3/2 has been detected in TlTiOPO 4 and KTiOPO 4, which relates well with the constancy of averaged P – O and Ti – O chemical bond lengths in this crystal family. The superstructure ordering of the TlTiOPO 4 surface subjected to polishing and annealing has been detected by reflectance high energy electron diffraction (RHEED). From comparison of surface crystallographic properties of TlTiOPO 4 and KTiOPO 4, the most typical superstructure indices have been revealed.

X-Ray Photoelectron Spectroscopic Studies of Palladium Dispersed on Carbon Surfaces Modified by Ion Beams and Plasmatic Oxidation

1995 ◽  
Vol 60 (3) ◽  
pp. 383-392 ◽  
Author(s):  
Zdeněk Bastl
Keyword(s):  
Binding Energy ◽  
Photoelectron Spectroscopy ◽  
Surface Coverage ◽  
Spectroscopic Studies ◽  
Core Level ◽  
Graphite Surface ◽  
Photoelectron Spectra ◽  
Surface Layers ◽  
X Ray ◽  
Core Level Binding Energy

The effects of ion bombardment and r.f. plasma oxidation of graphite surfaces on subsequent growth and electronic properties of vacuum deposited palladium clusters have been investigated by methods of X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy with X-ray excitation (XAES). Due to the significantly increased density of surface defects on which the nucleation process occurs the bulk value of the Pd 3d core level binding energy is achieved at higher surface coverage by palladium on bombarded surfaces than on ordered graphite. Angle resolved photoelectron spectra of oxidized graphite surfaces reveal significant embedding of oxygen in graphite surface layers. The C 1s and O 1s photoelectron spectra are consistent with presence of two major oxygen species involving C-O and C=O type linkages which are not homogeneously distributed within the graphite surface layers. Two effects were observed on oxidized surfaces: an increase of palladium dispersion and interaction of the metal clusters with surface oxygen groups. Using the simple interpretation of the modified Auger parameter the relaxation and chemical shift contributions to the measured Pd core level shifts are estimated. In the region of low surface coverage by palladium the effect of palladium-oxygen interaction on Pd core level binding energy exceeds the effects of increased dispersity.

scholarly journals Relating X-Ray Photoelectron Spectroscopy Data to Chemical Bonding in MXenes

2021 ◽  
Author(s):  
Nestor Garcia-Romeral ◽  
Masoomeh Keyhanian ◽  
Angel Morales-Garcia ◽  
Francesc Illas
Keyword(s):  
Binding Energy ◽  
Chemical Bonding ◽  
Photoelectron Spectroscopy ◽  
Core Level ◽  
Spectroscopy Data ◽  
X Ray ◽  
The Relationship ◽  
Core Level Binding Energy

The relationship between core level binding energy shifts (CLBEs), that can be experimentally determined by X-Ray Photoelectron Spectroscopy, and chemical bonding is analyzed for a series of MXenes, a new...

HIGH RESOLUTION CORE LEVEL SPECTROSCOPY AT THE Cu/Ru(0001) INTERFACE

2002 ◽  
Vol 09 (02) ◽  
pp. 723-727 ◽  
Author(s):  
T. H. ANDERSEN ◽  
L. BECH ◽  
J. ONSGAARD ◽  
S. V. HOFFMANN ◽  
Z. LI
Keyword(s):  
High Resolution ◽  
Synchrotron Radiation ◽  
Binding Energy ◽  
Energy Shift ◽  
Core Level ◽  
Photoemission Spectroscopy ◽  
Copper Adsorption ◽  
X Ray ◽  
Level Shifts ◽  
Binding Energy Shift

Copper adsorption on Ru(0001) has been studied by synchrotron radiation. The clean Ru 3d 5/2 spectra were found to consist of two components with a binding energy shift of 400 meV. The component with the lower binding energy represents the first layer of ruthenium atoms. Adsorption of copper gives rise to core level shifts of the Ru 3d 5/2 components, which were studied as a function of Cu coverage. Experiments were carried out with copper coverages varying from the submonolayer range up to two monolayers of copper. The binding energy of the Cu 2p 3/2 level was measured by X-ray photoemission spectroscopy.

Origin of the Ba core-level binding-energy difference between tetragonal and orthorhombicYBa2Cu3O7−δ

1991 ◽  
Vol 43 (4) ◽  
pp. 3695-3698 ◽  
Author(s):  
F. Parmigiani ◽  
G. Pacchioni ◽  
C. R. Brundle ◽  
D. E. Fowler ◽  
P. S. Bagus
Keyword(s):  
Binding Energy ◽  
Energy Difference ◽  
Core Level ◽  
Binding Energy Difference ◽  
Core Level Binding Energy

Core level binding energy shifts for reconstructed GaAs(001) surfaces

Physica B+C ◽  
1983 ◽  
Vol 117-118 ◽  
pp. 822-824 ◽  
Author(s):  
J.F. van der Veen ◽  
L. Smit ◽  
P.K. Larsen ◽  
J.H. Neave
Keyword(s):  
Binding Energy ◽  
Core Level ◽  
Core Level Binding Energy

O 1s Core-Level Positions of Bi2Sr2CaCu2O8-x by OKα-Ray Emission

1989 ◽  
Vol 44 (9) ◽  
pp. 780-784
Author(s):  
F. Burgäzy ◽  
C. Politis ◽  
P. Lamparter ◽  
S. Steeb
Keyword(s):  
Binding Energy ◽  
Energy Level ◽  
Photoelectron Spectrum ◽  
Local Density ◽  
Binding Energies ◽  
Core Level ◽  
X Ray ◽  
Band Structure Calculations ◽  
Density Band ◽  
Structure Calculations

Abstract The measured O Kα X-ray emission spectrum of the high-Tc superconductor Bi2Sr2CaCu2O8-x is compared with a spectrum based on local density band structure calculations. By taking also into account the shape of the measured O 1s X-ray photoelectron spectrum an energy level diagram for the O 1s core-level binding energies of the three different oxygen sites is constructed. The O 1s binding energy in the Bi2O2-layers is found to be about the same as that one in the SrO-layers, whereas the binding energy in the CuO2-layers is lower by about 0.5 eV.

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