Chemistry in Super Acids. I: Hydrogen Exchange and Polycondensation of Methane and Alkanes in FSO3H–SbF5 ("Magic Acid") Solution. Protonation of Alkanes and the Intermediacy of CH5+ and Related Hydrocarbon Ions. The High Chemical Reactivity of "Paraffins" in Ionic Solution Reactions

Author(s):  
George A. Olah ◽  
Richard H. Schlosberg
Author(s):  
Jun-Ichi Saito ◽  
Kuniaki Ara ◽  
Ken-Ichiro Sugiyama ◽  
Hiroshi Kitagawa ◽  
Haruyuki Nakano ◽  
...  

Liquid sodium is used as the coolant of the fast breeder reactor (FBR). A weak point of sodium is a high chemical reactivity with water or oxygen. So an idea of chemical reactivity suppression of liquid sodium itself is proposed. The idea is that nano-meter size particles (hereafter called nano-particles) are dispersed in liquid sodium, and an atomic interaction which is generated between nano-particle and sodium atoms is applied to suppress the chemical reactivity. We call sodium that has dispersed the nano-particle a Nano-fluid. Three key technologies which are the trial manufacture of Nano-fluid, the reaction property of the Nano-fluid and applicability of Nano-fluid to FBR Plant have been carried out to develop the Nano-fluid.


2011 ◽  
Vol 17 (26) ◽  
pp. 7345-7356 ◽  
Author(s):  
Luis Amorim ◽  
Filipa Marcelo ◽  
Cyril Rousseau ◽  
Lidia Nieto ◽  
Jesús Jiménez‐Barbero ◽  
...  

Holzforschung ◽  
1991 ◽  
Vol 45 (6) ◽  
pp. 433-436 ◽  
Author(s):  
Samia A. Helmy ◽  
M. Amine Abou-State

2018 ◽  
Author(s):  
Nicholas D. C. Allen ◽  
David R. Worton ◽  
Paul J. Brewer ◽  
Céline Pascale ◽  
Bernhard Niederhauser

Abstract. Monoterpenes play an important role in atmospheric chemistry due to their large anthropogenic and biogenic emission sources and high chemical reactivity. As a consequence, measurements are required to assess how changes in emissions of monoterpenes impact air quality. Accurate and comparable measurements of monoterpenes in indoor and outdoor environments require gaseous primary reference materials (PRMs) that are traceable to the international system of units (SI). PRMs of monoterpenes are challenging to produce due to the high chemical reactivity and low vapour pressures of monoterpenes and also their propensity to convert into other compounds, including other terpenes. In this paper, the long-term stability of gravimetrically prepared static monoterpene PRMs produced in differently passivated cylinders, including sampling canisters, was assessed. We demonstrate that static PRMs of multiple monoterpenes can be prepared and used as a suitable long-term standard. For the first time the effect of cylinder pressure and decanting from one cylinder to another on the chemical composition and amount fraction of monoterpenes was also studied. Gravimetrically prepared PRMs of limonene in high pressure cylinders were compared to a novel portable dynamic reference gas generator based on dilution of pure limonene vapour emitted from a permeation tube.


2019 ◽  
Vol 9 (18) ◽  
pp. 3861 ◽  
Author(s):  
Augusto Stancampiano ◽  
Tommaso Gallingani ◽  
Matteo Gherardi ◽  
Zdenko Machala ◽  
Paul Maguire ◽  
...  

The interaction of plasmas and liquid aerosols offers special advantages and opens new perspectives for plasma–liquid applications. The paper focuses on the key research challenges and potential of plasma-aerosol interaction at atmospheric pressure in several fields, outlining opportunities and benefits in terms of process tuning and throughputs. After a short overview of the recent achievements in plasma–liquid field, the possible application benefits from aerosol injection in combination with plasma discharge are listed and discussed. Since the nature of the chemicophysical plasma-droplet interactions is still unclear, a multidisciplinary approach is recommended to overcome the current lack of knowledge and to open the plasma communities to scientists from other fields, already active in biphasic systems diagnostic. In this perspective, a better understanding of the high chemical reactivity of gas–liquid reactions will bring new opportunities for plasma assisted in-situ and on-demand reactive species production and material processing.


2018 ◽  
Vol 68 (12) ◽  
pp. 2922-2924
Author(s):  
Gabriela Ignat ◽  
Cintia Colibaba ◽  
Carmen Luiza Costuleanu ◽  
Andreea Alexandra Timofte ◽  
Ion Sandu ◽  
...  

The vine contains, in addition to sugars and acids, important amounts of phenolic compounds that accumulate in the solid parts of grapes (clusters, seeds) and skin. The quantity and quality of phenol compounds depends on both the plant and the technology of grape processing. Their high chemical reactivity makes them participate in chemical processes, especially oxido-reduction and condensation. At the same time, these substances have antioxidant qualities that delay the oxidation of wine components. Phenolic compounds also have interesting biological properties. Recent medical research attributed to phenolic compounds from grapes, juice and wines, especially red ones, remarkable sanogenic qualities, due in particular to their antioxidant action when it comes to polyphenols, cardiovascular protection, antiviral, antihistaminic, anti-cancer, anti-inflammatory, etc.This study analyses the management of various maceration-fermentation processes and their influence on the antioxidant capacity of some wines from Iasi vineyard, but also their correlation with specific phenol compounds. The management of winemaking technologies can produce wines with high antioxidant potential, a plus for an increasingly demanding consumer.


2007 ◽  
Vol 2 (4) ◽  
pp. 403-406
Author(s):  
Yinheng Fan ◽  
Yunling Zou ◽  
Dan Jin ◽  
Qiang Wu ◽  
Tong Liu ◽  
...  

1984 ◽  
Vol 2 (6) ◽  
pp. 439-453 ◽  
Author(s):  
F.T. Lee ◽  
J. Green ◽  
R.D. Gibilisco

FR-D, a new phosphorus-containing diol has, previously, been demonstrated to be an effective combustion modifier in producing pour-in-place rigid urethane foams meeting ASTM E-84 Class I and Class II requirements. Continued developmental efforts led to optimized Class I and Class II foams which contain significantly less amount of combustion modifiers and are thus more cost effective than those reported earlier. FR-D is also suitable for spray foam applications because of its high chemical reactivity and high hydroxy number (#OH = 460). In this paper, recently developed FR-D based Class I and Class II pour as well as spray formulations along with their processing characteristics, E-84 data and foam physicals are discussed.


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