Specific heat and thermal conductivity of nanomaterials

2017 ◽  
Vol 31 (02) ◽  
pp. 1750011 ◽  
Author(s):  
Sandhya Bhatt ◽  
Raghuvesh Kumar ◽  
Munish Kumar

A model is proposed to study the size and shape effects on specific heat and thermal conductivity of nanomaterials. The formulation developed for specific heat is based on the basic concept of cohesive energy and melting temperature. The specific heat of Ag and Au nanoparticles is reported and the effect of size and shape has been studied. We observed that specific heat increases with the reduction of particle size having maximum shape effect for spherical nanoparticle. To provide a more critical test, we extended our model to study the thermal conductivity and used it for the study of Si, diamond, Cu, Ni, Ar, ZrO2, BaTiO3 and SrTiO3 nanomaterials. A significant reduction is found in the thermal conductivity for nanomaterials by decreasing the size. The model predictions are consistent with the available experimental and simulation results. This demonstrates the suitability of the model proposed in this paper.

2013 ◽  
Vol 117 (47) ◽  
pp. 25160-25168 ◽  
Author(s):  
Huziel E. Sauceda ◽  
Fernando Salazar ◽  
Luis A. Pérez ◽  
Ignacio L. Garzón

2005 ◽  
Author(s):  
Zhanrong Zhong ◽  
Xinwei Wang

In this work, thermal transport in nanocrystalline materials is studied using large-scale equilibrium molecular dynamics (MD) simulation. Nanocrystalline materials with different grain sizes are studied to explore how and to what extent the size of nanograins affects the thermal conductivity and specific heat. Substantial thermal conductivity reduction is observed and the reduction is stronger for nanocrystalline materials with smaller grains. On the other hand, the specific heat of nanocrystalline materials shows little change with the grain size. The simulation results are compared with the thermal transport in individual nanograins based on MD simulation. Further discussions are provided to explain the fundamental physics behind the observed thermal phenomena in this work.


2005 ◽  
Vol 20 (3) ◽  
pp. 659-665 ◽  
Author(s):  
Jaeryeong Lee ◽  
Ikkyu Lee ◽  
Dongjin Kim ◽  
Jonggwan Ahn ◽  
Hunsaeng Chung

The particle size and shape effects of starting raw powders on the synthesis of aluminum nitride by combustion reaction technique were investigated with four sizes of AlN powder as diluent and two shapes of Al powder as reactant. It was found that the structure of beds of starting particles significantly affected the pore channels for nitrogen gas accessibility into a mixture compact and the passages for combustion wave propagation through particles, resulting in changes of AlN product morphology and purity. Through control of the starting particle size and shape, high-purity (over 98%) AlN products several tens of microns in size were synthesized.


1964 ◽  
Vol 4 (01) ◽  
pp. 67-72 ◽  
Author(s):  
Louis H. Wolfe ◽  
James O. Thieme

Abstract The tensile and shear strengths of frozen soil and the compressive strengths of ice and frozen soil were measured. These tests showed that the strength of ice and of frozen soil increased as the temperature was decreased. A method is presented for the measurement of thermal conductivity and specific heat of earth and ice. Using the parameters thermal conductivity, specific heat and density, the thermal property tests establish water as the major variable contributing to thermal property values. Introduction During the last few years, a considerable interest has developed in underground storage of cryogenic liquids such as liquid natural gas. Because of its economy and safety, underground storage is being used. Before underground caverns could be seriously considered, however, the strength and thermal characteristics of the soil had to be obtained. Methods are presented herein for measuring tensile, compressive and shear strengths, specific heats and thermal conductivities. The tests were performed on two soils at temperatures from ambient to −195C.Because it is difficult to find data in the literature that pertain to a particular soil, ice was used to evaluate some of the experimental procedures. Some of our ice data are compared to the published values. PHYSICAL PROPERTIES SOIL SELECTION AND SAMPLE PREPARATIONS The physical and thermal tests were performed on recompacted samples of two typical soils that might be encountered in underground caverns: a gray, fire clay that had been pulverized and mixed with water into a pliable mud; and a brown, sandy silt that was dug from a dry river bank and subsequently mixed with tap water. The moisture content of the test specimens was 17 to 22 per cent (based on the wet weight of the soil). This amount of water nearly saturated the silt, but the clay was well below the saturation point. The soils are partially described by the sieve analyses (Fig. 1) which show the particle size distribution of the coarser than 44 micron portion of the soils. The curves also show that approximately 75 per cent of the clay and 20 per cent of the silt are finer than 44 microns. The particle size seems to affect some of the physical properties, and the finer than 44 micron portion is important in the thermal conductivity test. Physical specimens were cut with a bandsaw from frozen blocks of the soil. The specimens were then sanded and kept frozen until after they were tested. They were stored at the approximate test temperature for several hours. Then, to equilibrate the samples to the test temperature, they were stored at the temperature at least an hour before they were tested. TEST EQUIPMENT An Instron, which is a constant speed gear-driven instrument, applied force to the samples and drew stress-strain plots of the test. All of the samples were strained at 0.02 in./min. All of the physical tests were conducted in a temperature cabinet that controlled the temperature to +/- 1C. TENSILE STRENGTH Briquette or "dog-bone" shaped tensile specimens were pulled with suitably shaped jaws. JPT P. 67ˆ


2011 ◽  
Vol 1369 ◽  
Author(s):  
Xianbao Duan ◽  
Zhengzheng Chen ◽  
Neeti Kapur ◽  
Xianghong Hao ◽  
Kyeongjae Cho ◽  
...  

ABSTRACTBimetallic Pd-Au nanoparticles have received much attention due to their potential applications in catalysis. We have developed a Pd-Au alloy potential based on Chen-Mobius lattice inversion method and applied it to the investigation of the melting of Pd-Au binary nanoparticles via molecular dynamics simulations. Our simulation results show the particle size dependence of the melting point and an enrichment of Au atoms to the surface near melting temperature.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2287
Author(s):  
Lubos Kristak ◽  
Ivan Ruziak ◽  
Eugenia Mariana Tudor ◽  
Marius Cătălin Barbu ◽  
Günther Kain ◽  
...  

The effects of using 100% larch bark (Larix decidua Mill) as a raw material for composite boards on the thermophysical properties of this innovative material were investigated in this study. Panels made of larch bark with 4–11 mm and 10–30 mm particle size, with ground bark oriented parallel and perpendicular to the panel’s plane at densities varying from 350 to 700 kg/m3 and bonded with urea-formaldehyde adhesive were analyzed for thermal conductivity, thermal resistivity and specific heat capacity. It was determined that there was a highly significant influence of bulk density on the thermal conductivity of all the panels. With an increase in the particle size, both parallel and perpendicular to the panel´s plane direction, the thermal conductivity also increased. The decrease of thermal diffusivity was a consequence of the increasing particle size, mostly in the parallel orientation of the bark particles due to the different pore structures. The specific heat capacity is not statistically significantly dependent on the density, particle size, glue amount and particle orientation.


Author(s):  
Ola Adel Qasim

Concrete properties are the most essential and critical physical material property when reinforced concrete structures are planned. Because of the development and in types and nature of material used to enhance the concrete innovation, materials and mix proportions, test measure, mixing strategy, and testing condition have noteworthy impacts on highlights of concrete strength, in light of the fact that the control specimen sizes and shapes might be unique in relation from State to State. Testing of mechanical properties (especially compressive strength and tensile strength) of concrete is one of the most urgent stages of development. To control the nature of the concrete, there are different molds used for pouring concrete samples according to different directions in different countries. Many researchers have realized that the specific shapes and sizes of concrete samples can cause different types in the consequences of compressive strength or tensile strength. The relationship between the compressive strength of the concrete cube and the cylinder is complex. The cylinder and concrete cube samples were compared in the pressure test by studying previous research, including the test methodology, factors affecting the cylinder / cube strength ratio, and the coefficients, equations and components of the conversion factors. Previous attempts to determine experimental transformational relationships and conversion factors have proved that it is disturbing (if not impossible) to predict the relationships between the forces of the cylinder and the cube. Previous research has shown that the ratio of the strength of the cylinder / cube is between 0.65 and 0.90, despite the fact that the ratios outside this range have been found similarly. In light of this review of previous research, the test of the cylinder is not initiated by testing the cube. This study is a review of the sample size and shape effect on concrete properties.


Calphad ◽  
2012 ◽  
Vol 36 ◽  
pp. 52-56 ◽  
Author(s):  
Grzegorz Garzel ◽  
Jolanta Janczak-Rusch ◽  
Leszek Zabdyr

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