Characteristics of Pyrolysis and Low Oxygen Combustion of Long Flame Coal and Reburning of Residues

To further understand the problems of coal combustion and coalfield fire reignition, this paper researched the reaction characteristics of coal pyrolysis and low oxygen combustion and the reburning oxidation characteristics of residual structure by thermal analysis methods. The results show that temperature promotes both pyrolysis and low oxygen combustion reactions, but low oxygen combustion reaction is more sensitive to temperature changes. As the constant temperature rises, the mass reduction rate of low oxygen combustion of coal samples reaches 80% on average, which is 4 times that of pyrolysis, and the variations of thermogravimetric parameters are also significantly higher than those of pyrolysis. However, the higher the pyrolysis degree of the residues, the stronger their oxidizability, which greatly enhances the intensity and concentration of the secondary combustion, and the mass of residues is reduced by 90% on average. Conversely, because the combustible components are continuously consumed during low oxygen combustion, the reburning characteristics of residues become less obvious. For instance, the weight loss rate slows down, the burning becomes dispersed, and the burning intensity is weakened. In addition, the heat release is reduced from 8662 to 444.5 J/g, and the change trend is just opposite to that of pyrolysis. The above results show that as the constant temperature rises, the pyrolysis reaction greatly shortens the reburning process, while the low oxygen combustion reaction largely inhibits the reburning.

Rancang Bangun dan Pengujian Penghalang Heliks sebagai Pencampur Udara-Biogas pada Motor Otto

A helical barrier as air-biogas mixing device was designed and tested for direct use of biogas from digester in otto cycle generator set. Homogeneity of the air-fuel mixture can give better combustion reaction and increase engine power. The design was based on simulation, which shows that a 0.039 m length of helical barrier gave a 5% increase in power compared to non-helical barrier. Likewise, the simulations also showed that the helical barrier reduced specific fuel consumption (SFC) by 8%. Accordingly, the mixer with helical barrier was designed, and fabricated. Its performance test confirms the improvement resulted by using helical barriers as air-biogas mixer in the engine. The experiment showed that the power increased by 5% when using helical barrier, while SFC decreased by 4.5%. It is concluded that the helical barrier can increase the homogeneity of the mixture resulting in better engine performance. Besides, emissions produced from the engine using a helical barrier also decreased.

Effect of CaO on catalytic combustion of semi-coke

Generally, adding a certain amount of an additive to pulverized coal can promote its combustion performance. In this paper, the effect of CaO on the combustion characteristics and kinetic behavior of semi-coke was studied by thermogravimetric (TG) analysis. The results show that adding proper amount of CaO can reduce the ignition temperature of semi-coke and increase the combustion rate of semi-coke; with the increase in CaO content, the combustion rate of semi-coke increases first and then decreases, and the results of TG analysis showed that optimal addition amount of CaO is 2 wt%. The apparent activation energy of CaO with different addition amounts of CaO was calculated by Coats–Redfern integration method. The apparent activation energy of semi-coke in the combustion reaction increases first and then decreases with the increase in CaO addition. The apparent activation energies of different samples at different conversion rates were calculated by Flynn–Wall–Ozawa integral method. It was found that the apparent activation energies of semi-coke during combustion reaction decreased with the increase in conversion.