MASS AND LIFETIME MEASUREMENTS AT THE PRESENT ESR FACILITY

2009 ◽  
Vol 18 (02) ◽  
pp. 323-334 ◽  
Author(s):  
YURI A. LITVINOV

Mass and lifetime measurements of stored exotic nuclei is one of the successful experimental programs at the FRS-ESR facility of GSI, Darmstadt. Two experimental techniques, namely Isochronous and time-resolved Schottky mass spectrometry have been developed. Nuclides in a very broad range of half-lives starting from stable down to only a few ten microseconds can be addressed. Single stored ions can be measured which makes these techniques highly efficient. More than 1100 atomic masses have been measured meanwhile. Half-life measurements are performed with bare and few-electron ions. Decay properties of such highly-charged ions can be dramatically different from the ones known in neutral atoms. Single-particle decay spectroscopy has been developed for investigations of two-body beta decays. A brief description of the experimental methods and recent results will be presented. Future experiments at the present facility and the perspectives with the new NuSTAR/ILIMA project at FAIR will be outlined.

2020 ◽  
Author(s):  
Paul Dominic B. Olinares ◽  
Jin Young Kang ◽  
Eliza Llewellyn ◽  
Courtney Chiu ◽  
James Chen ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2545
Author(s):  
Luna Song ◽  
Hehe Bai ◽  
Chenyang Liu ◽  
Wenjun Gong ◽  
Ai Wang ◽  
...  

Two light-activated NO donors [RuCl(qn)(Lbpy)(NO)]X with 8-hydroxyquinoline (qn) and 2,2′-bipyridine derivatives (Lbpy) as co-ligands were synthesized (Lbpy1 = 4,4′-dicarboxyl-2,2′-dipyridine, X = Cl− and Lbpy2 = 4,4′-dimethoxycarbonyl-2,2′-dipyridine, X = NO3−), and characterized using ultraviolet–visible (UV-vis) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, nuclear magnetic resonance (1H NMR), elemental analysis and electrospray ionization mass spectrometry (ESI-MS) spectra. The [RuCl(qn)(Lbpy2)(NO)]NO3 complex was crystallized and exhibited distorted octahedral geometry, in which the Ru–N(O) bond length was 1.752(6) Å and the Ru–N–O angle was 177.6(6)°. Time-resolved FT-IR and electron paramagnetic resonance (EPR) spectra were used to confirm the photoactivated NO release of the complexes. The binding constant (Kb) of two complexes with human serum albumin (HSA) and DNA were quantitatively evaluated using fluorescence spectroscopy, Ru-Lbpy1 (Kb~106 with HSA and ~104 with DNA) had higher affinity than Ru-Lbpy2. The interactions between the complexes and HSA were investigated using matrix assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF-MS) and EPR spectra. HSA can be used as a carrier to facilitate the release of NO from the complexes upon photoirradiation. The confocal imaging of photo-induced NO release in living cells was successfully observed with a fluorescent NO probe. Moreover, the photocleavage of pBR322 DNA for the complexes and the effect of different Lbpy substituted groups in the complexes on their reactivity were analyzed.


1983 ◽  
Vol 55 (8) ◽  
pp. 1310-1313 ◽  
Author(s):  
David N. Heller ◽  
James. Yergey ◽  
Robert J. Cotter

2011 ◽  
Vol 102 (1-2) ◽  
pp. 49-56 ◽  
Author(s):  
Elmar Gelhausen ◽  
Klaus-Peter Hinz ◽  
Andres Schmidt ◽  
Bernhard Spengler

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