Cyclic voltammetry of water-soluble manganese porphyrins in the presence of cyclodextrins
2005 ◽
Vol 09
(05)
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pp. 368-376
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Keyword(s):
The addition of cyclodextrins (α-CD, β-CD, 2-hydroxopropyl-β-CD and γ-CD) to aqueous solutions of representative cationic ( MnTMPyP ) and anionic ( MnTPPS 4) water-soluble Mn porphyrins only substantially affect the behavior of the Mn (III)/ Mn (II) couple when inclusion complexes (i.e. for MnTPPS 4) are formed. The voltammetric responses were interpreted under the assumption that the inclusion complexes are electroactive, which occurs after their adsorption on the electrode surface. In addition, the results point to a higher affinity of the cyclodextrins for Mn II TPPS 4 than for Mn III TPPS 4.
2005 ◽
Vol 09
(06)
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pp. 436-443
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Keyword(s):
1931 ◽
Vol 6
(1)
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pp. 1-11
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Keyword(s):
1999 ◽
Vol 69
(12)
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pp. 956-960
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1994 ◽
Vol 368
(1-2)
◽
pp. 323-327
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2016 ◽
Vol 12
◽
pp. 549-563
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2002 ◽
Vol 106
(42)
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pp. 11064-11068
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