Quantification of Gas-Phase H-Atom Number Density by Tungsten Phosphate Glass

2005 ◽  
Vol 44 (1B) ◽  
pp. 732-735 ◽  
Author(s):  
Takashi Morimoto ◽  
Hironobu Umemoto ◽  
Koji Yoneyama ◽  
Atsushi Masuda ◽  
Hideki Matsumura ◽  
...  
1993 ◽  
Vol 334 ◽  
Author(s):  
Michael E. Coltrin ◽  
William G. Breiland ◽  
Pauline Ho

AbstractSilicon atom number density profiles have been measured using laser-induced fluorescence during the chemical vapor deposition of silicon from silane. Measurements were obtained in a rotating-disk reactor as a function of silane partial pressure and the amount of hydrogen added to the carrier gas. Absolute number densities were obtained using an atomic absorption technique. Results were compared with calculated density profiles from a model of the coupled fluid flow, gas-phase and surface chemistry for an infinite-radius rotating disk. An analysis of the reaction mechanism showed that the unimolecular decomposition of SiH2 is not the dominant source of Si atoms. Profile shapes and positions, and all experimental trends are well matched by the calculations. However, the calculated number density is up to 100 times smaller than measured.


1992 ◽  
Vol 46 (9) ◽  
pp. 1370-1375 ◽  
Author(s):  
King-Dow Su ◽  
King-Chuen Lin ◽  
Wei-Tzou Luh

We have demonstrated that the laser-enhanced ionization (LEI) technique can be used to determine the efficiency of atomization of metal elements in an atmospheric acetylene/air flame. We have derived a useful relation between the time-integrated LEI signal and the total free atom number density in a flame. We determine the efficiency of atomization of ∼0.13–0.37 for the lithium element and of ∼1.0 for the sodium element. Our results agree well with AA measurements reported previously.


2006 ◽  
Vol 110 (9) ◽  
pp. 2868-2875 ◽  
Author(s):  
Dane W. Comerford ◽  
Andrew Cheesman ◽  
Thomas P. F. Carpenter ◽  
David M. E. Davies ◽  
Neil A. Fox ◽  
...  

AIP Advances ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 107220 ◽  
Author(s):  
Guanglong Chen ◽  
A. S. Boldarev ◽  
Xiaotao Geng ◽  
Yi Xu ◽  
Yunjiu Cao ◽  
...  

2012 ◽  
Vol 16 (5) ◽  
pp. 1391-1394 ◽  
Author(s):  
Kun Zhou

A new Monte Carlo method termed Comb-like frame Monte Carlo is developed to simulate the soot dynamics. Detailed stochastic error analysis is provided. Comb-like frame Monte Carlo is coupled with the gas phase solver Chemkin II to simulate soot formation in a 1-D premixed burner stabilized flame. The simulated soot number density, volume fraction, and particle size distribution all agree well with the measurement available in literature. The origin of the bimodal distribution of particle size distribution is revealed with quantitative proof.


2002 ◽  
Vol 2 (2) ◽  
pp. 93-98 ◽  
Author(s):  
S. Fueglistaler ◽  
B.P. Luo ◽  
C. Voigt ◽  
K.S. Carslaw ◽  
Th. Peter

Abstract. Polar stratospheric clouds (PSCs) of type 1a or 1a-enh containing high number densities of nitric acid trihydrate (NAT) particles, can act as mother clouds for extremely large NAT particles, termed NAT-rocks, provided the air below the clouds is supersaturated with respect to NAT. Individual NAT particles at the cloud base fall into undepleted gas phase and rapidly accelerate due to a positive feedback between their growth and sedimentation. The resulting reduction in number density is further enhanced by the strong HNO3 depletion within a thin layer below the mother cloud, which delays subsequent particles. This paper introduces the basic microphysical principles behind this mother cloud/NAT-rock mechanism, which produces 10-4 cm-3 NAT-rocks with radii around 10 mm some kilometers below the mother cloud. The mechanism does not require selective nucleation and works even for a monodisperse particle size distribution in the mother cloud.


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