Fabrication of Titanium Nitride and Molybdenum Nitride for Supercapacitor Electrode Application

2019 ◽  
Vol 35 (32) ◽  
pp. 133-139 ◽  
Author(s):  
Yen-Jui (Bernie) Ting ◽  
Keryn Lian ◽  
Nazir Kherani
Keyword(s):  
Titanium Nitride ◽  
Molybdenum Nitride ◽  
Supercapacitor Electrode

Capacitive Behavior of Sodium Ion Pre-Intercalation Manganese Dioxide Supported on Titanium Nitride Substrate

NANO ◽  
2020 ◽  
Vol 15 (12) ◽  
pp. 2050152 ◽  
Author(s):  
Yibing Xie
Keyword(s):  
Titanium Nitride ◽  
Manganese Dioxide ◽  
Density Functional ◽  
Sodium Ion ◽  
High Rate ◽  
Current Response ◽  
Supercapacitor Electrode ◽  
Capacitive Performance ◽  
Calculation Results ◽  
Ion Size

The sodium ion pre-intercalation manganese dioxide (Na[Formula: see text]MnO[Formula: see text] is supported on titanium nitride (TiN) substrate to form electroactive Na[Formula: see text]MnO2/TiN electrode through an electrodeposition process in Mn(CH3COOH)2/Na2SO4 precursors with high Mn/Na ratio. MnO2 has a tiled leaf-like structure with a wrinkling morphology. Na[Formula: see text]MnO2 has a cross-linking nanorod structure with a nanoporous morphology, which is beneficial for electrolyte ion diffusion. The density functional theory (DFT) calculation results indicate that Na[Formula: see text]MnO2 reveals the enhanced density of states (DOS) and the lowered band gap than MnO2, which is consistent with higher cyclic voltammetry current response due to superior electroactivity of Na[Formula: see text]MnO2. The Faradaic process involves Na[Formula: see text] adsorption/desorption on the surface of MnO2 by contributing to electrochemical capacitance and Na[Formula: see text] intercalation/deintercalation on the deep interlayer of pre-intercalation Na[Formula: see text]MnO2 by contributing to pseudocapacitance. Concerning the electrolyte ion size effect, both MnO2/TiN and Na[Formula: see text]MnO2/TiN electrodes have higher capacitive performance in Li2SO4 electrolyte than that in Na2SO4 and K2SO4 electrolyte due to more feasible Li[Formula: see text] diffusion. When MnO2 is converted into Na[Formula: see text]MnO2, the capacitance at 2.5 mA cm[Formula: see text] increases from 351.3 mF cm[Formula: see text] to 405.6 mF cm[Formula: see text] in Na2SO4 electrolyte and from 376.3 mF cm[Formula: see text] to 465.1 mF cm[Formula: see text] in Li2SO4 electrolyte. The conductive TiN substrate leads to high rate capacity retention ratio of 50.7% for MnO2/TiN and 49.5% for Na[Formula: see text]MnO2/TiN when current density increases from 0.5 mA cm[Formula: see text] to 5 mA cm[Formula: see text]. So, Na[Formula: see text]MnO2/TiN with sodium ion pre-intercalation exhibits the improved capacitive performance in Li2SO4 electrolyte to act well as the promising supercapacitor electrode.

scholarly journals Plasma enhanced atomic layer deposition of titanium nitride-molybdenum nitride solid solutions

2021 ◽  
Vol 39 (1) ◽  
pp. 012407
Author(s):  
Md. Istiaque Chowdhury ◽  
Mark Sowa ◽  
Alexander C. Kozen ◽  
Brandon A. Krick ◽  
Jewel Haik ◽  
...  
Keyword(s):  
Atomic Layer Deposition ◽  
Titanium Nitride ◽  
Solid Solutions ◽  
Atomic Layer ◽  
Molybdenum Nitride ◽  
Layer Deposition

Evolution of the microstructure of Cu(Ti)/SiO2 layers annealed in NH3

1995 ◽  
Vol 53 ◽  
pp. 452-453
Author(s):  
J. Liu ◽  
N. D. Theodore ◽  
D. Adams ◽  
S. Russell ◽  
T. L. Alford ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Titanium Nitride ◽  
Large Scale ◽  
Standard Procedure ◽  
Alloy Film ◽  
Electron Beam Evaporation ◽  
Copper Metallization ◽  
Nominal Composition ◽  
Ti Alloy ◽  
Thermally Grown

Copper-based metallization has recently attracted extensive research because of its potential application in ultra-large-scale integration (ULSI) of semiconductor devices. The feasibility of copper metallization is, however, limited due to its thermal stability issues. In order to utilize copper in metallization systems diffusion barriers such as titanium nitride and other refractory materials, have been employed to enhance the thermal stability of copper. Titanium nitride layers can be formed by annealing Cu(Ti) alloy film evaporated on thermally grown SiO2 substrates in an ammonia ambient. We report here the microstructural evolution of Cu(Ti)/SiO2 layers during annealing in NH3 flowing ambient.The Cu(Ti) films used in this experiment were prepared by electron beam evaporation onto thermally grown SiO2 substrates. The nominal composition of the Cu(Ti) alloy was Cu73Ti27. Thermal treatments were conducted in NH3 flowing ambient for 30 minutes at temperatures ranging from 450°C to 650°C. Cross-section TEM specimens were prepared by the standard procedure.

High-performance Supercapacitor Electrode based on 3D Rose-like β-Ni(OH)2 /rGO nanohybrid

2019 ◽  
Author(s):  
Junli Liu ◽  
Yuhan Wang ◽  
Ruijing Hu ◽  
Hui Liu
Keyword(s):  
High Performance ◽  
Supercapacitor Electrode

GLANCING INCIDENCE X-RAY STUDIES OF TITANIUM NITRIDE THIN FILMS USING A NEW MULTIPURPOSE LABORATORY SPECTROMETER

1989 ◽  
Vol 50 (C7) ◽  
pp. C7-169-C7-173
Author(s):  
R.C BUSCHERT ◽  
P. N. GIBSON ◽  
W. GISSLER ◽  
J. HAUPT ◽  
T. A. CRABB
Keyword(s):  
Thin Films ◽  
Titanium Nitride ◽  
X Ray

Tribotechnical Characteristics of Titanium Nitride Coating for Heavy-Duty Friction Clutches.

1980 ◽  
Vol 41 (5) ◽  
pp. 558-566
Author(s):  
O. Yu Elagina ◽  
◽  
D.O. Kolbas ◽  
A.G. Buklakov ◽  
N. Derr ◽  
...  
Keyword(s):  
Titanium Nitride ◽  
Nitride Coating ◽  
Heavy Duty ◽  
Titanium Nitride Coating ◽  
Tribotechnical Characteristics
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