Light Element Analysis Using Txrf

1995 ◽  
Vol 39 ◽  
pp. 781-790 ◽  
Author(s):  
T. Fukuda ◽  
T. Shoji ◽  
M. Funabashi ◽  
T. Utaka ◽  
T. Arai ◽  
...  
Keyword(s):  
Silicon Wafer ◽  
Heavy Element ◽  
Light Element ◽  
Wafer Surface ◽  
Light Elements ◽  
Element Analysis ◽  
The Past ◽  
Substantial Progress ◽  
Analytical Range ◽  
Sodium Impurity

Over the past few years there has been substantial progress in the TXRF analysis of heavy element surface contamination on silicon wafers. Further advances and improvements are desired in the analytical performance and hardware. Extension of the analytical range to include the light elements is particularly desirable.In the case of light element analysis, sodium and aluminum impurities have been monitored in the IC production process. The increase of the sodium impurity in a silicon wafer gives rise to a decrease in the insulation in IC devices and the growth of the SiO2 film is disturbed by the prsence of aluminum impurity on the silicon wafer surface.

Evaluation of the New Generation of Dual-Anode X-ray Tubes

1984 ◽  
Vol 28 ◽  
pp. 107-112 ◽  
Author(s):  
J. N. Kikkert ◽  
J. J. de Koning
Keyword(s):  
Heavy Element ◽  
Light Element ◽  
Element Analysis ◽  
Side Window ◽  
X Ray ◽  
Excitation Efficiency ◽  
The Past ◽  
Recent Addition ◽  
New Generation ◽  
Dual Target

Traditionally users of x-ray spectrometers have been forced to optimize their instrument for light element analysis and heavy element analysis through the choice of either a light or heavy element anode. The advent of the rhodium tube brought some relief to this situation, but some compromise was still required. The recent addition of the scandium side-window tube to the range has provided twice the excitation efficiency of the chromium tube, whilst providing an equivalent heavy element performance.In the past there have been attempts to produce x-ray tubes combining the properties of both light and heavy element tubes. An example of this is the dual-target tube which has two preferentially excited targets (anodes) of different materials constructed side-by-side.

scholarly journals The light elements in a helio- and asteroseismic perspective

2009 ◽  
Vol 5 (S268) ◽  
pp. 387-394
Author(s):  
Sylvie Vauclair
Keyword(s):  
Main Sequence ◽  
Light Element ◽  
Heavy Elements ◽  
Light Elements ◽  
Main Sequence Stars ◽  
General Introduction ◽  
Helium Content ◽  
Element Abundances ◽  
The Past

AbstractAsteroseismology is a powerful tool to derive stellar parameters, including the helium content and internal helium gradients, and the macroscopic motions which can lead to lithium, beryllium, and boron abundance variations. Precise determinations of these parameters need deep analyses for each individual stars. After a general introduction on helio and asteroseismology, I first discuss the solar case, the results which have been obtained in the past two decades, and the crisis induced by the new determination of the abundances of heavy elements. Then I discuss asteroseismology in relation with light element abundances, especially for the case of main sequence stars.

Effect of X-ray Tube Window Thickness on Detection Limits for Light Elements in XRF Analysis

1994 ◽  
Vol 38 ◽  
pp. 299-305
Author(s):  
Daniel J. Whalen ◽  
D. Clark Turner
Keyword(s):  
Light Element ◽  
Detection Limits ◽  
X Rays ◽  
Light Elements ◽  
Absorption Data ◽  
Element Analysis ◽  
X Ray ◽  
Data Compilation ◽  
Beryllium Window ◽  
X Ray Background

Abstract Widespread interest in light element analysis using XRF has stimulated the development of thin x-ray tube windows. Thinner windows enhance the soft x-ray output of the tube, which more efficiently excite the light elements in the sample. A computer program that calculates the effect of window thickness on light element sample fluorescence has been developed. The code uses an NIST algorithm to calculate the x-ray tube spectrum given various tube parameters such as beryllium window thickness, operating voyage, anode composition, and take-off angle. The interaction of the tube radiation with the sample matrix is modelled to provide the primary and secondary fluorescence from the sample. For x-rays in the energy region 30 - 1000 eV the mass attenuation coefficients were interpolated from the photo absorption data compilation of Henke, et al. The code also calculates the x-ray background due to coherent and incoherent scatter from the sample, as well as the contribution of such scatter to the sample fluorescence. Given the sample fluorescence and background the effect of tube window thickness on detection limits for light elements can be predicted.

Comparison of Experimental and Theoretical Intensities for a New X-Ray Tube for Light Element Analysis

1983 ◽  
Vol 27 ◽  
pp. 423-426 ◽  
Author(s):  
John Kikkert ◽  
Graham Hendry
Keyword(s):  
Atomic Number ◽  
Light Element ◽  
Fluorescence Spectrometry ◽  
Light Elements ◽  
Element Analysis ◽  
X Ray ◽  
Highly Sensitive ◽  
Low Sensitivity

While x-ray fluorescence spectrometry is a highly sensitive and highly repoducible method of analysing samples, its one weakness is its relatively low sensitivity for light elements. This is mainly due to two problems: firstly the low fluorescent yield of the low atomic number elements, and secondly to the inherent inefficiency of exciting these elements. While it is not possible to improve the fluorescent yield, considerable improvements in light element sensitivity can be achieved by improvements in x-ray tubes.

Light Element Analysis with TXRF

1991 ◽  
Vol 35 (B) ◽  
pp. 947-952
Author(s):  
Christina Streli ◽  
Peter Wobrauschek ◽  
Hannes Aiginger
Keyword(s):  
Trace Element Analysis ◽  
Light Element ◽  
Fluorescence Analysis ◽  
Analytical Tool ◽  
Total Reflection ◽  
Light Elements ◽  
Element Analysis ◽  
X Ray ◽  
Background Reduction ◽  
Powerful Analytical Tool

AbstractTotal Reflection X-Ray Fluorescence Analysis (TXRF) has become a powerful analytical tool for trace element analysis. Because of its advantages in excitation and background reduction TXRF has been applied for the analysis of light elements (C,O,F,Na,...). A special Ge(HP) detector offering an ultra thin window in combination with a spectrometer specially designed for the requirements of light element analysis was used. Also a new windowless X-ray tube for efficient excitation of the light elements was tested. The system was checked with standard aqueous solutions; detection limits in the ng range (7 ng for O) are obtained.

Three-Step Room Temperature Wet Cleaning Process for Silicon Substrate

2009 ◽  
Vol 145-146 ◽  
pp. 189-192 ◽  
Author(s):  
Rui Hasebe ◽  
Akinobu Teramoto ◽  
Tomoyuki Suwa ◽  
Rihito Kuroda ◽  
Shigetoshi Sugawa ◽  
...  
Keyword(s):  
High Temperature ◽  
Silicon Wafer ◽  
Chemical Vapor ◽  
Wafer Surface ◽  
The Past ◽  
Silicon Wafer Surface ◽  
Alkali Solutions ◽  
High Temperature Processes ◽  
Clean Air ◽  
Processing Steps

With a progress of device dimension miniaturization, an ultraclean wafer surface is continuously increasing its importance crucial for high quality processing in Silicon Technologies [1]-[8]. Cleaning of silicon wafer surface has been accomplished by RCA wet cleaning in the past [9], where there exists high temperature processes consisting of H2SO4/H2O2/H2O, NH4OH/H2O2/H2O and HCl/H2O2/H2O treatments. Thus, RCA cleaning requires a large number of processing steps, resulting in the consumption of a huge volume of liquid chemicals and UPW, and simultaneously consuming a large volume of clean air exhaust to suppress chemical vapor from getting into the clean room. Moreover, RCA cleaning is used at high temperature and contain alkali solutions, which increase the roughness of the silicon wafer surface [10].

Light Element Analysis with an Electron Microprobe

1964 ◽  
Vol 8 ◽  
pp. 341-351 ◽  
Author(s):  
Poen Sing Ong
Keyword(s):  
Electron Microprobe ◽  
Analytical Data ◽  
Light Element ◽  
Spectrochemical Analysis ◽  
Light Elements ◽  
Instrumental Performance ◽  
Element Analysis ◽  
X Ray ◽  
Lead Stearate

AbstractIn the microprobe, lead stearate decanoate multilayer analyzers have proven to be practical components for X-ray spectrochemical analysis of the light elements. Better controlled techniques in the deposition of the layers have already produced analyzers yielding improved peak to background ratios as well as higher counting rates. Operational techniques, optimizing instrumental performance, will be discussed. Analytical data on the elements fluorine through boron, obtained with a modified commercial microprobe, will be presented.

A Method of Liquid Analyses Providing Increased Sensitivity for Light Elements

1966 ◽  
Vol 10 ◽  
pp. 506-519
Author(s):  
D. W. Beard ◽  
E. M. Proctor
Keyword(s):  
Light Element ◽  
Sample Surface ◽  
X Rays ◽  
Light Elements ◽  
Element Analysis ◽  
X Ray ◽  
Surface Method ◽  
Liquid Cell ◽  
Increased Sensitivity ◽  
Typical Solution

AbstractA method for analyzing solutions using a sample surface directly exposed to the primary X-ray beam is discussed. This method eliminates the need for the conventional Mylar covered liquid cells. The advantages of this method are the elimination of the scattering of the longer wavelength X-rays and the absorption effects due to the Mylar covering, thereby giving significant improvement in peak-to-background ratios and peak intensities for the light elements. This increased sensitivity can be used to improve the limits of detectability for light elements in solutions, broaden the range of practical elemental determinations, and reduce the counting time for any light element analysis in liquids.A new liquid cell, developed for this technique, provides easily repeatable setting of target-to-sample distance and simplified preparation and handling of samples. A comparison between results obtained with conventional method and this uncovered sample surface method is made for typical solution applications.

Low Voltage Biological X-Ray Microanalysis: Progress and a Remaining Problem

2000 ◽  
Vol 6 (S2) ◽  
pp. 758-759
Author(s):  
Patrick Echlin
Keyword(s):  
Low Voltage ◽  
Light Element ◽  
Primary Electron ◽  
X Rays ◽  
Element Analysis ◽  
X Ray ◽  
Analytical Technique ◽  
The Past ◽  
Beam Sample ◽  
Wide Range

Experimental work in a number of research groups over the past five years have demonstrated, unequivocally, that low voltage i.e. 5kV and below, quantitative x-ray microanalysis is a valid analytical technique which can be applied to a wide range of specimens. The advantages of this approach are now generally well known and include improved image contrast, diminished bulk charging of the sample and for bulk specimens, a reduction in the size of the beam-sample interactive volume from which the x-rays are generated, and as a consequence, a considerable improvement in the microanalytical spatial resolution. In addition, low voltages ensure a sensitive surface analysis procedure which provides true topographic contrast and that in the case of light element analysis, quantitation is simplified because the atomic number (Z), absorption (A) and fluorescence (F) effects are minimised. All these advantages are improved further if one uses a field emission gun as the primary electron source.

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