Determination of NH4+in Environmental Water with Interfering Substances Using the Modified Nessler Method
Nitrogen is an essential element in the environment. If excess nitrogen includingNH4 +is present in water, however, it can result in algae blooming and eventually the destruction of the aquatic ecosystem. Therefore, the determination ofNH4 +in streams, lakes, and effluents of the treatment facilities has long been carried out. The Nessler method is the most common spectrophotometric method to measureNH4 +in water. However, the result of the method becomes inaccurate if there are interfering substances such as Cl2, Cl−, hardness-causing compounds (e.g., Mg2+), and Fe2+in target water samples. In this study, therefore, the traditional Nessler method has been modified to eliminate the effects of interfering substances; the so-called MS was added to water samples. In addition, the polyvinyl alcohol reagent as a dispersing agent was added to water samples to increase the sensitivity and reproducibility of the method. The modified method could successfully analyzeNH4 +of water samples even with the interfering substance at high concentration.