scholarly journals A Review and Comparative Study of Existing Shrinkage Prediction Models for Portland and Non-Portland Cementitious Materials

2016 ◽  
Vol 2016 ◽  
pp. 1-13 ◽  
Author(s):  
Hailong Ye ◽  
Aleksandra Radlińska
Keyword(s):  
Experimental Data ◽  
Portland Cement ◽  
Theoretical Basis ◽  
Ordinary Portland Cement ◽  
Prediction Models ◽  
High Water ◽  
Cementitious Materials ◽  
Published Data ◽  
Activated Slag ◽  
Specific Comparison

This paper reviews shrinkage prediction models for cementitious materials and presents analysis of selected published data utilizing the aforementioned models. The main objective of this review is to revisit and reexamine the primary shrinkage mechanisms, that is, capillary pressure theory, Gibbs-Bangham shrinkage, and withdrawal of disjoining pressure in Portland and non-Portland cement. In particular, the theoretical basis for current shrinkage models is elaborated on and its soundness and applicability to explain the published experimental data are discussed. Additionally, a specific comparison was made among high water-to-cement (w/c) ratio ordinary Portland cement (OPC), low w/c OPC, and alkaline activated slag.

scholarly journals A Review of the Mechanical Properties and Durability of Ecological Concretes in a Cold Climate in Comparison to Standard Ordinary Portland Cement-Based Concrete

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3467
Author(s):  
Ankit Kothari ◽  
Karin Habermehl-Cwirzen ◽  
Hans Hedlund ◽  
Andrzej Cwirzen
Keyword(s):  
Carbon Dioxide ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cementitious Materials ◽  
Cold Climate ◽  
Supplementary Cementitious Materials ◽  
Short Exposure ◽  
Chemical Admixtures ◽  
Composite Cements ◽  
Alkali Activated

Most of the currently used concretes are based on ordinary Portland cement (OPC) which results in a high carbon dioxide footprint and thus has a negative environmental impact. Replacing OPCs, partially or fully by ecological binders, i.e., supplementary cementitious materials (SCMs) or alternative binders, aims to decrease the carbon dioxide footprint. Both solutions introduced a number of technological problems, including their performance, when exposed to low, subfreezing temperatures during casting operations and the hardening stage. This review indicates that the present knowledge enables the production of OPC-based concretes at temperatures as low as −10 °C, without the need of any additional measures such as, e.g., heating. Conversely, composite cements containing SCMs or alkali-activated binders (AACs) showed mixed performances, ranging from inferior to superior in comparison with OPC. Most concretes based on composite cements require pre/post heat curing or only a short exposure to sub-zero temperatures. At the same time, certain alkali-activated systems performed very well even at −20 °C without the need for additional curing. Chemical admixtures developed for OPC do not always perform well in other binder systems. This review showed that there is only a limited knowledge on how chemical admixtures work in ecological concretes at low temperatures and how to accelerate the hydration rate of composite cements containing high amounts of SCMs or AACs, when these are cured at subfreezing temperatures.

A Review of Alkali-Activated Slag as Cement Replacement

2019 ◽  
Vol 803 ◽  
pp. 262-266
Author(s):  
Osama Ahmed Mohamed ◽  
Maadoum M. Mustafa
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Construction Industry ◽  
Ordinary Portland Cement ◽  
Environmental Footprint ◽  
Alkali Activated Slag ◽  
Cement Replacement ◽  
Activated Slag ◽  
Alkali Activated

Alkali activated slag (AAS) offers opportunities to the construction industry as an alternative to ordinary Portland cement (OPC). The production of OPC and its use contributes significantly to release of CO2 into the atmosphere while AAS is an industrial by-product that contributes much less to the environmental footprint that needs to be recycled if not landfilled. This paper outlines some of the key properties, merits and demerits of AAS when used as alternative to OPC. Competitive compressive strength of AAS concrete is amongst of the advantages of replacing cement with AAS while high shrinkage and carbonation levels are potential disadvantages.

scholarly journals Effect of Elevated Temperature on Alkali Activated Slag and Fly Ash based Geopolymer Concrete

2020 ◽  
Vol 9 (4) ◽  
pp. 1241-1250
Keyword(s):  
Compressive Strength ◽  
Elevated Temperature ◽  
Fly Ash ◽  
Flexural Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Geopolymer Concrete ◽  
Base Materials ◽  
Activated Slag ◽  
Alkali Activated

Activated Slag (AAS) and Fly Ash (FA) based geopolymer concrete a new blended alkali-activated concrete that has been progressively studied over the past years because of its environmental benefits superior engineering properties. Geopolymer has many favorable characteristics in comparison to Ordinary Portland Cement. Many base materials could be utilized to make geopolymer with the convenient concentration of activator solution. In this study, the experimental program composed of two phases; phase on divided into four groups; Group one deliberated the effect of sodium hydroxide molarity and different curing condition on compressive strength. Group two studied the effect of alkali activated solution (NaOH and Na2SiO3) content on compressive strength and workability. The effect of sand replacement with slag on compressive strength and workability was explained in group three. Group four studied the effect of slag replacement with several base materials Fly Ash (FA), Ordinary Portland Cement (OPC), pulverized Red Brick (PRB), and Meta Kaolin (MK). Phase two contains three mixtures from phase one which had the highest compressive strength. For each mixture, the fresh concrete test was air content. In addition the hardened concrete tests were the compressive strength at 3, 7, 28, 90, 180, and 365 days, the flexural strength at 28, 90, and 365 days, and the young's modulus at 28, 90, and 365 days. Moreover; the three mixtures were exposed to elevated temperature at 100oC, 300oC, and 600oC to study the effect of elevated temperature on compressive and flexural strength.

scholarly journals Alteration of Bentonite Reacted with Cementitious Materials for 5 and 10 Years in the Mont Terri Rock Laboratory (CI Experiment)

Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 251
Author(s):  
Shingo Yokoyama ◽  
Misato Shimbashi ◽  
Daisuke Minato ◽  
Yasutaka Watanabe ◽  
Andreas Jenni ◽  
...  
Keyword(s):  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Current Knowledge ◽  
Cementitious Materials ◽  
Opalinus Clay ◽  
Secondary Products ◽  
Rock Laboratory ◽  
Mineral Compositions ◽  
Mont Terri ◽  
Mont Terri Rock Laboratory

The cement–clay interaction (CI) experiment was carried out at the Mont Terri rock laboratory to complement the current knowledge on the influence that cementitious materials have on Opalinus Clay (OPA) and bentonite (MX). Drill cores including the interface of OPA, concrete (LAC = low-alkali binder, and OPC = ordinary Portland cement), and MX, which interacted for 4.9 and 10 years, were successfully retrieved after drilling, and detailed analyses were performed to evaluate potential mineralogical changes. The saturated compacted bentonites in core samples were divided into ten slices, profiling bentonite in the direction towards the interface, to evaluate the extent and spatial variation of the mineralogical alteration of bentonite. Regarding the mineral compositions of bentonite, cristobalite was dissolved within a range of 10 mm from the interface in both LAC-MX and OPC-MX, while calcite precipitated near the interface for OPC-MX. In LAC-MX and OPC-MX, secondary products containing Mg (e.g., M-S-H) also precipitated within 20 mm of the interface. These alterations of bentonite developed during the first 4.9 years, with very limited progress observed for the subsequent 5 years. Detectable changes in the mineralogical nature of montmorillonite (i.e., the formation of illite or beidellite, increase in layer charge) did not occur during the 10 years of interaction.

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