scholarly journals Analysis of Hydrogeochemical Characteristics of Tunnel Groundwater Based on Multivariate Statistical Technology

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Chen Peng ◽  
Yuanming Liu ◽  
Huiyu Chen ◽  
Qiaowei Yuan ◽  
Qingzhi Chen ◽  
...  
Keyword(s):  
Saturation Index ◽  
Karst Aquifer ◽  
Principal Component ◽  
Geological Structure ◽  
Chemical Components ◽  
Multivariate Statistical ◽  
Tunnel Excavation ◽  
Aquifer System ◽  
Karst Aquifer System ◽  
Natural Water Bodies

Following tunnel excavation, which is influenced by hydraulic fracturing and geological structure, a series of hydrochemical reactions occur in the karst aquifer, which has a significant impact on groundwater hydrology and the earth process. Based on five sets of 38 samples collected in the Tongzi Tunnel in 2020 and 2021, the main geochemical processes and water quality conditions of the karst aquifer system during tunnel construction were revealed by multivariate statistical analysis and graphical methods. The results showed that water-rock action is the main mechanism controlling groundwater chemistry in the study area; HCO3-, Ca2+, and Mg2+ are associated with the widely distributed carbonate rocks in the study area. SO42- is derived from gypsum and sulfate rocks and special strata, which are another important source of Ca2+. Sodium-containing silicates and reverse cation exchange as the causal mechanisms of Na+ whereas F- is derived from fluorite. According to the mineral saturation index calculations, the dissolution and precipitation of minerals such as alum, gypsum, calcite, dolomite, and salt rock have an important influence on the main chemical components in water. The 38 samples were subjected to cluster analysis, and the results could be classified into seven categories. The representative clusters 1, 3, and 5 were selected for principal component analysis. Clusters 1 and 5 of groundwater represent weathering, dissolution, and ion exchange of carbonate and sulfate rocks and are closely related to the lithologic limestone, limestone intercalated with carbonaceous mudstone, carbonaceous mudstone, and coal-measure strata in the aquifer. Cluster 3 is dominated by upper surface river water and characterizes the geochemistry in natural water bodies dominated by the dissolution of carbonate, sulfate, and salt rocks. Finally, groundwater quality is mostly found in Class IV, with NO3- and F- being the main contaminants in the water.

scholarly journals Geological structure, recharge processes and underground drainage of a glacierised karst aquifer system, Tsanfleuron-Sanetsch, Swiss Alps

2009 ◽  
Vol 17 (8) ◽  
pp. 1833-1848 ◽  
Author(s):  
Vivian Gremaud ◽  
Nico Goldscheider ◽  
Ludovic Savoy ◽  
Gérald Favre ◽  
Henri Masson
Keyword(s):  
Karst Aquifer ◽  
Geological Structure ◽  
Swiss Alps ◽  
Aquifer System ◽  
Karst Aquifer System

scholarly journals Characterization of the Volatile Profile of Cultivated and Wild-Type Italian Celery (Apium graveolens L.) Varieties by HS-SPME/GC-MS

2021 ◽  
Vol 11 (13) ◽  
pp. 5855
Author(s):  
Samantha Reale ◽  
Valter Di Cecco ◽  
Francesca Di Donato ◽  
Luciano Di Martino ◽  
Aurelio Manzi ◽  
...  
Keyword(s):  
Solid Phase ◽  
Principal Component ◽  
Apium Graveolens ◽  
Gas Chromatography Mass Spectrometry ◽  
Bioactive Metabolites ◽  
Chemical Components ◽  
Volatile Profile ◽  
Wild Type ◽  
Multivariate Statistical ◽  
Clear Differentiation

Celery (Apium graveolens L.) is a vegetable belonging to the Apiaceae family that is widely used for its distinct flavor and contains a variety of bioactive metabolites with healthy properties. Some celery ecotypes cultivated in specific territories of Italy have recently attracted the attention of consumers and scientists because of their peculiar sensorial and nutritional properties. In this work, the volatile profiles of white celery “Sedano Bianco di Sperlonga” Protected Geographical Indication (PGI) ecotype, black celery “Sedano Nero di Torricella Peligna” and wild-type celery were investigated using head-space solid-phase microextraction combined with gas-chromatography/mass spectrometry (HS-SPME/GC-MS) and compared to that of the common ribbed celery. Exploratory multivariate statistical analyses were conducted using principal component analysis (PCA) on HS-SPME/GC-MS patterns, separately collected from celery leaves and petioles, to assess similarity/dissimilarity in the flavor composition of the investigated varieties. PCA revealed a clear differentiation of wild-type celery from the cultivated varieties. Among the cultivated varieties, black celery “Sedano Nero di Torricella Peligna” exhibited a significantly different composition in volatile profile in both leaves and petioles compared to the white celery and the prevalent commercial variety. The chemical components of aroma, potentially useful for the classification of celery according to the variety/origin, were identified.

scholarly journals Simulation of Regional Karst Aquifer System and Assessment of Groundwater Resources in Manatí-Vega Baja, Puerto Rico

2015 ◽  
Vol 07 (12) ◽  
pp. 909-922 ◽  
Author(s):  
Balati Maihemuti ◽  
Reza Ghasemizadeh ◽  
Xue Yu ◽  
Ingrid Padilla ◽  
Akram N. Alshawabkeh
Keyword(s):  
Puerto Rico ◽  
Groundwater Resources ◽  
Karst Aquifer ◽  
Aquifer System ◽  
Karst Aquifer System ◽  
Vega Baja

scholarly journals Comparison of Multiple Bioactive Constituents in the Flower and the Caulis of Lonicera japonica Based on UFLC-QTRAP-MS/MS Combined with Multivariate Statistical Analysis

Molecules ◽  
2019 ◽  
Vol 24 (10) ◽  
pp. 1936 ◽  
Author(s):  
Zhichen Cai ◽  
Chengcheng Wang ◽  
Lisi Zou ◽  
Xunhong Liu ◽  
Jiali Chen ◽  
...  
Keyword(s):  
Comprehensive Evaluation ◽  
Principal Component ◽  
Quinic Acid ◽  
Lonicera Japonica ◽  
Herbal Remedies ◽  
Chemical Components ◽  
Bioactive Constituents ◽  
Multivariate Statistical ◽  
Intrinsic Quality ◽  
Fast Liquid Chromatography

Lonicerae japonicae flos (LJF) and Lonicerae japonicae caulis (LJC) are derived from different parts of Lonicera japonica Thunb. (Caprifoliaceae), and have been used as herbal remedies to treat various diseases for thousands of years with confirmed curative effects. However, little attention has been paid to illustrating the differences in efficacy from the perspective of phytochemistry. In the present study, a simultaneous determination of 47 bioactive constituents, including 12 organic acids, 12 flavonoids, six iridoids, 13 amino acids and four nucleosides in 44 batches of LJF and LJC samples from different habitats and commercial herbs was established based on ultra-fast liquid chromatography tandem triple quadrupole mass spectrometry (UFLC-QTRAP-MS/MS). Moreover, principal component analysis (PCA), partial least squares discriminant analysis (PLS-DA) and t-test were then performed to classify and reveal the differential compositions of LJF and LJC according to the content of the tested constituents. The results demonstrated that the types and contents of chemical components (e.g., isochlorogenic acid A, chlorogenic acid, neochlorogenic acid, quinic acid, secologanic acid, luteoloside, loganin, secoxyloganin, morroniside and L-isoleucine) were significantly different, which may lead to the classification and the differences in efficacy of LJF and LJC. Our findings not only provide a basis for the comprehensive evaluation and intrinsic quality control of LJF and LJC, but also pave the way for discovering the material basis contributing to the different properties and efficacies of the two medicinal materials at the phytochemical level.

Principal Component Analyses of Potential Repository Groundwaters

1999 ◽  
Vol 556 ◽  
Author(s):  
H. Sasamoto ◽  
P. Salter ◽  
M. Apted ◽  
M. Yuiv
Keyword(s):  
Radioactive Waste ◽  
Principal Component ◽  
Chemical Components ◽  
Compacted Clay ◽  
Multivariate Statistical ◽  
Data Set ◽  
High Level Radioactive Waste ◽  
Scenario Analyses ◽  
Statistical Analysis Technique ◽  
High Level

AbstractThe chemical composition of ambient groundwater for a geological, high level radioactive waste repository is of crucial significance to issues such as radioelement solubility limits, sorption, corrosion of the overpack, behavior of compacted clay buffers, and many other factors involved in repository safety assessment. At this time, there are no candidate repository sites established in Japan for the geological disposal of high-level radioactive waste, and only generic rock formations are under consideration. It is important that a small, but representative set of groundwater types be identified so that defensible models and data for generic repository performance assessment can be established. Over 15,000 separate analyses of Japanese groundwaters have been compiled into a data set for the purpose of evaluating the range of geochemical conditions for waste repositories in Japan. This paper demonstrates the use of a multivariate statistical analysis technique, principal component analysis (PCA), to derive a set of statistically based, representative groundwater categories from the multiple chemical components and temperature that characterize the deep Japanese groundwater analyses. PCA also can be used to guide the selection of groundwaters that could be used in scenario analyses of future geological events in Japan.

scholarly journals The Effectiveness of Wenner-Schlumberger and Dipole-dipole Array of 2D Geoelectrical Survey to Detect The Occurring of Groundwater in the Gunung Kidul Karst Aquifer System, Yogyakarta, Indonesia

2016 ◽  
Vol 1 (2) ◽  
pp. 71 ◽  
Author(s):  
Oktanius Richard Hermawan ◽  
Doni Prakasa Eka Putra
Keyword(s):  
Karst Aquifer ◽  
Groundwater Exploration ◽  
Karst Area ◽  
Karst Terrain ◽  
Aquifer System ◽  
Crystalline Limestone ◽  
Karst Aquifer System ◽  
Dipole Configuration ◽  
Underground River ◽  
Water Saturated

Until today, geoelectrical survey is the most effective method for groundwater exploration. 2D method or known as horizontal profiling is now the most appropriate method in the geoelectrical survey compare to vertical electrical sounding method. The 2D method of Wenner-Schlumberger and Dipole-dipole configuration proved to be very effective to locate conventional aquifer occurrence on volcanic terrain or sedimentary terrain. Karst aquifer system is an unconventional aquifer and acts very differ in contrast with the conventional sedimentary aquifer. Heterogeneity and discontinuity of limestones in karst terrain will reveal a wide variety of resistivities, hence it is difficult to interpret. This research has important objective to define the effectiveness of the Wenner-Schlumberger and Dipole-dipole configuration in the 2D geoelectrical survey to explore groundwater in the karst area. Field observation of geology and 2D geoelectrical survey were conducted in underground river of Kali Suci Area, Gunung Kidul. In Kali Suci where an endokarst cave was occured on the surface, line survey was placed in the top of the cave and across the geometry of the cave. Measured stratigraphy in the wall of the cave found four types of limestone which consist of packstone, wackestone, grainstone and crystalline limestone. The Wenner-Schlumberger and Dipole-dipole method can detect differentiation of limestone types and also the exposed underground river successfully. However, compared to Wenner-Schlumberger array, Dipole-dipole array reveals less vertical accuration.. Therefore, on this research, the best method to detect water saturated zone or gourndwater in the karst system is the Wenner-Schlumberger method.

scholarly journals Hydrogeological map of the Dinaric Karst Aquifer System

2017 ◽  
Author(s):  
Chloé Meyer
Keyword(s):  
Adriatic Sea ◽  
Karst Aquifer ◽  
High Quality ◽  
Dinaric Karst ◽  
Resources Management ◽  
Aquifer System ◽  
Ne Italy ◽  
Aquifer Systems ◽  
Hydrogeological Map ◽  
Karst Aquifer System

Groundwaters of the Dinaric Karst form some of the world's largest karst aquifer systems. The Dinaric region contains huge amounts of high quality groundwater. It is one of the major contributors of freshwater entering the Adriatic Sea. The Dinaric Karst Aquifer System extends from NE Italy through Slovenia, Croatia, Bosnia & Herzegovina, Montenegro to Albania. Karst formations connected with the Dinaric carbonate chain outcrop also in Serbia, FYR Macedonia, and possibly in NW Greece. In the framework of the DIKTAS GEF-project (2010-2014) executed by UNESCO-IHP, the four DIKTAS project countries (Albania, Bosnia and Herzegovina, Croatia and Montenegro) have agreed to create two mechanisms in order to facilitate enhanced consultation and exchange of information between the governmental entities that are involved in water resources management. Groundwater Karst Transboundary

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