Micro-Pore Reservoir Spaces and Gas-Bearing Characteristics of the Shale Reservoirs of the Coal Measure Strata in the Qinshui Basin

2021 ◽  
Vol 21 (1) ◽  
pp. 371-381
Author(s):  
Ruying Ma ◽  
Meng Wang ◽  
Weidong Xie ◽  
Haichao Wang
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Physical Properties ◽  
Specific Surface ◽  
Pore Volume ◽  
Gas Content ◽  
Positive Correlation ◽  
Specific Pore Volume ◽  
Shale Reservoirs ◽  
Gas Bearing

To study the exploration potential of the Carboniferous-Permian transitional shale reservoirs in the Qinshui Basin, the Y5 well was selected as the research object, and experiments including organic geochemical tests, microscopic observations, scanning electron microscopy, X-ray diffraction analysis, high-pressure mercury intrusion, methane isothermal adsorption, and low-temperature nitrogen adsorption were carried out to analyse the physical properties of the shale reservoirs of interest. The results show that (1) The organic matter type of the samples is type III, the total organic carbon contents range from 0.27% to 20.52% (avg. 3.15%), the RO values are between 2.45% and 3.36% (avg. 2.86%), and the Tmax values range from 311.00 °C to 575.20 °C (avg. 493.31 °C). These results indicate that the organic matter in the study area is abundant and has experienced a high degree of thermal evolution. (2) The brittleness index is low (avg. 43.81%), and the shale pores in the study area are well developed. The pores contain organic matter-hosted pores, intraparticle pores, interparticle pores, and micro-cracks. (3) The methane isotherm adsorption average contents of the two samples are 0.2968 m3/t and 1.0824 m3/t, and the average contents of the on-site desorbed gas content and measured total gas content are 0.55889 m3/t and 0.8624 m3/t, respectively. (4) The kaolinite and illite contents have a significant negative effect on the specific surface area of the macro-pores and the specific pore volume of the meso-pores. The illite content is conducive to the development of the pore diameter and specific surface area of the meso-pores, and the quartz content has a positive correlation with the specific pore volume of the macro-pores. (5) The measured total gas content has a significant positive correlation with the total organic carbon and a weak positive correlation with the contents of quartz and illite, and the desorbed gas content shows the same correlations. This study demonstrates the physical properties, microscopic pore characteristics, and gas-bearing characteristics of shale reservoirs and their influencing factors in detail.

scholarly journals Micropore Characteristics and Gas-Bearing Characteristics of Marine-Continental Transitional Shale Reservoirs in the East Margin of Ordos Basin

2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Yuanzhen Ma ◽  
Meng Wang ◽  
Ruying Ma ◽  
Jiamin Li ◽  
Asiya Bake ◽  
...  
Keyword(s):  
High Pressure ◽  
Specific Surface ◽  
Surface Area ◽  
Clay Minerals ◽  
Pore Volume ◽  
Ordos Basin ◽  
Gas Content ◽  
The Ordos Basin ◽  
Shale Reservoirs ◽  
Gas Bearing

In order to deeply study the exploration potential of Carboniferous-Permian marine-continental transitional shale reservoirs in the Ordos Basin, the shale samples from well Y1 in the central-southern part of the Hedong Coalfield were used as the research object. The organic geochemical test, scanning electron microscope, X-ray diffraction, and high pressure mercury injection and low-temperature nitrogen adsorption experiments have studied the microscopic characteristics and gas content characteristics of shale reservoirs. The results show that the organic matter type of the sample is type III; the TOC content ranges from 0.28% to 16.87%, with an average of 2.15%; R o is from 2.45% to 3.36%, with an average value of 2.86%; the shale pores in the study area are well developed, containing more organic pores and intergranular pores of clay minerals. Based on the two-dimensional SEM image fractal theory to study different types of pores, the fractal dimension of shale pore fracture morphology is between 2.34 and 2.50, and the heterogeneity is moderate. The high-pressure mercury intrusion experiment characterizes the pore size distribution of shale macropores and transition pores. The pore diameters are mostly nm-scale. Transition pores are the main pores of the shale in the study area. Based on the characteristics of the pore structure, the adsorption capacity and gas content of CH4 in shale reservoir were analyzed by methane isothermal adsorption and gas content experiments. The results showed that the pore volume and specific surface area were positively correlated with clay mineral content, TOC, and RO, but negatively correlated with the quartz content. In clay minerals and brittle minerals, pore volume and specific surface area are positively correlated with illite content and negatively correlated with the quartz and kaolinite content. The measured total gas content and desorbed gas content are significantly positively correlated with TOC, but are weakly positively correlated with the quartz and illite content. This study finely characterizes the physical properties, micropore characteristics, gas-bearing characteristics, and influencing factors of shale reservoirs, which has certain theoretical guiding significance for the research and development of coal-measure shale in the Ordos Basin.

scholarly journals Titanium Carbide Nanocrystals Synthesized from a Metatitanic Acid-Sucrose Precursor via a Carbothermal Reduction

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Hyunho Shin ◽  
Jun-Ho Eun
Keyword(s):  
Process Control ◽  
Titanium Carbide ◽  
Specific Surface ◽  
Surface Area ◽  
Pore Volume ◽  
Carbothermal Reduction ◽  
Crystal Size ◽  
Reduction Process ◽  
Specific Pore Volume ◽  
Metatitanic Acid

A TiC powder is synthesized from a micron-sized mesoporous metatitanic acid-sucrose precursor (precursor M) by a carbothermal reduction process. Control specimens are also prepared using a nanosized TiO2-sucrose precursor (precursor T) with a higher cost. When synthesized at 1500°C for 2 h in flowing Ar, the characteristics of the synthesized TiC from precursor M are similar to those of the counterpart from precursor T in terms of the crystal size (58.5 versus 57.4 nm), oxygen content (0.22 wt% versus 0.25 wt%), and representative sizes of mesopores: approximately 2.5 and 19.7–25.0 nm in both specimens. The most salient differences of the two specimens are found in the TiC from precursor M demonstrating (i) a higher crystallinity based on the distinctive doublet peaks in the high-two-theta XRD regime and (ii) a lower specific surface area (79.4 versus 94.8 m2/g) with a smaller specific pore volume (0.1 versus 0.2 cm3/g) than the counterpart from precursor T.

scholarly journals KEROGEN TYPES OF BAZHENOV FORMATION BASED ON PYROLYSIS DATA AND THEIR COMPARISON WITH OIL PARAMETERS

2017 ◽  
pp. 34-43
Author(s):  
E. E. Oksenoyd ◽  
V. A. Volkov ◽  
E. V. Oleynik ◽  
G. P. Myasnikova
Keyword(s):  
Organic Matter ◽  
Lower Cretaceous ◽  
Alternative Model ◽  
Oil And Gas ◽  
Upper Jurassic ◽  
Gas Content ◽  
Basin Modeling ◽  
Bazhenov Formation ◽  
Gas Bearing

Based on pyrolytic data (3 995 samples from 208 wells) organic matter types of Bazhenov Formation are identified in the central part of Western Siberian basin. Zones of kerogen types I, II, III and mixed I-II and II-III are mapped. Content of sulfur, paraffins, resins and asphaltenes, viscosity, density, temperature and gas content in oils from Upper Jurassic and Lower Cretaceous sediments (3 806 oil pools) are mapped. Oil gradations are identified and distributed. The alternative model of zones of kerogen II and IIS types is presented. The established distributions of organic matter types can be used in basin modeling and in assessment of oil-and-gas bearing prospects.

scholarly journals Quantitative Characterization for the Micronanopore Structures of Terrestrial Shales with Different Lithofacies Types: A Case Study of the Jurassic Lianggaoshan Formation in the Southeastern Sichuan Basin of the Yangtze Region

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Weiwei Liu ◽  
Kun Zhang ◽  
Qianwen Li ◽  
Zhanhai Yu ◽  
Sihong Cheng ◽  
...  
Keyword(s):  
Organic Matter ◽  
Specific Surface ◽  
Pore Structure ◽  
Surface Area ◽  
Specific Surface Area ◽  
Pore Volume ◽  
Sichuan Basin ◽  
Parallel Plate ◽  
Quantitative Characterization ◽  
Southeastern Sichuan Basin

Due to the specificity of the geological background, terrestrial strata are widely distributed in the major hydrocarbon-bearing basins in China. In addition, terrestrial shales are generally featured with high thickness, multiple layers, high TOC content, ideal organic matter types, and moderate thermal evolution, laying a solid material foundation for hydrocarbon generation. However, the quantitative characterization study on their pore structure remains inadequate. In this study, core samples were selected from the Middle Jurassic Lianggaoshan Formation in the southeastern Sichuan Basin of the Upper Yangtze Region for analyses on its TOC content and mineral composition. Besides, experiments including oil washing, the adsorption/desorption of CO2 and nitrogen, and high-pressure mercury pressure experiments were carried out. The pore structure of different petrographic types of terrestrial shales can be accurately and quantitatively characterized with these works. The following conclusions were drawn: for organic-rich mixed shales and organic-rich clay shales, the TOC content is the highest; the pore volume, which is primarily provided by macropores and specific surface area, which is provided by mesopores, was the largest, thus providing more space for shale oil and gas reservation. The pores take on a shape either close to a parallel plate slit or close to or of an ink bottle. For organic-matter-bearing shales, both the pore volume and specific surface area are the second-largest and are provided by the same sized pores with organic-rich mixed shales. Its pores take on a shape approximating either a parallel plate slit or an ink bottle. Organic-matter-bearing mixed shales have the lowest pore volume and specific surface area; its pore volume is primarily provided by macropores, and the specific surface area by mesopores and the shape of the pores are close to an ink bottle.

scholarly journals Acid Modification of Diatomite-Based Sorbents

2020 ◽  
Vol 22 (3) ◽  
pp. 157
Author(s):  
A. Nurgain ◽  
M. Nazhipkyzy ◽  
A.A. Zhaparova ◽  
A.T. Issanbekova ◽  
M. Alfe ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Pore Volume ◽  
Acid Modification ◽  
Acid Pretreatment ◽  
Specific Pore Volume ◽  
Calcination Temperatures ◽  
Pre Treatment ◽  
Hcl Concentration

In this work, the effect of acid pre-treatment (hydrochloric acid, HCl) and calcination of diatomite, a silicon dioxide-material from natural sources, was studied with the aim to obtain diatomite-based sorbents with specific physicochemical properties. For this, acid pre-treatments with HCl at different calcination conditions, namely HCl concentration (0.5, 1 M) and calcination temperatures (from 600 to 900 °C) were studied. Morphological features different from those of natural diatomite were obtained. It has been found that treatment of diatomite with 0.5 M HCl at 800 °C showed a specific pore volume of 0.008 cm3/g, and a specific surface area of 19.26 m2/g, while the treatment of diatomite with 1.0 M HCl showed a specific pore volume of 0.011cm3/g, and a specific surface area of 25.57 m2/g. The performance of the acid pretreatment of diatomite for adsorption of Pb ions from water was also studied.

scholarly journals Shale favorable area optimization in coal-bearing series: A case study from the Shanxi Formation in Northern Ordos Basin, China

2017 ◽  
Vol 36 (5) ◽  
pp. 1295-1309 ◽  
Author(s):  
Wei Guo ◽  
Weijun Shen ◽  
Shangwen Zhou ◽  
Huaqing Xue ◽  
Dexun Liu ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Shale Gas ◽  
Ordos Basin ◽  
Sedimentary Facies ◽  
Gas Content ◽  
Burial Depth ◽  
Organic Carbon Content ◽  
River Channels

Shales in the Well district of Yu 106 of the Shanxi Formation in the Eastern Ordos Basin is deposited in the swamp between delta plains, distributary river channels, natural levee, the far end of crevasse splay, and depression environments. According to organic geochemistry, reservoir physical property, gas bearing capacity, lithology experimental analysis, combined with the data of drilling, logging, testing and sedimentary facies, the reservoir conditions of shale gas and the distribution of an advantageous area in Shanxi Formation have been conducted. The results show that the total organic carbon content of the Shanxi Formation is relatively high, with an average content value of 5.28% in the segment 2 and 3.02% in segment 1, and the organic matter is mainly kerogen type II2 and III. The maturity of organic matter is high with 1.89% as the average value of Ro which indicates the superior condition for gas generation of this reservoir. The porosity of shales is 1.7% on average, and the average permeability is 0.0415 × 10−3 µm2. The cumulative thickness is relatively large, with an average of 75 m. Brittle mineral and clay content in shales are 49.9% and 50.1%, respectively, but the burial depth of shale is less than 3000 m. The testing gas content is relatively high (0.64 × 104 m3/d), which shows a great potential in commercial development. The total organic carbon of the segment 2 is higher than that of the segment 1, and it is also better than segment 1 in terms of gas content. Based on the thickness of shale and the distribution of sedimentary facies, it is predicted that the advantageous area of shale gas in the segment 2 is distributed in a striped zone along the northeast and the northsouth direction, which is controlled by the swamp microfacies between distributary river channels.

Modelling dynamic interactions between soil structure and soil organic matter

2020 ◽  
Author(s):  
Nicholas Jarvis ◽  
Elsa Coucheney ◽  
Claire Chenu ◽  
Anke Herrmann ◽  
Thomas Keller ◽  
...  
Keyword(s):  
Organic Matter ◽  
Carbon Sequestration ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Physical Properties ◽  
Management Practices ◽  
Animal Manure ◽  
Soil Bulk Density ◽  
Organic Carbon Content

<p>The aggregated structure of soil is known to reduce rates of soil organic matter (SOM) decomposition and therefore influence the potential for long-term carbon sequestration. In turn, the storage and turnover of SOM strongly determines soil aggregation and thus the physical properties of soil. The two-way nature of these interactions has not yet been explicitly considered in soil organic matter models. In this study, we present and describe a new model of these dynamic feedbacks between SOM storage, soil pore structure and soil physical properties. We show the results of a test of the model against measurements made during 61 years in a field trial located near Uppsala (Sweden) in two treatments with different OM inputs (bare fallow, animal manure). The model was able to successfully reproduce long-term trends in soil bulk density and organic carbon content (SOC), as well as match limited data on soil pore size distribution and surface elevation. The results suggest that the model approach presented here could prove useful in analyses of the effects of soil and crop management practices and climate change on the long-term potential for soil organic carbon sequestration.</p>

Freeze-thaw dynamics in synthetic permafrost soil columns with variable organic carbon content

2020 ◽  
Author(s):  
Jelte de Bruin ◽  
Victor Bense ◽  
Martine van der Ploeg
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Physical Properties ◽  
Groundwater Flow ◽  
Soil Column ◽  
Soil Physical Properties ◽  
Soil Columns ◽  
Cold Regions ◽  
Warming Climate ◽  
Permafrost Thawing

<p>Cold-regions hold a pool of organic carbon that has accumulated over many thousands to millions of years and which is currently kept immobile by permafrost. However, in a warming climate, a deepening of the active layer results in the release of greenhouse gasses CO<sub>2</sub> and CH<sub>4</sub> into the atmosphere from this carbon pool. Additionally, due to the degradation of deeper permafost, soil hydraulic properties and associated groundwater flow paths are shifting rapidly as a result of which also organic carbon in deeper permafrost is being dissolved into groundwater, which can then reach the surface environment via groundwater flow.  This provides an additional mechanism by which permafrost carbon can be mobilized in  a warming climate, and one which is likely increasingly important for progressive surface warming.</p><p>Although the process of carbon leaching from thawing organic rich permafrost layers into the groundwater is an increasingly important part of the carbon cycle of cold-regions, it is notoriously difficult to measure in situ or incorporate into numerical model assessments due to the highly heterogeneous properties of the permafrost, and lack of process knowledge. In particular, the crucial understanding of the influence of different soil physical properties such as soil grain size and organic matter content on permafrost thawing processes is missing, as well the precise release mechanisms  of organic matter into pore waters in thawing soils.</p><p>This study employs lab soil column experiments to investigate the interplay between soil physical properties and thawing dynamics of permafrost. One meter high soil columns are frozen to create controlled permafrost conditions. A range of sand grain sizes (0.1 to 0.8mm) and organic matter contents (1 to 10 wt%) representative for sedimentary permafrost are used. The column is thermally insulated on the sides and top, exposing only one face to ambient temperature in the climate chamber. In this way one-dimensional heat flow conditions are created. So far, the columns are equipped with arrays of temperature sensors. Experiments consist of a cycle of freezing and thawing. Our initial data and analysis illustrate how a fast evolving thawing front develops through the frozen soil column  including the effects of latent heat at the thawing front. Numerical modeling allows to infer the soil thermal properties relevant to model the permafrost thawing process.</p>

scholarly journals STUDY OF NaOH - ACTIVATION TEMPERATURE INFLUENCE TOWARD CHARACTER OF MESOPOROUS CARBON BASED ON TEXTILE SLUDGE WASTE

2010 ◽  
Vol 8 (3) ◽  
pp. 348-352 ◽  
Author(s):  
Tutik Setianingsih ◽  
Uswatun Hasanah ◽  
Darjito Darjito
Keyword(s):  
Optimum Condition ◽  
Specific Surface ◽  
Surface Area ◽  
Pore Volume ◽  
Mesoporous Carbon ◽  
Activation Temperature ◽  
Specific Pore Volume ◽  
Sludge Waste ◽  
Textile Sludge ◽  
Hcl Solution

Textile sludge waste contains many organic matters so that it is potential to be used as mesoporous carbon precursor. Actived carbon with mesopore character is effective as adsorbent and catalyst carrier of large molecules. Synthesis of the activated mesoporous carbon was done with purpose to study influence of activation temperature toward characters of the carbon. Process of the synthesis involved dry sludge (50 g) as precursor, concentrated sodium silicate solution SiO2 24.5% and Na2O 7.5% (50 mL) as template source, 1 M HCl solution (50 mL) as polimering agent, carbonization condition at 600 °C 3 h under nitrogen gas flow, activation conditions with NaOH 50% and various temperatures (400, 500, 600, 700, and 800 °C), and demineralizatin conditions with 0.1 M HCl solution for 4 h and 125 rpm. All of the products were characterized with methylen blue method to determine specific pore volume and specific surface area. The carbon obtained at optimum temperature was characterized again with surface area analyzer. Result of the research showed that the optimum condition was achieved at activation temperature of 500 °C. Characters of the synthesized carbon at the optimum condition were specific surface area of 638.32 m2/g, specific pore volume of 0.35 cm3/g, average pore diameter of 21.78 Å, and methylene blue number of 358.87 mg/g.   Keywords: actived mesoporous carbon, textile sludge, temperature

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