Treatment of Landfill Leachate by Combined Submerged Membrane Bioreactor (SMBR) and Electrochemical Oxidation

2020 ◽  
Vol 12 (7) ◽  
pp. 953-960
Author(s):  
Bo Peng ◽  
Di Qiu ◽  
Xiaogang Wu
Keyword(s):  
Electrochemical Oxidation ◽  
Removal Efficiency ◽  
Landfill Leachate ◽  
Membrane Bioreactor ◽  
Carbon Particle ◽  
Three Dimensional ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Chloride Ions ◽  
Submerged Membrane Bioreactor

To efficiently treat landfill leachate, we prepared a new integrated submerged membrane bioreactor (SMBR) and oxidation technology. Our results, under organic loading rates of 2.0–2.3 kg COD/(m3 ·d), showed that through SMBR we can acquire removal efficiencies of 91.2% and 87.3% for ammonia and chemical oxygen demand (COD), respectively. A Ti/RuO2–IrO2 anode and stainless-steel cathode combination was engaged to carry out electrochemical oxidation of SMBR permeate. Ammonia and COD were removed after 3 h electrochemical oxidation (at 40 mA/cm2 current density), and achieved 93.5% and 66.9% removal efficiency with activated carbon particle electrode introduced in the three-dimensional electrodes, respectively. The higher removal efficiency for ammonia nitrogen than COD can be rendered by excited chloride ions, as they affect the competition between organic matter and ammonia nitrogen. Thus, SMBR combined with electrochemical oxidation possesses good prospects to be applied for efficient reduction of ammonia and COD in landfill leachates.

scholarly journals Performance of a membrane bioreactor in extreme concentrations of bisphenol A

2018 ◽  
Vol 77 (6) ◽  
pp. 1505-1513 ◽  
Author(s):  
Yassine Ouarda ◽  
Mehdi Zolfaghari ◽  
Patrick Drogui ◽  
Brahima Seyhi ◽  
Gerardo Buelna ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Removal Efficiency ◽  
Retention Time ◽  
Membrane Bioreactor ◽  
Heterotrophic Bacteria ◽  
Oxygen Demand ◽  
Ammonia Removal ◽  
Biodegradation Rate ◽  
Solid Retention Time ◽  
Submerged Membrane Bioreactor

Abstract In this study, a submerged membrane bioreactor was used to study the effect of low and high bisphenol A (BPA) concentration on the sludge biological activity. The pilot was operated over 540 days with hydraulic retention time and solid retention time of 5.5 hours and 140 days, respectively. As a hydrophobic compound, BPA was highly adsorbed by activated sludge. In lower concentrations, the biodegradation rate remained low, since the BPA concentration in the sludge was lower than 0.5 mg/g TS; yet, at an influent concentration up to 15 mg/L, the biodegradation rate was increasing, resulting in 99% BPA removal efficiency. The result for chemical oxygen demand removal showed that BPA concentration has no effect on the heterotrophic bacteria that were responsible for the organic carbon degradation. In higher concentrations, up to 16 mg of BPA was used for each gram of sludge as a source of carbon. However, the activity of autotrophic bacteria, including nitrifiers, was completely halted in the presence of 20 mg/L of BPA or more. Although nitrification was stopped after day 400, ammonia removal remained higher than 70% due to air stripping. Assimilation by bacteria was the only removal pathway for phosphorus, which resulted in an average 35% of P-PO4 removal efficiency.

scholarly journals Optimization of Coagulation-Flocculation Process of Landfill Leachate by Tin (IV) Chloride Using Response Surface Methodology

2019 ◽  
Vol 6 (1) ◽  
pp. 41-48 ◽  
Author(s):  
Abdul Aziz Hamidi ◽  
Syed Zainal Sharifah Farah Fariza ◽  
Alazaiza Motasem Y.D
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Removal Efficiency ◽  
Landfill Leachate ◽  
Chemical Properties ◽  
Oxygen Demand ◽  
Statistical Design ◽  
Water Infiltration ◽  
Flocculation Process ◽  
Maximum Removal

Landfill leachate is highly polluted and generated as a result of water infiltration through solid waste produced domestically and industrially. This study investigated the applicability of the response surface methodology (RSM) to optimize the removal performances of chemical oxygen demand (COD), color, and suspended solids (SS) from landfill leachate by coagulation process using Tin tetrachloride pentahydrate. The leachate samples were collected from Alor Pongsu Landfill (APLS) in Perak, Malaysia. Before starting the experiments, general characterization was carried out for raw leachate samples to investigate their physical and chemical properties. The effects of the dosage and pH of SnCl4 on the removal performances were evaluated as well. An ideal experimental design was performed based on the central composite design (CCD) by RSM. In addition, this RSM was used to evaluate the effects of process variables and their interaction toward the attainment of their optimum conditions. The statistical design of the experiments and data analysis was resolved using the Design-Expert software. Further, the range of coagulant dosage and pH was selected based on a batch study which was conducted at 13000 mg/L to 17000 mg/L of SnCl4 and pH ranged from 6 to 10. The results showed that the optimum pH and dosage of SnCl4 were 7.17 and 15 g/L, respectively, where the maximum removal efficiency was 67.7% for COD and 100% for color and SS. The results were in agreement with the experimental data with a maximum removal efficiency of 67.84 %, 98.6 %, and 99.3%, for COD, color, and SS, respectively. Overall, this study verified that the RSM method was viable for optimizing the operational condition of the coagulation-flocculation process.

scholarly journals Analysis of the Bioaugmentation Potential of Pseudomonas putida OR45a and Pseudomonas putida KB3 in the Sequencing Batch Reactors Fed with the Phenolic Landfill Leachate

Water ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 906
Author(s):  
Justyna Michalska ◽  
Artur Piński ◽  
Joanna Żur ◽  
Agnieszka Mrozik
Keyword(s):  
Pseudomonas Putida ◽  
Landfill Leachate ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Batch Reactors ◽  
Sequencing Batch Reactors ◽  
High Toxicity ◽  
High Enzymatic Activity ◽  
Wastewater Treatment Systems ◽  
Nonspecific Esterases

The treatment of landfill leachate could be challenging for the biological wastewater treatment systems due to its high toxicity and the presence of poorly biodegradable contaminants. In this study, the bioaugmentation technology was successfully applied in sequencing batch reactors (SBRs) fed with the phenolic landfill leachate by inoculation of the activated sludge (AS) with two phenol-degrading Pseudomonas putida OR45a and Pseudomonas putida KB3 strains. According to the results, the SBRs bioaugmented with Pseudomonas strains withstood the increasing concentrations of the leachate. This resulted in the higher removal efficiency of the chemical oxygen demand (COD) of 79–86%, ammonia nitrogen of 87–88% and phenolic compounds of 85–96% as compared to 45%, 64%, and 50% for the noninoculated SBR. Simultaneously, the bioaugmentation of the AS allowed to maintain the high enzymatic activity of dehydrogenases, nonspecific esterases, and catalase in this ecosystem, which contributed to the higher functional capacity of indigenous microorganisms than in the noninoculated AS. Herein, the stress level experienced by the microorganisms in the SBRs fed with the leachate computed based on the cellular ATP measurements showed that the abundance of exogenous Pseudomonas strains in the bioreactors contributed to the reduction in effluent toxicity, which was reflected by a decrease in the stress biomass index to 32–45% as compared to the nonbioaugmented AS (76%).

scholarly journals The comparison of efficiency of Fenton and photo-Fenton treatment of stabilised landfill leachate / Porównanie efektywności oczyszczania odcieków z ustabilizowanego składowiska odpadów komunalnych w procesie Fentona i foto-Fentona

2015 ◽  
Vol 26 (3) ◽  
pp. 49-53 ◽  
Author(s):  
Anna Kwarciak-Kozłowska ◽  
Aleksandra Krzywicka
Keyword(s):  
Landfill Leachate ◽  
Fenton Reaction ◽  
Ferrous Sulphate ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Ammonia Removal ◽  
Mass Ratio ◽  
Leachate Treatment ◽  
Initial Ph ◽  
Removal Efficiencies

Abstract The goal of this article was to compare the efficiency of Fenton and photo-Fenton reaction used for stabilised landfill leachate treatment. The mass ratio of COD:H2O2 was fixed to 1:2 for every stages. The dose of reagents (ferrous sulphate/hydrogen peroxide) was different and ranged from 0.1 to 0.5. To determine the efficiency of treatment, the BOD (biochemical oxygen demand COD (chemical oxygen demand), TOC (total organic carbon) , ammonia nitrogen and BOD/COD ratio was measured. The experiment was carried out under the following conditions: temperature was 25ºC, the initial pH was adjusted to 3.0. Every processes were lasting 60 minutes. The most appropriate dose of reagents was 0.25 (Fe2+/H2O2). It was found that the application of UV contributed to increase of COD, TOC and ammonia removal efficiencies by an average of 14%.

The ecological filter system for treatment of decentralized wastewater

2016 ◽  
Vol 74 (7) ◽  
pp. 1553-1560
Author(s):  
Kun Zhong ◽  
Yi-yong Luo ◽  
Zheng-song Wu ◽  
Qiang He ◽  
Xue-bin Hu ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Organic Pollutants ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Nitrogen And Phosphorus ◽  
Treatment Technology ◽  
Removal Rates ◽  
Carbon Nitrogen Ratio ◽  
Ecological Filter ◽  
Aerated Filter

A vertical flow constructed wetland was combined with a biological aerated filter to develop an ecological filter, and to obtain the optimal operating parameters: The hydraulic loading was 1.55 m3/(m2·d), carbon–nitrogen ratio was 10, and gas–water ratio was 6. The experimental results demonstrated considerable removal efficiency of chemical oxygen demand (COD), ammonia nitrogen (NH4+-N), total nitrogen (TN), and total phosphorus (TP) in wastewater by the ecological filter, with average removal rates of 83.79%, 93.10%, 52.90%, and 79.07%, respectively. Concentration of NH4+-N after treatment met the level-A discharge standard of GB18918-2002. Compared with non-plant filter, the ecological filter improved average removal efficiency of COD, NH4+-N, TN, and TP by 13.03%, 25.30%, 14.80%, and 2.32%, respectively: thus, plants significantly contribute to the removal of organic pollutants and nitrogen. Through microporous aeration and O2 secretion of plants, the ecological filter formed an aerobic–anaerobic–aerobic alternating environment; thus aerobic and anaerobic microbes were active and effectively removed organic pollutants. Meanwhile, nitrogen and phosphorus were directly assimilated by plants and as nutrients of microorganisms. Meanwhile, pollutants were removed through nitrification, denitrification, filtration, adsorption, and interception by the filler. High removal rates of pollutants on the ecological filter proved that it is an effective wastewater-treatment technology for decentralized wastewater of mountainous towns.

Combined technology for clomazone herbicide wastewater treatment: three-dimensional packed-bed electrochemical oxidation and biological contact degradation

2013 ◽  
Vol 68 (1) ◽  
pp. 257-260 ◽  
Author(s):  
Yujie Feng ◽  
Junfeng Liu ◽  
Limin Zhu ◽  
Jinzhi Wei
Keyword(s):  
Electrochemical Oxidation ◽  
Organic Contaminants ◽  
Removal Rate ◽  
Three Dimensional ◽  
Oxygen Demand ◽  
Cell Voltage ◽  
Packed Bed ◽  
Cod Removal ◽  
Cod Removal Rate ◽  
Oxidation Reactor

The clomazone herbicide wastewater was treated using a combined technology composed of electrochemical catalytic oxidation and biological contact degradation. A new type of electrochemical reactor was fabricated and a Ti/SnO2 electrode was chosen as the anode in electrochemical-oxidation reactor and stainless steel as the cathode. Ceramic rings loaded with SnO2 were used as three-dimensional electrodes forming a packed bed. The operation parameters that might influence the degradation of organic contaminants in the clomazone wastewater were optimized. When the cell voltage was set at 30 V and the volume of particle electrodes was designed as two-thirds of the volume of the total reactor bed, the chemical oxygen demand (COD) removal rate could reach 82% after 120 min electrolysis, and the ratio of biochemical oxygen demand (BOD)/COD of wastewater increased from 0.12 to 0.38. After 12 h degradation with biological contact oxidation, the total COD removal rate of the combined technology reached 95%, and effluent COD was below 120 mg/L. The results demonstrated that this electrocatalytic oxidation method can be used as a pretreatment for refractory organic wastewater before biological treatment.

Removal of organic micro-pollutants from solid waste landfill leachate in membrane bioreactor operated without excess sludge discharge

2012 ◽  
Vol 66 (8) ◽  
pp. 1774-1780 ◽  
Author(s):  
V. Boonyaroj ◽  
C. Chiemchaisri ◽  
W. Chiemchaisri ◽  
K. Yamamoto
Keyword(s):  
Solid Waste ◽  
Landfill Leachate ◽  
Membrane Bioreactor ◽  
Hollow Fiber Membrane ◽  
Oxygen Demand ◽  
Disposal Site ◽  
Two Stage ◽  
Mixed Liquor ◽  
Aerobic Reactor ◽  
Micro Pollutants

Two-stage membrane bioreactor (MBR) system was applied to the treatment of landfill leachate from a solid waste disposal site in Thailand. The first stage anoxic reactor was equipped with an inclined tube module for sludge separation. It was followed by an aerobic stage with a hollow fiber membrane module for solid liquid separation. Mixed liquor sludge from the aerobic reactor was re-circulated back to anoxic reactor in order to maintain constant mixed liquor suspended solids (MLSS) concentration in the aerobic reactor. The removal of micro-pollutants from landfill leachate along the treatment period of 300 days was monitored. The results indicated that two-stage MBRs could remove biochemical oxygen demand (BOD), chemical oxygen demand (COD) and NH4+ by 97, 87 and 91% at steady operating condition. Meanwhile organic micro-pollutant removals were 50–76%. The removal efficiencies varied according to the hydrophobic characteristic of compounds but they were improved during long-term MBR operation without sludge discharge.

Treatment of petrochemical secondary effluent by an up-flow biological aerated filter (BAF)

2016 ◽  
Vol 73 (8) ◽  
pp. 2031-2038 ◽  
Author(s):  
L. Y. Fu ◽  
C. Y. Wu ◽  
Y. X. Zhou ◽  
J. E. Zuo ◽  
Y. Ding
Keyword(s):  
Removal Efficiency ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Gas Chromatography Mass Spectrometry ◽  
Secondary Effluent ◽  
Biological Aerated Filter ◽  
Total Removal ◽  
Aerated Filter ◽  
Final Effluent

In this study, petrochemical secondary effluent was treated by a 55 cm diameter pilot-scale biological aerated filter (BAF) with a media depth of 220 cm. Volcanic rock grains were filled as the BAF media. Median removal efficiency of chemical oxygen demand (COD) and ammonia nitrogen (NH3-N) was 29.35 and 57.98%, respectively. Moreover, the removal profile of the COD, NH3-N, total nitrogen and total organic carbon demonstrated that the filter height of 140 cm made up to 90% of the total removal efficiency of the final effluent. By gas chromatography–mass spectrometry, removal efficiencies of 2-chloromethyl-1,3-dioxolane, and benzonitrile, indene and naphthalene were obtained, ranging from 30.12 to 63.01%. The biomass and microbial activity of the microorganisms on the filter media were in general reduced with increasing filter height, which is consistent with the removal profile of the contaminants. The detected genera Defluviicoccus, Betaproteobacteria_unclassified and the Blastocatella constituted 1.86–6.75% of the identified gene, enhancing the COD and nitrogen removal in BAF for treating petrochemical secondary effluent.

Co-treatment of landfill leachate in laboratory-scale sequencing batch reactors: analysis of system performance and biomass activity by means of respirometric techniques

2014 ◽  
Vol 69 (6) ◽  
pp. 1267-1274 ◽  
Author(s):  
M. Capodici ◽  
D. Di Trapani ◽  
G. Viviani
Keyword(s):  
Landfill Leachate ◽  
Oxygen Uptake Rate ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Ammonia Nitrogen ◽  
Synthetic Wastewater ◽  
Batch Reactors ◽  
Sequencing Batch Reactors ◽  
Population Average ◽  
Biomass Activity

Aged or mature leachate, produced by old landfills, can be very refractory; for this reason mature leachate is difficult to treat alone, but it can be co-treated with sewage or domestic wastewater. The aim of the study was to investigate the feasibility of leachate co-treatment with synthetic wastewater, in terms of process performance and biomass activity, by means of respirometric techniques. Two sequencing batch reactors (SBRs), named SBR1 and SBR2, were fed with synthetic wastewater and two different percentages of landfill leachate (respectively 10% and 50% v v−1 in SBR1 and SBR2). The results showed good chemical oxygen demand (COD) removal efficiency for both reactors, with average COD removals equal to 91.64 and 89.04% respectively for SBR1 and SBR2. Furthermore, both SBRs showed good ammonia-nitrogen (AN) removal efficiencies, higher than 60%, thus confirming the feasibility of leachate co-treatment with a readily biodegradable wastewater. Significant respiration rates were obtained for the heterotrophic population (average values of maximum oxygen uptake rate equal to 37.30 and 56.68 mg O2 L−1 h−1 respectively for SBR1 and SBR2), thus suggesting the feasibility of leachate co-treatment with synthetic wastewater.

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