The Mystery of Ice Crystal Multiplication in a Laboratory Experiment

2013 ◽  
Vol 71 (1) ◽  
pp. 89-97 ◽  
Author(s):  
Gianni Santachiara ◽  
Franco Belosi ◽  
Franco Prodi

Abstract This paper addresses the problem of the large discrepancies between ice crystal concentrations in clouds and the number of ice nuclei in nearby clear air reported in published papers. Such discrepancies cannot always be explained, even by taking into account both primary and secondary ice formation processes. A laboratory experiment was performed in a cylindrical column placed in a cold room at atmospheric pressure and temperature in the −12° to −14°C range. Supercooled droplets were nucleated in the column, in the absence of aerosol ice nuclei, by injecting ice crystals generated outside in a small syringe. A rapid increase in the ice crystal concentration was observed in the absence of any known ice multiplication. The ratio between the mean number of ice crystals in the column, after complete droplet vaporization, and the number of ice crystals introduced in the column was about 10:1. The presence of small ice crystals (introduced at the top of the column) in the unstable system (supercooled droplets) appears to trigger the transformation in the whole supercooled liquid cloud. A possible explanation could be that the rapidly evaporating droplets cool sufficiently to determine a homogeneous nucleation.

2020 ◽  
Vol 12 (13) ◽  
pp. 2094
Author(s):  
Chong Cheng ◽  
Fan Yi

Falling mixed-phase virga from a thin supercooled liquid layer cloud base were observed on 20 occasions at altitudes of 2.3–9.4 km with ground-based lidars at Wuhan (30.5 °N, 114.4 °E), China. Polarization lidar profile (3.75-m) analysis reveals some ubiquitous features of both falling mixed-phase virga and their liquid parent cloud layers. Each liquid parent cloud had a well-defined base height where the backscatter ratio R was ~7.0 and the R profile had a clear inflection point. At an altitude of ~34 m above the base height, the depolarization ratio reached its minimum value (~0.04), indicating a liquid-only level therein. The thin parent cloud layers tended to form on the top of a broad preexisting aerosol/liquid water layer. The falling virga below the base height showed firstly a significant depolarization ratio increase, suggesting that most supercooled liquid drops in the virga were rapidly frozen into ice crystals (via contact freezing). After reaching a local maximum value of the depolarization ratio, both the values of the backscatter ratio and depolarization ratio for the virga exhibited an overall decrease with decreasing height, indicating sublimated ice crystals. The diameters of the ice crystals in the virga were estimated based on an ice particle sublimation model along with the lidar and radiosonde observations. It was found that the ice crystal particles in these virga cases tended to have smaller mean diameters and narrower size distributions with increasing altitude. The mean diameter value is 350 ± 111 µm at altitudes of 4–8.5 km.


2012 ◽  
Vol 12 (7) ◽  
pp. 17295-17345
Author(s):  
D. P. Grosvenor ◽  
T. W. Choularton ◽  
T. Lachlan-Cope ◽  
M. W. Gallagher ◽  
J. Crosier ◽  
...  

Abstract. In-situ aircraft observations of ice crystal concentrations in Antarctic clouds are presented for the first time. Orographic, layer and wave clouds around the Antarctic Peninsula and Larsen Ice shelf regions were penetrated by the British Antarctic Survey's Twin Otter Aircraft, which was equipped with modern cloud physics probes. The clouds studied were mostly in the free troposphere and hence ice crystals blown from the surface are unlikely to have been a major source for the ice phase. The temperature range covered by the experiments was 0 to −21°C. The clouds were found to contain supercooled liquid water in most regions and at heterogeneous ice formation temperatures ice crystal concentrations (60 s averages) were often less than 0.07 l−1, although values up to 0.22 l−1 were observed. Estimates of observed aerosol concentrations were used as input into the DeMott et al., 2010 ice nuclei (IN) parameterisation. The observed ice crystal number concentrations were generally in broad agreement with the IN predictions, although on the whole the predicted values were higher. Possible reasons for this are discussed and include the lack of IN observations in this region with which to characterise the parameterisation, and/or problems in relating ice concentration measurements to IN concentrations. Other IN parameterisations significantly overestimated the number of ice particles. Generally ice particle concentrations were much lower than found in clouds in middle latitudes for a given temperature. Higher ice crystal concentrations were sometimes observed at temperatures warmer than −9 °C, with values of several per litre reached. These were attributable to secondary ice particle production by the Hallett Mossop process. Even in this temperature range it was observed that there were regions with little or no ice that were dominated by supercooled liquid water. It is likely that in some cases this was due to a lack of seeding ice crystals to act as rimers to initiate secondary ice particle production. This highlights the complicated nature of this process and indicates that the accurate representation of it in global models is likely to represent a challenge. However, the contrast between Hallett Mossop zone ice concentrations and the fairly low concentrations of heterogeneously nucleated ice suggests that the Hallet Mossop process has the potential to be very important in remote, pristine regions such as around the Antarctic coast.


2012 ◽  
Vol 12 (23) ◽  
pp. 11275-11294 ◽  
Author(s):  
D. P. Grosvenor ◽  
T. W. Choularton ◽  
T. Lachlan-Cope ◽  
M. W. Gallagher ◽  
J. Crosier ◽  
...  

Abstract. In-situ aircraft observations of ice crystal concentrations in Antarctic clouds are presented for the first time. Orographic, layer and wave clouds around the Antarctic Peninsula and Larsen Ice shelf regions were penetrated by the British Antarctic Survey's Twin Otter aircraft, which was equipped with modern cloud physics probes. The clouds studied were mostly in the free troposphere and hence ice crystals blown from the surface are unlikely to have been a major source for the ice phase. The temperature range covered by the experiments was 0 to −21 °C. The clouds were found to contain supercooled liquid water in most regions and at heterogeneous ice formation temperatures ice crystal concentrations (60 s averages) were often less than 0.07 l−1, although values up to 0.22 l−1 were observed. Estimates of observed aerosol concentrations were used as input into the DeMott et al. (2010) ice nuclei (IN) parameterisation. The observed ice crystal number concentrations were generally in broad agreement with the IN predictions, although on the whole the predicted values were higher. Possible reasons for this are discussed and include the lack of IN observations in this region with which to characterise the parameterisation, and/or problems in relating ice concentration measurements to IN concentrations. Other IN parameterisations significantly overestimated the number of ice particles. Generally ice particle concentrations were much lower than found in clouds in middle latitudes for a given temperature. Higher ice crystal concentrations were sometimes observed at temperatures warmer than −9 °C, with values of several per litre reached. These were attributable to secondary ice particle production by the Hallett Mossop process. Even in this temperature range it was observed that there were regions with little or no ice that were dominated by supercooled liquid water. It is likely that in some cases this was due to a lack of seeding ice crystals to act as rimers to initiate secondary ice particle production. This highlights the chaotic and spatially inhomogeneous nature of this process and indicates that the accurate representation of it in global models is likely to represent a challenge. However, the contrast between Hallett Mossop zone ice concentrations and the fairly low concentrations of heterogeneously nucleated ice suggests that the Hallet Mossop process has the potential to be very important in remote, pristine regions such as around the Antarctic coast.


2009 ◽  
Vol 9 (5) ◽  
pp. 20347-20369 ◽  
Author(s):  
K. D. Froyd ◽  
D. M. Murphy ◽  
P. Lawson ◽  
D. Baumgardner ◽  
R. L. Herman

Abstract. The composition of residual particles from evaporated cirrus ice crystals near the tropical tropopause as well as unfrozen aerosols were measured with a single particle mass spectrometer. Subvisible cirrus residuals were predominantly composed of internal mixtures of neutralized sulfate with organic material and were chemically indistinguishable from unfrozen sulfate-organic aerosols. Ice residuals were also similar in size to unfrozen aerosol. Heterogeneous ice nuclei such as mineral dust were not enhanced in these subvisible cirrus residuals. Biomass burning particles were depleted in the residuals. Cloud probe measurements showing low cirrus ice crystal number concentrations were inconsistent with conventional homogeneous freezing. Recent laboratory studies provide heterogeneous nucleation scenarios that may explain tropopause level subvisible cirrus formation.


2007 ◽  
Vol 112 (D10) ◽  
Author(s):  
Anthony J. Prenni ◽  
Paul J. DeMott ◽  
Cynthia Twohy ◽  
Michael R. Poellot ◽  
Sonia M. Kreidenweis ◽  
...  

2018 ◽  
Vol 11 (7) ◽  
pp. 4015-4031 ◽  
Author(s):  
Armin Afchine ◽  
Christian Rolf ◽  
Anja Costa ◽  
Nicole Spelten ◽  
Martin Riese ◽  
...  

Abstract. The ice water content (IWC) of cirrus clouds is an essential parameter determining their radiative properties and thus is important for climate simulations. Therefore, for a reliable measurement of IWC on board research aircraft, it is important to carefully design the ice crystal sampling and measuring devices. During the ML-CIRRUS field campaign in 2014 with the German Gulfstream GV HALO (High Altitude and Long Range Research Aircraft), IWC was recorded by three closed-path total water together with one gas-phase water instrument. The hygrometers were supplied by inlets mounted on the roof of the aircraft fuselage. Simultaneously, the IWC is determined by a cloud particle spectrometer attached under an aircraft wing. Two more examples of simultaneous IWC measurements by hygrometers and cloud spectrometers are presented, but the inlets of the hygrometers were mounted at the fuselage side (M-55 Geophysica, StratoClim campaign 2017) and bottom (NASA WB57, MacPex campaign 2011). This combination of instruments and inlet positions provides the opportunity to experimentally study the influence of the ice particle sampling position on the IWC with the approach of comparative measurements. As expected from theory and shown by computational fluid dynamics (CFD) calculations, we found that the IWCs provided by the roof inlets deviate from those measured under the aircraft wing. As a result of the inlet position in the shadow zone behind the aircraft cockpit, ice particle populations with mean mass sizes larger than about 25 µm radius are subject to losses, which lead to strongly underestimated IWCs. On the other hand, cloud populations with mean mass sizes smaller than about 12 µm are dominated by particle enrichment and thus overestimated IWCs. In the range of mean mass sizes between 12 and 25 µm, both enrichment and losses of ice crystals can occur, depending on whether the ice crystal mass peak of the size distribution – in these cases bimodal – is on the smaller or larger mass mode. The resulting deviations of the IWC reach factors of up to 10 or even more for losses as well as for enrichment. Since the mean mass size of ice crystals increases with temperature, losses are more pronounced at higher temperatures, while at lower temperatures IWC is more affected by enrichment. In contrast, in the cases where the hygrometer inlets were mounted at the fuselage side or bottom, the agreement of IWCs is most frequently within a factor of 2.5 or better – due to less disturbed ice particle sampling, as expected from theory – independently of the mean ice crystal sizes. The rather large scatter between IWC measurements reflects, for example, cirrus cloud inhomogeneities and instrument uncertainties as well as slight sampling biases which might also occur on the side or bottom of the fuselage and under the wing. However, this scatter is in the range of other studies and represent the current best possible IWC recording on fast-flying aircraft.


2010 ◽  
Vol 10 (1) ◽  
pp. 245-280
Author(s):  
P. Jish Prakash ◽  
P. Pradeep Kumar

Abstract. Laboratory investigations have been carried out to find the sign and magnitude of charge transfer during the collision between ice crystals and graupel in the presence of supercooled water droplets inside the cylindrical steel chamber kept inside a walk-in cold room, which can reach a temperature of −30 °C. The experiments were performed with pure water (Milli-Q, 18.2 Megohms-cm) and with trace amounts of organic acids and metals at low Rime Accretion Rate (<0.40 g m−2 s-1) applicable to stratiform clouds in the temperature range −5 to −27 °C. The ice crystals and supercooled droplets collided with the graupel target at a constant impact velocity of 2.2 m/s. The presence of trace chemicals (organics or metals) saw significant increase in the magnitude of charge transferred per crystal collision to the graupel. These experiments therefore suggest that the presence of trace amounts of organics or metals in cloud water can significantly alter the electrical structure of stratiform clouds.


2010 ◽  
Vol 10 (1) ◽  
pp. 209-218 ◽  
Author(s):  
K. D. Froyd ◽  
D. M. Murphy ◽  
P. Lawson ◽  
D. Baumgardner ◽  
R. L. Herman

Abstract. The composition of residual particles from evaporated cirrus ice crystals near the tropical tropopause as well as unfrozen aerosols were measured with a single particle mass spectrometer. Subvisible cirrus residuals were predominantly composed of internal mixtures of neutralized sulfate with organic material and were chemically indistinguishable from unfrozen sulfate-organic aerosols. Ice residuals were also similar in size to unfrozen aerosol. Heterogeneous ice nuclei such as mineral dust were not enhanced in these subvisible cirrus residuals. Biomass burning particles were depleted in the residuals. Cloud probe measurements showing low cirrus ice crystal number concentrations were inconsistent with conventional homogeneous freezing. Recent laboratory studies provide heterogeneous nucleation scenarios that may explain tropopause level subvisible cirrus formation.


Author(s):  
I. Taylor ◽  
P. Ingram ◽  
J.R. Sommer

In studying quick-frozen single intact skeletal muscle fibers for structural and microchemical alterations that occur milliseconds, and fractions thereof, after electrical stimulation, we have developed a method to compare, directly, ice crystal formation in freeze-substituted thin sections adjacent to all, and beneath the last, freeze-dried cryosections. We have observed images in the cryosections that to our knowledge have not been published heretofore (Figs.1-4). The main features are that isolated, sometimes large regions of the sections appear hazy and have much less contrast than adjacent regions. Sometimes within the hazy regions there are smaller areas that appear crinkled and have much more contrast. We have also observed that while the hazy areas remain still, the regions of higher contrast visibly contract in the beam, often causing tears in the sections that are clearly not caused by ice crystals (Fig.3, arrows).


1969 ◽  
Vol 26 (6) ◽  
pp. 1342-1343 ◽  
Author(s):  
A. H. Auer ◽  
D. L. Veal ◽  
J. D. Marwitz
Keyword(s):  

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