Assessing glass-fiber modification developments by comparison of glass-fiber epoxy composites with reference materials: Some thoughts on relevance

Author(s):  
Marion Frey ◽  
Andreas J Brunner

Any approach for designing composites with improved mechanical properties finally has to be assessed for respective improvements achieved. Glass-fiber reinforced epoxy matrix laminates consist of several constituents. Pretreatment of the constituents, the processes combining the matrix with the reinforcing fibers as well as the curing of the laminate may all have an effect on the resulting mechanical or fracture properties of the composites. In this contribution, the authors present selected cases from recent materials developments, dealing with glass-fiber epoxy laminates for which a thermal fiber treatment for desizing was compared with chemical solvent desizing. While desizing with a solvent and resizing with another type of sizing yielded tensile and interlaminar shear properties comparable to those of laminates prepared from as-received fibers, but lower for desized fibers, resizing after thermal desizing treatment exceeding +500 ℃ yielded lower properties for laminates from desized and resized fibers, but roughly in the same percentage difference as chemically desized and resized fiber laminates. This raises the question of how material or interface modifications in glass-fiber epoxy composites can best be compared for an assessment of the improvements achieved by the fiber treatments or the fiber–matrix interface modifications.

2011 ◽  
Vol 675-677 ◽  
pp. 419-422 ◽  
Author(s):  
Hong Yan Chen ◽  
Zhen Xing Kong ◽  
Ji Hui Wang

Carbon nanotubes (CNTs) were incorporated into glass fiber/ vinyl ester resins composites to improve their mechanical and thermal properties, especially the interlaminar shear and longitudinal compressive strengths which are belong to the matrix-dominanted properties and much weaker than the fiber-dominated properties. In this study, a higher temperature initiator was added to improve the polymerization degree and raise the transition temperature (Tg). Mechanical testing indicated that by adding 0.4 wt% CNTs, the nano-filled composites attributed to 21%, 16%, 10%, and 8% improvement in interlaminar shear strength, compressive strength, tensile strength and flexural strength with respect to their counterparts without CNTs, respectively. Moreover, Thermogravimetric analysis (TGA) also exhibits approximately 14°C higher decomposition temperature than those of conventional composites.


2021 ◽  
Author(s):  
Chinnappan Balaji Ayyanar ◽  
S. K. Pradeep Mohan ◽  
C. Bharathiraj ◽  
Sanjay Rangappa ◽  
Suchart Siengchin

2021 ◽  
pp. 004051752110519
Author(s):  
Yecheng Fan ◽  
Shen Ziyue ◽  
Shaohua Zeng ◽  
Pengpeng Chen ◽  
Ying Xu ◽  
...  

To improve the interfacial adhesion of glass fiber (GF)/epoxy composites, the GF surface was treated by dispersing aliphatic diamine-functionalized multi-walled carbon nanotubes (MWCNTs). Carboxyl MWCNTs were first modified by aliphatic diamine with different alkyl chain lengths and then deposited on the surface of GF. The effect of aliphatic diamine chain lengths on the MWCNTs’ dispersion and interfacial properties of resultant composites was investigated in detail. The results showed that uniform dispersion of MWCNTs and strong fiber/matrix interfacial adhesion could be achieved, based on the grafting of 1,8-octanediamine onto MWCNTs. Compared with the control sample, the interlaminar shear, flexural, and tensile strengths of the treated composites increased by 41%, 29%, and 30%, respectively; the interlaminar fracture toughness and storage modulus in the glass region were significantly enhanced; and the glass transition temperature increased by more than 8°C. This work demonstrates that the carbon nanotubes functionalized by appropriate chain lengths of amine modifier can improve the fiber/matrix interfacial interactions and thus enhance the strength, toughness, and stiffness of fiber-reinforced composites.


e-Polymers ◽  
2018 ◽  
Vol 18 (1) ◽  
pp. 35-47 ◽  
Author(s):  
Shaohua Zeng ◽  
Mingxia Shen ◽  
Pengpeng Duan ◽  
Fengling Lu ◽  
Shangneng Chen ◽  
...  

AbstractIn this study, an ultrasonic-assisted impregnation method was employed to deposit carboxyl multiwalled carbon nanotubes (MWCNTs) onto the E-glass fiber fabric (GFf) for the preparation of the MWCNT-GFf reinforcer. The effects of ultrasonic power, duration and temperature on the dispersion of MWCNTs onto GFf were investigated, and the mechanical properties, interlaminar adhesion, and dynamic viscoelasticity of the resulting MWCNT-GFf-reinforced composites (MGCs) were evaluated. The results indicated that an effective dispersion of MWCNTs onto GFf without obvious breakage of the MWCNTs was achieved under an ultrasonic power of 600 W, duration of 6 min, and processing temperature of about 0°C. Compared with the GFf-reinforced composite, the tensile strength, flexural strength and interlaminar shear strength of the MGCs exhibited maximum increments of 38.4%, 34.6% and 47.1%, respectively. Moreover, the storage moduli and glass-transition temperatures of the MGCs were significantly enhanced. The ultrasonic parameters were of key importance for dispersing MWCNTs onto GFf and improving the interfacial properties of the composites.


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