The effects of pore‐fluid salinity on ultrasonic wave propagation in sandstones
Petrophysical interpretation of increasingly refined seismic data from subsurface formations requires a more fundamental understanding of seismic wave propagation in sedimentary rocks. We consider the variation of ultrasonic wave velocity and attenuation in sandstones with pore‐fluid salinity and show that wave propagation is modified in proportion to the clay content of the rock and the salinity of the pore fluid. Using an ultrasonic pulse reflection technique (590–890 kHz), we have measured the P-wave and S-wave velocities and attenuations of 15 saturated sandstones with variable effective pressure (5–60 MPa) and pore‐fluid salinity (0.0–3.4 M). In clean sandstones, there was close agreement between experimental and Biot model values of [Formula: see text], but they diverged progressively in rocks containing more than 5% clay. However, this effect is small: [Formula: see text] changed by only 0.6% per molar change in salinity for a rock with a clay content of 29%. The variation of [Formula: see text] with brine molarity exhibited Biot behavior in some samples but not in others; there was no obvious relationship with clay content. P-wave attenuation was independent of pore‐fluid salinity, while S-wave attenuation was weakly dependent. The velocity data suggest the frame bulk and shear moduli of sandstones are altered by changes in the pore‐fluid salinity. One possible mechanism is the formation damage caused by clay swelling and migration of fines in low‐molarity electrolytes. The absence of variation between the attenuation in water‐saturated and brine‐saturated samples indicates the attenuation mechanism is relatively unaffected by changes in the frame moduli.