Volatile fatty acid adsorption on anion exchange resins: kinetics and selective recovery of acetic acid

Author(s):  
Tejaswini Eregowda
1999 ◽  
Vol 40 (9) ◽  
pp. 207-214 ◽  
Author(s):  
J.-P. Croué ◽  
D. Violleau ◽  
C. Bodaire ◽  
B. Legube

The objective of this work was to compare the affinity of well characterized NOM fractions isolated from two surface waters with strong (gel matrix and macroporous matrix) and weak anion exchange resins (AER) using batch experiment conditions. The structural characterization of the fraction of NOM has shown that the higher the hydrophilic character, the lower the C/O atomic ratio, the lower the SUVA, the lower the aromatic carbon content and the lower the molecular weight. In general (not always), strong AER was more efficient to remove DOC than weak AER. For the same water source (Suwannee River), the higher the molecular weight of the NOM fraction, the lower the affinity with AER. Increasing the ionic strength favored the removal of the hydrophobic NOM fraction (“salting out” effect) while increasing the pH apparently reduced the removal of the hydrophilic NOM fraction. Results were discussed in terms of size exclusion, adsorption, anion exchange and also hydrophobic/hydrophilic repulsion.


Author(s):  
Sio Stefanus ◽  
I.G. Mahardika ◽  
I.B.G Partama ◽  
N.N. Suryani

The research has been conducted to find out rumen metabolite of Balinese cows that being given stewed water of Lannea coromandelica peel as a feed additive. The research used group random design (RAK) with 4 treatments of rations and 3 times repetition. Each repetition used three Balinese cows. The weight of cows being used ranging between 137.5 – 235 kg. Basic rations being given were equal, arranged based on a percentage of dry material (% DM) namely: 50% of arrow grass, 20% of gamal leaves (Gliricidia sepium), 1% of urea and 29% of rice bran. Whereas for treatment was feed additive level. The basic ratio of +0 was feed additive (A). The basic ration of +1000 ml was feed additive (B). The basic ration of +1500 ml was feed additive (C) and a basic ration of +2000 ml was feed additive (D). Variables being observed were: N-NH3, volatile fatty acid total and volatile fatty acid partial (acetic acid, propionate acid and butyrate acid). The result of research showed that the administration of 1000 ml-2000 ml of feed additive of stewed water of Lannea coromandelica peel in basic ration differed markedly (P<0.05) to increase the concentration of N-NH3, volatile fatty acid total and volatile fatty acid partial. The utilization of stewed water of Lannea coromandelica peel as a feed additive in basic ration was increasing rumen metabolite of Balinese cows.


2020 ◽  
pp. 039139882094773
Author(s):  
Karin Strobl ◽  
Stephan Harm ◽  
Ute Fichtinger ◽  
Claudia Schildböck ◽  
Jens Hartmann

Introduction: Heparin and citrate are commonly used anticoagulants in membrane/adsorption based extracorporeal liver support systems. However, anion exchange resins employed for the removal of negatively charged target molecules including bilirubin may also deplete these anticoagulants due to their negative charge. The aim of this study was to evaluate the adsorption of citrate by anion exchange resins and the impact on extracorporeal Ca2+ concentrations. Methods: Liver support treatments were simulated in vitro. Citrate and Ca2+ concentrations were measured pre and post albumin filter as well as pre and post adsorbents. In addition, batch experiments were performed to quantify citrate adsorption. Results: Pre albumin filter target Ca2+ concentrations were reached well with only minor deviations. Citrate was adsorbed by anion exchange resins, resulting in a higher Ca2+ concentration downstream of the adsorbent cartridges during the first hour of treatment. Conclusions: The anion exchange resin depletes citrate, leading to an increased Ca2+ concentration in the extracorporeal circuit, which may cause an increased risk of clotting during the first hour of treatment. An increase of citrate infusion during the first hour of treatment should therefore be considered to compensate for the adsorption of citrate.


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