1102 Effect of Counter-ion Concentration on Flow Characteristics in a Cavity Swept by Cationic Surfactant Solution

2012 ◽  
Vol 2012 (0) ◽  
pp. 411-412
Author(s):  
Hiroshi SUZUKI ◽  
Yuta HIGUCHI ◽  
Yoshiyuki KOMODA ◽  
Ruri HIDEMA
Author(s):  
Nguyen Anh Tuan ◽  
Hiroshi Mizunuma

An impinging jet is characterized by high heat transfer and thus is widely used in cooling and heating process in industry. On the other hand, surfactant solutions reduce pipe friction in turbulent flow and at the same time reduce heat transfer. In our past study, it was found that the surfactant solution with higher counter-ion concentration did not reduce the heat transfer in the impinging jet. This phenomenon suggested that the high heat transfer was characterized by high shear rate in impinging jet and not by turbulence. However, it has not yet been determined satisfactorily how the heat transfer is influenced by surfactant solutions in the impinging jet. Especially, the influence of the counter-ion concentration is important, because the counter-ion changes not only the heat transfer but also the rheology of the surfactant solutions. In this study, we visualized the impinging jet of the surfactant solutions, and the influence of the counter-ion was investigated. The results indicated that the wall flow was remarkably influenced by the counter-ion concentration in the impinging jet. In the case of the surfactant solution with equi-molar counter-ion, the induced wall flow was continued only near the stagnation point. By contrast, the solution with higher molar counter-ion induced the radial boundary layer flow on the wall similar to the water flow. This difference in flow would cause the different heat transfer, and the solution with higher molar counter-ion produces normal heat transfer. When comparing the visualized results of the impinging jet with the numerically simulated results, the qualitative agreement was not satisfactory for the surfactant solution with counter-ion of equi-molar concentration. The simulation used a Bingham model as the rheological equation, the constants of which were obtained from a cone and a plate rheometer. It was suggested that the surfactant solution indicated different rheological behavior in these viscometric flow and impinging jet.


Weed Science ◽  
1976 ◽  
Vol 24 (6) ◽  
pp. 549-552 ◽  
Author(s):  
J. D. Gaynor ◽  
V. V. Volk

The effects of soil organic matter, clay, extractable Al, cation exchange capacity, and pH on the adsorption of picloram (4-amino-3,5,6-trichloropicolinic acid) from aqueous and surfactant solutions were investigated. Linear adsorption isotherms for the soils were obtained with the Freundlich equation. Of the five soil properties investigated, Freundlich K values correlated with extractable Al and clay content. Picloram adsorption from aqueous solutions and from the non-ionic and anionic surfactant solutions was greater on the soils at pH 5 than at pH 7. The anionic surfactant competed with picloram for adsorption sites on the soils at pH 5. Picloram adsorption from solutions containing 0.1 and 1% cationic surfactant was greater than that from aqeuous and anionic and nonionic surfactant solutions. Picloram adsorption from the 10% cationic surfactant solution was similar on soils with pH 5 and 7 and increased with decreased organic matter content.


MRS Advances ◽  
2020 ◽  
Vol 5 (17) ◽  
pp. 907-915 ◽  
Author(s):  
Jessica L. Sargent ◽  
Xunkai Chen ◽  
Mitchell C. Brezina ◽  
Sebastian Aldwin ◽  
John A. Howarter ◽  
...  

ABSTRACTIonic hydrogels are an abundant class of materials with applications ranging from drug delivery devices to high performance concrete to baby diapers. A more thorough understanding of interactions between polyelectrolyte networks and ionic solutes is critical as these materials are further tailored for performance applications in highly targeted ionic environments. In this work, we seek to develop structure-property relationships between polyelectrolyte gels and environments containing high concentrations of multivalent ions. Specifically, this work seeks to elucidate the causes behind differences in hydrogel response to divalent ions of main group metals versus transition metals. PANa-co-PAM hydrogels containing low and high fractions of ionic groups are investigated in solutions of DI water, NaCl, CaCl2, and CuSO4 at concentrations ranging from 5 to 100 mM in order to understand 1) the transient or permanent nature of crosslinks produced in these networks by divalent counter-ions, 2) the role of polymer ionic content in these interactions, and 3) how these interactions scale with salt concentration. Gravimetric swelling and mechanical compression testing are employed to characterize water and salt-swollen hydrogels in order to develop guiding principles to control and manipulate material properties through polymer-counter-ion interactions. The work presented here confirms the formation of permanent crosslinks by transition metal ions, offers explanation for the behavioral discrepancy observed between ionic hydrogels and main group versus transition metal ions, and illustrates how such hydrogel properties scale with counter-ion concentration.


Soft Matter ◽  
2009 ◽  
Vol 5 (21) ◽  
pp. 4212 ◽  
Author(s):  
Daniel Kopetzki ◽  
Youlia Michina ◽  
Thomas Gustavsson ◽  
David Carrière

1987 ◽  
Vol 36 (1) ◽  
pp. 38-41
Author(s):  
Osamu OKUMURA ◽  
Hirofumi KANAO ◽  
Shigeru YANABA ◽  
Kentaro KIYAMA

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