Study on Urea-Formaldehyde Prepolymer and Hot-Press Treatment of Italian Poplar Wood

2012 ◽  
Vol 62 (5) ◽  
pp. 406-411
Author(s):  
Guofeng Wu ◽  
Yifei Jiang ◽  
Ping Qu ◽  
Shuping Song ◽  
Junwen Pu
2010 ◽  
Vol 129-131 ◽  
pp. 46-49 ◽  
Author(s):  
Guo Feng Wu ◽  
Yi Fei Jiang ◽  
Hao Zhang ◽  
Bin Wang ◽  
He Yu Chen ◽  
...  

The objective of this study was to determine the chemical and physical changes of chemical modified on poplar wood. The chemical modifier was impregnated into cell lumen space by pulse-dipping machine to improve the dimension stability and mechanical property of timber. The timbers were compressed and dried by the multilayer hot-press drying to produce the modified timber. The modified timber had better dimension stability than the natural wood when they were immerged water continuous eight-hour. Characteristics of Fourier Transform Infrared Spectroscopy (FTIR) for modified were studied by the FTIR spectrometer. The intensity of hydroxyl absorption peak in the infrared absorption spectrogram decreased significantly, and that of carbonyl decreased lightly, which due to the bond of the function groups of -NHCH2OH of urea-formaldehyde prepolymer react with the wood carboxyl (C=O) and hydroxyl(-OH). The morphologic models of chemical within wood were discovered by SEM.


2011 ◽  
Vol 121-126 ◽  
pp. 493-498 ◽  
Author(s):  
Huei Ruey Ong ◽  
Reddy Prasad ◽  
Md. Maksudur Rahman Khan ◽  
Md. Najmul Kabir Chowdhury

Increased demand for wood adhesives, environmental concerns, and the uncertainty of continuing availability of petrochemicals have led to recent attention on protein-based adhesives. This study was conducted to investigate the physico-chemical interaction of palm kernel meal (PKM) with melamine urea formaldehyde (MUF) resins in adhesive formulation by using Fourier Transform Infrared (FTIR) Spectroscopy. The effect of hot press on PKM extender has been investigated by FTIR and blue shift is observed due to the hot press indicating that the functional groups (such as C=O, -OH and NH) are become more free in the samples. In the case of PKM-MUF blend bonding interactions observed where, PKM played the role as an extender. Red shift of C=O and N-H groups stretching in PKM-MUF-Wood blend is observed which suggests the interaction of these functional groups through hydrogen bonding. The results suggest that PKM extender-based MUF adhesive resins have potential application for the production of exterior plywood.


BioResources ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. 3718-3733
Author(s):  
Osman Camlibel

Physical, mechanical, and formaldehyde emission properties were studied for medium density fiberboard (MDF) produced with oak (75%) and pine (25%) fibers that had been mechanically refined in the presence of calcite particles. The calcite slurry was prepared at two levels of solids, 1.5% and 3% (10 and 20 kg·m-³). Chips were cooked for 4 min at 185 °C, under 8 bar vapor pressure in an Andritz defibrillator. 1.8% liquid paraffin, 0.72% ammonium sulphate solution, and 11% urea-formaldehyde were added by percentage based on oven-dried wood fibers in the blowline at the exit of the defibrator. The fibers were dried to 11% moisture content. MDF boards (2100 mm × 2800 mm × 18 mm) were created using a continuous hot-press process. The addition of calcite in the course of MDF production resulted in improved physical properties, such as thickness swelling (ThS 24 hours) and water absorption (WA 24 hours). MDF boards prepared with calcite exhibited higher internal bond (IB), modulus of rupture (MOR), and modulus of elasticity (MOE). Resistance to axial withdrawal of screw also was increased by addition of 3% calcite. In addition, the lowest levels of formaldehyde emission were observed for MDF prepared with calcite at the 3% level.


2015 ◽  
Vol 5 (4) ◽  
pp. 152-161
Author(s):  
Кантиева ◽  
Ekaterina Kantieva ◽  
Разиньков ◽  
Egor Razinkov ◽  
Сладких ◽  
...  

One of the main objectives of the enterprises for production of furniture is decrease in a material capacity of production and as a result decrease in its prime cost. Producers of kitchen table-tops for this purpose pass to production of table-tops of the combined design, replacing thick wood-shaving plates 25, 38 mm thick, with thinner 16 mm.For maintenance of more massive appearance of such table-tops to thin wood chipboard in the longitudinal direction at the edges of a board paste longitudinal strips from chipboard. The economy of material can lead to a deflection, the received table-tops. In this work the deflection of table-tops of the combined design was investigated. For studying of the reasons of emergence of a deflection and ways of its decrease the samples received in laboratory and working conditions were investigated. For pasting of boards from chipboard the paper and layered plastic used glue on the basis of polyvinyl acetate dispersion and the combined glue with various ratio of urea-formaldehyde resinand polyvinyl acetate dispersion. At the first stage defined a deflection of not revertedwood-shaving plates. Then controlled change of a deflection after gluing of plastic, paper from the back (and, paper and plastic made a veneering consistently and at the same time), after gluing of levels from chipboard. The deflection was defined in various directions of a furniture board in dynamics. Determined durability of gluing of plastic by above-mentioned glues. As a result of work it is established that the veneering of the front and reverse parties of plates in a hot press needs to be made at the same time. By production of the combined design of table-tops it is more expedient to use pure polyvinyl acetate dispersion. Durability on a plastic separation from wood-shaving plates is higher when using of the mixed glue on the basis of polyvinyl acetate dispersion and urea-formaldehyde resin.


2012 ◽  
Vol 200 ◽  
pp. 335-338 ◽  
Author(s):  
Peng Luo ◽  
Chuan Min Yang ◽  
Hong Wei Ji

The goal of this work was to make particleboards for manufacturing pallets from wheat straw using low cost urea formaldehyde (UF) resin adhesive. The wheat straws were subject to steam explosion pretreatment to improve bondability with UF resin. Particleboards were obtained from the steam explosion pretreated wheat straws with UF resin. Particleboard manufacturing parameters, such as pressing time, temperature and board density, were optimized to achieve high performance panel board for pallets. The optimum parameters were found to be: hot press temperature 170 °C, hot press time 40 s/mm, resin application ratio 10%, and straw particle size 12 mm. Under the optimum conditions particleboards met the mechanical requirements for the industrial use particleboards based on the Chinese National Standard for Particleboard and were able to make pallets.


2013 ◽  
Vol 701 ◽  
pp. 53-58 ◽  
Author(s):  
Elammaran Jayamani ◽  
Sinin Hamdan

In this Investigation, the influence of two kind of polymers (Urea-formaldehyde and Polypropylene) mixed with natural fibre (Kenaf) were studied for their sound absorption coefficients. Four samples were made; Samples A1 and A2 are made of Kenaf core fibre with adhesive of high emission Urea-formaldehyde resin (HN 100) with 51.6 % solid content. The fabrication of the particle board was done using a hot press for 6 minutes under the pressure of 40 Ton at 180°C for different fibre lengths 1 mm (Sample A1) and 0.6 mm (Sample A2) with weight fraction of 80%. Sample B1 and B2 are made of Kenaf core fibre with polypropylene matrix materials with coupling agent of polyvinyl alcohol. The fabrication of the sample was done using hot press for 30 minutes under the pressure of 1000 Psi at 180°C for different lengths of 1 mm (Sample B1) and 0.6 mm (Sample B2) with weight fraction of 20%. The sound absorption coefficients of samples were measured according to American society for Testing Materials (ASTM E1050 10) two microphone method. It is evident that type of polymer influences the sound absorption coefficients.


2011 ◽  
Vol 181-182 ◽  
pp. 287-292 ◽  
Author(s):  
Zhen Zhong Gao ◽  
Feng Liao

The phenol-melamine-urea-formaldehyde (PMUF) cocondensed resin adhesive was prepared by using phenol, urea, melamine and formaldehyde as reactants. It was characterized by 13C NMR and the results indicated that the PMUF could reduce the content of free formaldehyde, and it could make wood-based panel with high water resistance and weatherability. Sodium carbonate (Na2CO3) was able to shorten the curing time by 40% when applied to the plywood process. The addition of Na2CO3 as the curing accelerator of a PMUF had little influence on the bonding strength of waterproof layer and could shorten the hot-press time.


2011 ◽  
Vol 675-677 ◽  
pp. 411-414
Author(s):  
Guo Feng Wu ◽  
Yi Fei Jiang ◽  
Ping Qu ◽  
Sheng Yao ◽  
Jun Wen Pu

In this research, the urea-formaldehyde prepolymer and multilayer hot-press drying was used to obtain modified wood. The timbers were compressed and dried by the multilayer hot-press drying kiln. The combination of chemical modification and hot-press drying can improve the drying rate, which can also enhanced the physical and mechanical properties. Based on the findings, the basic density of modified wood improved 25.2 %, the bending strength and the bend elastic modulus improved 15.6 % and 25.0 % respectively. The dimensional stability of the treatment appeared to be slightly higher than that of untreated samples under the same conditions for processing temperatures and times. The improving dimensional stability of wood mainly was attributed to the prepolymer that changes wood cell wall components such as the degradation of the hemicelluloses and cellulose during hot-press drying treatment. The XRD results indicated that the degree of crystallinity increased to 35.45 %from 31.25 %. The TGA results show that the degradation of the samples can be divided into two step, both of the maximum weight loss velocity temperature of the two step increased to 266 °C, 355 °C from 244 °C and 341 °C.


2021 ◽  
Vol 5 (1) ◽  
pp. 21
Author(s):  
Nanda Putri Afrilda ◽  
Ety Jumiati ◽  
Abdul Halim Daulay

This test was carried out to reduce waste in coconut empty fruit bunches and to determine the characteristics and microstructure of the particle board surface.  The samples used consisted of bamboo powder and oil palm empty fruit bunches with gambier adhesive and urea formaldehyde with variations including: 10%:75%:15%:11%;  20%:65%:15%:11%, 30%:55%:15%:11%, 40%:45%:10%:11%.  The particleboard was printed and pressurized using a hot press of 16kg/cm2 for 15 minutes at a temperature of 120 oC, with a drying time of 14 days.  The test parameters include: density, moisture content, thickness expansion, and microstructural analysis using SEM (Scanning Electron Microscopy) which refers to SNI 03-2105-2006.  The characterization of particleboard produced in the density test is 0.66-0.74 g/cm3, the water content value is 2.4-6.9%, the thickness expansion value is 7.2-12%.  Based on the percentage value of the density of the resulting particleboard is a medium density particleboard.


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