Simultaneous Two-Dimensional Visualization of Soot and OH in Flames Using Laser-Induced Fluorescence

1996 ◽  
Vol 50 (9) ◽  
pp. 1182-1186 ◽  
Author(s):  
Per-Erik Bengtsson
Keyword(s):  
Laser Radiation ◽  
Detection System ◽  
Frequency Doubling ◽  
Ccd Camera ◽  
Laser Induced Fluorescence ◽  
Oh Radicals ◽  
Single Shot ◽  
Two Dimensional ◽  
Charge Coupled Device ◽  
Reaction Zones

Two-dimensional visualization of soot has been realized in flames with the use of laser-induced fluorescence in C2 from laser-vaporized soot [LIF(C2)LVS]. Soot particles are heated to vaporization temperatures by the absorption of laser radiation. C2 radicals produced by this process are excited at wavelengths around 563 nm through the transition v’ = 0 d3Πg ← v” = 1 a3Πu, and the subsequent fluorescence at ∼516 nm is detected. By frequency-doubling of the laser radiation, wavelengths around 281.5 nm are achieved, which can excite OH radicals to the v’ = 1 A2∑+ state from v” = 0 X2Π, with subsequent fluorescence at ∼310 nm. With the use of both these excitation wavelengths, and a Cassegrainian split-mirror telescope as the imaging detection system in front of the charge-coupled device (CCD) camera, simultaneous two-dimensional single-shot images of soot and OH were obtained on a single CCD chip, thus enabling both sooting regions and reaction zones in flames to be monitored.

scholarly journals X-rays only when you want them: optimized pump–probe experiments using pseudo-single-bunch operation

2015 ◽  
Vol 22 (3) ◽  
pp. 729-735 ◽  
Author(s):  
M. P. Hertlein ◽  
A. Scholl ◽  
A. A. Cordones ◽  
J. H. Lee ◽  
K. Engelhorn ◽  
...  
Keyword(s):  
Laser Excitation ◽  
Ccd Camera ◽  
Single Shot ◽  
X Rays ◽  
Time Resolved ◽  
Pump Probe ◽  
Charge Coupled Device ◽  
X Ray ◽  
X Ray Absorption ◽  
Sample Damage

Laser pump–X-ray probe experiments require control over the X-ray pulse pattern and timing. Here, the first use of pseudo-single-bunch mode at the Advanced Light Source in picosecond time-resolved X-ray absorption experiments on solutions and solids is reported. In this mode the X-ray repetition rate is fully adjustable from single shot to 500 kHz, allowing it to be matched to typical laser excitation pulse rates. Suppressing undesired X-ray pulses considerably reduces detector noise and improves signal to noise in time-resolved experiments. In addition, dose-induced sample damage is considerably reduced, easing experimental setup and allowing the investigation of less robust samples. Single-shot X-ray exposures of a streak camera detector using a conventional non-gated charge-coupled device (CCD) camera are also demonstrated.

Single-Shot Multiwavelength Imaging of Laser Plumes

1998 ◽  
Vol 52 (2) ◽  
pp. 179-186 ◽  
Author(s):  
Matthew P. Nelson ◽  
Wendy C. Bell ◽  
Michael L. McLester ◽  
M. L. Myrick
Keyword(s):  
Fiber Optics ◽  
Optical Fibers ◽  
Ccd Camera ◽  
Chemical Imaging ◽  
Single Shot ◽  
Charge Coupled Device ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Optic Array ◽  
A Charge

A novel optical approach to single-shot chemical imaging with high spectroscopic resolution is described with the use of a prototype dimension-reduction fiber-optic array. Images are focused onto a 30 × 20 array of hexagonally packed 250 μm o.d. f/2 optical fibers that are drawn into a 600 × 1 distal array with specific ordering. The 600 × 1 side of the array is imaged with an f/2 spectrograph equipped with a holographic grating and a charge-coupled device (CCD) camera for spectral analysis. Software is used to extract the spatial/spectral information contained in the CCD images and de-convolute them into wavelength-specific reconstructed images or position-specific spectra that span a 190 nm wavelength space. “White light” zero-order images and first-order spectroscopic images of laser plumes have been reconstructed to illustrate proof-of-principle. Index Headings: Fiber optics; Chemical imaging; Spectroscopic imaging; Charged-coupled device (CCD); Laser-induced breakdown spectroscopy (LIBS).

Profiling of Redox Atmosphere in Flames by Chemical Seeding/Planar Laser-Induced Fluorescence (CS/PLIF)

2005 ◽  
Vol 128 (4) ◽  
pp. 765-772 ◽  
Author(s):  
K. Kitagawa ◽  
S. Itoh ◽  
N. Arai ◽  
Ashwani K. Gupta
Keyword(s):  
Rotational Temperature ◽  
Thermal Dissociation ◽  
Flame Temperature ◽  
Ccd Camera ◽  
Laser Induced Fluorescence ◽  
Charge Coupled Device ◽  
Planar Laser ◽  
A Charge ◽  
Local Value ◽  
Redox Index

Knowledge on the local value of reducing and oxidizing (redox) atmospheres in flames is among the most important issues to be desired by combustion engineers. In this study, the spatial distribution of a redox atmosphere in flames has been measured experimentally by the chemical seeding/laser-induced fluorescence (CS/LIF) technique. A solution of iron was sprayed into a premixed propane-air flame supported on a slot burner. The LIF intensity of FeO band was compared to that of a Fe line to estimate the experimentally determined degree of atomization in the reaction FeO→Fe+O. The flame temperature profile was determined as a rotational temperature and was obtained by comparing the LIF (laser-induced fluorescence) intensities of OH rotational lines. The degree of atomization was theoretically calculated on the basis that simple thermal dissociation takes place in the reaction. The redox atmosphere, or a redox index, is defined as the ratio of the experimentally determined to theoretically calculated degrees of atomization. Two-dimensional distributions or profiles of the excitation temperature, experimentally determined degree of atomization, and redox index have been measured using a charge coupled device (CCD) camera fitted with an optical bandpass filter and the associated signal processing using a computer. This method has been successfully applied to quantitatively illustrate the local atmosphere and profile of the redox atmosphere in flames.

Detection of Hydrogen Peroxide Using Photofragmentation Laser-Induced Fluorescence

2008 ◽  
Vol 62 (1) ◽  
pp. 66-72 ◽  
Author(s):  
O. Johansson ◽  
J. Bood ◽  
M. Aldén ◽  
U. Lindblad
Keyword(s):  
Hydrogen Peroxide ◽  
Detection Limit ◽  
Signal Strength ◽  
Measurement Procedure ◽  
Laser Induced Fluorescence ◽  
Excitation Pulse ◽  
Oh Radicals ◽  
Single Shot ◽  
First Time ◽  
Hydrogen Peroxide Vapor

Photofragmentation laser-induced fluorescence (PF-LIF) is for the first time demonstrated to be a practical diagnostic tool for detection of hydrogen peroxide. Point measurements as well as two-dimensional (2D) measurements in free-flows, with nitrogen as bath gas, are reported. The present application of the PF-LIF technique involves one laser, emitting radiation of 266 nm wavelength, to dissociate hydrogen peroxide molecules into OH radicals, and another laser, emitting at 282.25 nm, to electronically excite OH, whose laser-induced fluorescence is detected. The measurement procedure is explained in detail and a suitable time separation between photolysis and excitation pulse is proposed to be on the order of a few hundred nanoseconds. With a separation time in that regime, recorded OH excitation scans were found to be thermal and the signal was close to maximum. The PF-LIF signal strength was shown to follow the same trend as the vapor pressure corresponding to the hydrogen peroxide liquid concentration. Thus, the PF-LIF signal appeared to increase linearly with hydrogen peroxide vapor-phase concentration. For 2D single shot measurements, a conservatively estimated value of the detection limit is 30 ppm. Experiments verified that for averaged point measurements the detection limit was well below 30 ppm.

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