scholarly journals Newly Synthesized N-Substituted Thiosemicarbazone as a Potential Corrosion Inhibitor for Mild Steel in 1 M HCl

2019 ◽  
Vol 7 (4.14) ◽  
pp. 168
Author(s):  
N Z. Nor Hashim ◽  
K Kassim ◽  
F H. Zaidon
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Langmuir Adsorption ◽  
Before And After ◽  
Ft Ir ◽  
L1 And L2

Two N-substituted thiosemicarbazone derivatives namely as 2-(4-chlorobenzylidene)-N-phenylhydrazinecarbothioamide and 2-benzylidene-N-phenylhydrazinecarbothioamide (L1 and L2, respectively) have been tested as corrosion inhibitors on mild steel in 1 M HCl. The ligands were synthesized and investigated using potentiodynamic polarization (PD) and electrochemical impedance spectroscopy (EIS).  The obtained results indicated that inhibition efficiency, (IE, %) L1 increased with increasing inhibitor concentrations which behaved as a good corrosion inhibitor compared to L2. The synthesized ligands were successfully characterized by melting point, elemental analysis (C, H, N, and S), Fourier-transform infrared spectroscopy (FT-IR) and NMR (1H and 13C) spectroscopy. The excellent inhibition effectiveness for both compounds on mild steel before and after immersion in 1 M HCl solution containing 40 ppm of L1 and L2 were also verified by scanning electron microscope (SEM). Based on potentiodynamic polarization results, it can be concluded that all investigated compounds are mixed-type inhibitors and obey the Langmuir adsorption isotherm. 

scholarly journals Effect of N-(6-aminobenzo[d]thiazol-2-yl)benzamide and 2,6-diamino-benzothiazole as Corrosion Inhibitor in acid medium

2016 ◽  
Vol 12 (12) ◽  
pp. 4593-4613
Author(s):  
Rekha. S ◽  
Kannan. K ◽  
Gnanavel. S
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Acid Medium ◽  
Potentiodynamic Polarization ◽  
Inhibition Efficiency ◽  
Free Energy Of Adsorption ◽  
Weight Loss Method ◽  
Ft Ir ◽  
Loss Method

2-amino-6-nitrobenzothiazole(ANBT) was used as an inhibitor for the corrosion of mild steel in acid medium since the inhibition efficiency was low for that compound, 2,6-diaminobenzothiazole (DABT) and N-(6-aminobenzo [d] thiazol-2-y1) benzamide(ABTB) was synthesized,  and characterized by FT-IR, H1NMR, and C13NMR.The synthesized compound was tested as a corrosion inhibitor for mild steel in 1N HCl solution using weight loss, Potentiodynamic polarization, and AC impedance techniques. The inhibition efficiency was studied at the different time, temperature and acid concentration by weight loss method. The values of activation energy and free energy of adsorption of these compounds were also calculated, which reveals that the inhibitor was adsorbed on the mild steel by physisorption mechanism. Adsorption obeys Langmuir and Temkin adsorption isotherms. The results obtained by weight loss method revealed that the compound performed as a better inhibitor for mild steel in 1N HCl. Potentiodynamic polarization studies showed that the inhibitor acts as a mixed type inhibitor.AC impedance studies revealed that the corrosion process was controlled by charge transfer process. Surface analysis was studied using SEM and FT-IR.

scholarly journals Isomers of Poly Aminophenol: Chemical Synthesis, Characterization, and Its Corrosion Protection Aspect on Mild Steel in 1 M HCl

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
G. Thenmozhi ◽  
P. Arockiasamy ◽  
R. Jaya Santhi
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Ammonium Persulfate ◽  
Inhibition Effect ◽  
Maximum Inhibition ◽  
Ft Ir ◽  
Polarization Studies

The oxidative chemical polymerizations of three isomers of aminophenol,ortho,meta, andpara(PoAP, PmAP, and PpAP), were performed in aqueous HCl using ammonium persulfate as an oxidant at 0–3°C. The synthesized polymers were characterized by employing elemental analysis, GPC, UV-VIS-NIR, FT-IR, XRD, and TGA. The corrosion inhibition effect of these three polymers on mild steel in 1 M HCl solution was studied by using electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy. These measurements reveal that the inhibition efficiency obtained by these polymers increased by increasing their concentration. The inhibition efficiency follows the order PpAP > PoAP > PmAP. The results further revealed that PpAP at a concentration of 250 mg/L furnishes maximum inhibition efficiency (96.5%). Polarization studies indicated that these three polymers act as the mixed type corrosion inhibitors.

OAT EXTRACT AS A NATURAL CORROSION INHIBITOR FOR MILD STEEL IN 3% NaCl SOLUTION

2021 ◽  
pp. 2150084
Author(s):  
A. ZAABAR ◽  
R. AITOUT ◽  
D. AMOURA ◽  
R. MAIZIA ◽  
D. AIT ABDESSELAM ◽  
...  
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Surface Condition ◽  
Sem Analysis ◽  
Environmental Legislation ◽  
Polarization Data ◽  
Langmuir Adsorption ◽  
Natural Corrosion

In this work, we have tested a new inhibitor formulation that is effective, economically efficient and in accordance with environmental legislation. The inhibitor tested is the crude extract of the oat plant (denoted as OE) obtained by the reflux method in the water. This extract is then used as a corrosion inhibitor of mild steel in 3% NaCl. This study was carried out by using electrochemical polarizations, Electrochemical Impedance Spectroscopy and gravimetric techniques. The results obtained showed that this extract satisfactorily inhibits the dissolution rate of mild steel. The inhibition efficiency increases with inhibitor concentration and reaches 72% at 5[Formula: see text]g[Formula: see text][Formula: see text][Formula: see text]L[Formula: see text] of oat extract. Polarization data indicate that the extract acted as mixed type. The adsorption of the inhibitor on the mild steel surface in 3% NaCl follows the Langmuir adsorption isotherm. SEM analysis of the electrode surface condition confirms the results obtained.

scholarly journals Experimental, DFT and MD Assessments of Bark Extract of Tamarix aphylla as Corrosion Inhibitor for Carbon Steel Used in Desalination Plants

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3679
Author(s):  
Ismat H. Ali
Keyword(s):  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Effect Of Temperature ◽  
Bark Extract ◽  
Plant Sample ◽  
Gravimetric Analysis ◽  
Sample Collection ◽  
Eis Measurements

This study aimed to examine the extract of barks of Tamarix aphylla as a corrosion inhibitor. The methodology briefly includes plant sample collection, extraction of the corrosion inhibitor, gravimetric analysis, plotting potentiodynamic polarization plots, electrochemical impedance spectroscopic measurements, optimization of conditions, and preparation of the inhibitor products. The results show that the values of inhibition efficiency (IE%) increased as the concentrations of the inhibitor increased, with a maximum achievable inhibition efficiency of 85.0%. Potentiodynamic polarization (PP) tests revealed that the extract acts as a dual-type inhibitor. The results obtained from electrochemical impedance spectroscopy (EIS) measurements indicate an increase in polarisation resistance, confirming the inhibitive capacity of the tested inhibitor. The adsorption of the inhibitor on the steel surface follows the Langmuir adsorption isotherm model and involves competitive physio-sorption and chemisorption mechanisms. The EIS technique was utilized to investigate the effect of temperature on corrosion inhibition within the 298–328 K temperature range. Results confirm that the inhibition efficiency (IE%) of the inhibitor decreased slightly as the temperature increased. Lastly, the thermodynamic parameters for the inhibitor were calculated.

scholarly journals Calcium D-Pantothenate as Green Corrosion Inhibitor on Mild Steel in 240 ppm NaCl Solution

2019 ◽  
Vol 9 (2S2) ◽  
pp. 435-442
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Density Functional ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Nacl Solution ◽  
Functional Theory ◽  
Vitamin B5 ◽  
Quantum Chemical Data

Corrosion inhibition of mild steel in 240 ppm NaCl solution using Calcium D-Pantothenate (Vitamin B5 ) as corrosion inhibitor is studied using electrochemical impedance, potentiodynamic polarization and weight loss studies. From the potentiodynamic polarization studies, icorr (corrosion current density) decreases with increasing the concentration of vitamin B5 (VB5 ). The CR (corrosion rate) decreases and the IE (inhibition efficiency) of VB5 increases on increasing the concentration of VB5 .Surface investigation using SEM, EDX spectra, UV-Vis, FTIR, electrochemical impedance, potentiodynamic polarization and adsorption isotherm parameter of VB5 in 240 ppm NaCl solution shows that VB5 can act asworthy corrosion inhibitors. Quantum chemical data obtained from density functional theory (DFT) calculations also agreed with the experimental outcomes.

scholarly journals Inhibition Effect of Miconazole Nitrate on the Corrosion of Mild Steel in Hydrochloric Acid Medium

2011 ◽  
Vol 2011 ◽  
pp. 1-8 ◽  
Author(s):  
J. Ishwara Bhat ◽  
Vijaya D. P. Alva
Keyword(s):  
Hydrochloric Acid ◽  
Mild Steel ◽  
Acid Medium ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Inhibitor Molecule ◽  
Langmuir Adsorption ◽  
Hydrochloric Acid Medium ◽  
Miconazole Nitrate ◽  
Impedance Spectroscopy Technique

The corrosion inhibition of mild steel by miconazole nitrate, an antifungal drug has been investigated using potentiodynamic polarization, electrochemical impedance spectroscopy technique, and weight loss methods. The experimental results suggested miconazole nitrate is a good corrosion inhibitor for mild steel in 1 M hydrochloric acid medium. The inhibition efficiency increased with increase in inhibitor concentration. The thermodynamic parameters were determined and discussed. The inhibition was assumed to occur via adsorption of the inhibitor molecule on the surface of mild steel following Langmuir adsorption isotherm.

Electrochemical behaviour of acetyl G as corrosion inhibitor for mild steel in acid medium

2015 ◽  
Vol 44 (6) ◽  
pp. 371-378 ◽  
Author(s):  
Y. Sangeetha ◽  
S. Meenakshi ◽  
C. Sairam Sundaram
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Acid Medium ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Behaviour ◽  
Green Inhibitor ◽  
Content Type ◽  
Mild Steel Surface

Purpose – The purpose of this paper is to develop an eco-friendly corrosion inhibitor for mild steel in 1 M HCl. Design/methodology/approach – A pharmaceutical drug acetyl G was investigated for its corrosion inhibition efficiency using weight loss method, potentiodynamic polarisation and electrochemical impedance spectroscopy. Findings – The inhibition efficiency increased with increase in inhibitor concentration. Results from polarisation studies revealed mixed type of inhibition. Impedance studies, scanning electron microscopy and Fourier transform spectroscopy confirm the adsorption of inhibitor on the mild steel surface. Research limitations/implications – The drug acetyl G has sulphur and nitrogen atoms which effectively block the corrosion of mild steel and is non-toxic and has good inhibition efficiency. Practical implications – This method provides an excellent, non-toxic and cost-effective material as a corrosion inhibitor for mild steel in acid medium. Originality/value – Application of this drug as a corrosion inhibitor has not been reported yet in the literature. Replacing the organic inhibitors, this green inhibitor shows excellent inhibition efficiency. This is adsorbed excellently on the mild steel surface due to the presence of long chain and hetero atoms. Thus, the drug retards the corrosion reaction.

N-cetyl-N,N,N trimethyl ammonium bromide (CTAB)-stabilized polyaniline: a corrosion inhibitor for mild steel

2018 ◽  
Vol 65 (2) ◽  
pp. 146-151 ◽  
Author(s):  
Mohd Rashid ◽  
Umesh S. Waware ◽  
Afidah A. Rahim ◽  
A.M.S. Hamouda
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Potentiodynamic Polarization ◽  
Acidic Medium ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
High Dispersion ◽  
Ammonium Bromide ◽  
Content Type

Purpose The purpose of this study is to compare the inhibitive effect of polyaniline (PAni) and N-cetyl-N,N,N trimethyl ammonium bromide (CTAB)-stabilized PAni in a hydrochloric acid (HCl) medium. Design/methodology/approach PAni has been deposited potentiodynamically on mild steel in the presence of CTAB as a stabilizing agent to achieve high corrosion inhibition performance by the polymer deposition. The corrosion inhibition studies of CTAB-stabilized PAni inhibitor in 0.1 M HCl acidic solution was carried out by electrochemical methods, namely, open-circuit potential, potentiodynamic polarization and electrochemical impedance spectroscopy technique. Findings The results of electrochemical studies have shown that the CTAB-stabilized PAni inhibitor has higher corrosion efficiency than PAni on mild steel in 0.1 M HCl solution. The maximum per cent efficiency evaluated using the potentiodynamic polarization method is approximately 91.9. Originality/value CTAB-stabilized PAni has never been studied as a corrosion inhibitor for mild steel in an acidic medium. The investigations demonstrate relatively the better corrosion inhibition efficiency and high dispersion of the polymer in the acidic medium.

scholarly journals Inhibition of Pipeline Steel Corrosion in 0.5 M H2SO4 Using Cotyledon of Chrysophyllum Albidum

2020 ◽  
Vol 24 (4) ◽  
pp. 691-697
Author(s):  
E.P. Othaki ◽  
N.C. Ngobiri
Keyword(s):  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Adsorption Process ◽  
Pipeline Steel ◽  
Steel Corrosion ◽  
Langmuir Adsorption ◽  
Extract Concentration ◽  
Ir Studies ◽  
Ft Ir ◽  
As Adsorption

The corrosion inhibition characteristics of Chrysophyllum albidum cotyledon extract was studied as a green and sustainable corrosion inhibitors for pipeline steel in acidic environment attemperatures, 303,313 and 323K using gravimetric technique.The results obtained showed that the inhibition efficiency increased with increase in extract concentration but decrease with increase in temperature. The extract attained an inhibition efficiency of 94 % with 5 g/L at 303 K and 52.2 % with 1 g/L at 333K. Also increase in concentration of the extract lead to increase in activation energydepicting an exothermic process.Fourier transform infrared spectroscopy (FT-IR) studies showed the mode of inhibition as adsorption of phytochemicals from the extract on pipeline steel surface. Langmuir adsorption isotherm best fitted into the adsorption process which is spontaneous and physical. Keywords: Chrysophyllum albidum, Pipeline steel, Inhibition, Adsorption.

Experimental Investigation of a New Derived Oleochemical Corrosion Inhibitor

2019 ◽  
Vol 796 ◽  
pp. 112-120
Author(s):  
Mysara Eissa Mohyaldinn ◽  
Wai Lin ◽  
Ola Gawi ◽  
Mokhtar Che Ismail ◽  
Quosay A. Ahmed ◽  
...  
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Dynamic Condition ◽  
Methyl Esters ◽  
Static Condition ◽  
Chemical Corrosion ◽  
Boron Fluoride

Most of the corrosion inhibitors that are used in industry contain chemicals that are harmful to health and environment. Corrosion inhibitors derived from green sources are, therefore, believed to be a good option for replacing the chemical corrosion inhibitors. In this work, a green oleochemical corrosion inhibitor derived from Jatropha Curcas is introduced. The paper discusses the methodology of deriving the corrosion inhibitor as well as the experimental test conducted for evaluating its corrosion inhibition efficiency. The new oleochemical corrosion inhibitor was derived via two reactions. Jatropha oil was firstly saponified with sodium hydroxide to yield gras acid and glycerol, which was then esterified with boron fluoride in presence of excess methanol to produce the oil methyl esters, which is used as oleo-chemical corrosion inhibitor. To evaluate the oleo-chemical corrosion inhibitor, the corrosion rate of mild steel in NaCl corrosive medium with CO2 is tested at static condition and two dynamic conditions, namely 500 and 1500 rpm. This is to simulate the transitional and turbulent flow in a pipeline. At each dynamic condition, the proposed corrosion inhibitor was tested at concentration dosages of 0, 50, 100, and 150 ppm. The experiments results revealed a good performance of the new oleochemical corrosion inhibitor. The inhibition efficiency was found to be highly affected by the concentration of corrosion inhibitor. Total corrosion inhibition of the mild steel was noticed by using 150 ppm at dynamic condition of 500 rpm.

Sign in / Sign up

Export Citation Format

Share Document