Opportunities and challenges for combining electro- and organometallic catalysis in C(sp2)-H phosphonation

The chemistry of organoelemental compounds including carbon-phosphorus derivatives is now one of the most rapidly developing fields of research, regarding both fundamental science and solution of applied problems. Extensive opportunities for the synthesis of organophosphorus compounds are opened up by the use of unconventional methods, first of all, electrochemical ones, which combine the benefits of usual homogeneous chemistry in solution and electrochemistry, where reactants are generated at the electrodes directly in the reaction system. The interest in the organic electrosynthesis is caused by several factors, including mild conditions (room temperature, atmospheric pressure), the possibility of conducting reactions in a closed system with a low concentration of the catalyst, which is readily regenerated. This mini-review generalizes the achievements in the field of development of new electrochemical, efficient and atom-economical, catalytic methods for the formation of aromatic carbon – phosphorus bonds and some historical background of these approaches.