Synthesis, Properties and Dimerization Study of Isocyanic Acid

2002 ◽  
Vol 57 (1) ◽  
pp. 19-24 ◽  
Author(s):  
Gerd Fischer ◽  
Janna Geith ◽  
Thomas M. Klapötke ◽  
Burkhard Krumm
Keyword(s):  
Mass Spectrometry ◽  
Thermal Stability ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Oxalic Acid ◽  
Gas Phase ◽  
Isocyanic Acid ◽  
Synthesis Properties ◽  
Phase Liquid ◽  
Thermal Stability Of

Isocyanic acid was prepared in pure form by reaction of KOCN or NaOCN with stearic or oxalic acid in good yield. Identification, characterization and investigation of the thermal stability of HNCO and evidence for a possible existence of “dicyanic acid” have been studied in gas phase, liquid and solid state by vibrational and NMR spectroscopy and mass spectrometry.

Preparation and Pyrolysis of Stereoisomeric Bromobicyclo[n.1.0]alkanes ( n = 6, 8 , 10)

1987 ◽  
Vol 42 (4) ◽  
pp. 489-494 ◽  
Author(s):  
Eckehard V. Dehmlow ◽  
Roland Kramer
Keyword(s):  
Thermal Stability ◽  
Gas Phase ◽  
Condensed Phase ◽  
Secondary Products ◽  
Gas Phase Reactions ◽  
Stereoselective Reduction ◽  
Derivatives Of ◽  
Thermal Stability Of

Abstract The title compounds la-3c were prepared by stereoselective reduction of the respective dibromides. Pyrolysis gave allylic bromides (8, 9, 11) as primary and dienes (10, 12) as secondary products. Product ratios were independent of the stereochemistry of the starting materials. No differences of the rearrangement rates of the stereoisomers were observed in gas phase reactions of the derivatives of bicyclo[6.1.0]- and bicyclo[8.1.0]alkanes. With the larger bicyclo[10.1.0] derivatives, however, distinct differences in the thermal stability of cis-trans-isomers4c/5c or 2c/3c were found in condensed phase.

Molecular Insights into the Thermal Stability of mAbs with Variable-Temperature Ion-Mobility Mass Spectrometry

ChemBioChem ◽  
2015 ◽  
Vol 17 (1) ◽  
pp. 46-51 ◽  
Author(s):  
Kamila J. Pacholarz ◽  
Shirley J. Peters ◽  
Rachel A. Garlish ◽  
Alistair J. Henry ◽  
Richard J. Taylor ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Thermal Stability ◽  
Ion Mobility ◽  
Variable Temperature ◽  
Ion Mobility Mass Spectrometry ◽  
Thermal Stability Of

Solid state amorphization reactions in deformed Ni-Zr multilayered composites

1990 ◽  
Vol 5 (3) ◽  
pp. 488-497 ◽  
Author(s):  
G. C. Wong ◽  
W. L. Johnson ◽  
E. J. Cotts
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Amorphous Phase ◽  
Equilibrium Phase ◽  
Solid State Reactions ◽  
Heat Of Mixing ◽  
Scanning Calorimetry ◽  
Multilayered Composites ◽  
State Amorphization ◽  
Thermal Stability Of

The mechanisms of metallic glass formation and competing crystallization processes in mechanically-deformed Ni-Zr multilayered composites have been investigated by means of differential scanning calorimetry and x-ray diffraction. Our investigation of the heat of formation of amorphous NixZr1−x alloys shows a large negative heat of mixing (on the order of 30 kJ/mole) for compositions near Zr55Ni45 with a compositional dependence qualitatively similar to that predicted by mean field theory. We find that the products of solid state reactions in composites of Ni and Zr can be better understood in terms of the equilibrium phase diagram and the thermal stability of liquid quenched metallic glasses. We have determined the composition of the growing amorphous phase at the Zr interface in these Ni-Zr diffusion couples to be 55 ± 4% Zr. We investigated the kinetics of solid state reactions competing with the solid state amorphization reaction and found the value of the activation energy of the initial crystallization and growth of the growing amorphous phase to be 2.0 ± 0.1 eV, establishing an upper limit on the thermal stability of the growing amorphous phase.

Improvement the thermal stability of bluish-cyan emitting phosphor Y2MgAl4SiO12:Eu2+ using substitution cations (Zn, Ca, Sr) for white LEDs

CrystEngComm ◽  
2021 ◽  
Author(s):  
Huifang Yang ◽  
Panlai Li ◽  
Zejun Ye ◽  
Xiaoxue Huo ◽  
Yu Wang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Solid State Method ◽  
White Leds ◽  
State Method ◽  
Thermal Stability Of

A series of bluish-cyan color adjustable phosphors Y2MgAl4SiO12:xEu2+(YMAS) and Y2(Mg1-y,My)Al4SiO12:Eu2+ (M=Zn, Ca, Sr) were synthesized by the solid-state method. The thermal stability can be improved by modifying cation, especially, the...

A furnace for in situ synchrotron Laue diffraction and its application to studies of solid-state phase transformations

1990 ◽  
Vol 23 (6) ◽  
pp. 545-549 ◽  
Author(s):  
H. L. Bhat ◽  
S. M. Clark ◽  
A. El Korashy ◽  
K. J. Roberts
Keyword(s):  
Experimental Data ◽  
Thermal Stability ◽  
Phase Transitions ◽  
Solid State ◽  
Synchrotron Radiation ◽  
Structural Phase ◽  
Structural Phase Transitions ◽  
Laue Diffraction ◽  
Thermal Stability Of

The design of a new microfurnace for use for Laue diffraction studies of solid-state transformations is described. The furnace operates in the temperature range 298–573 K with a thermal stability of about ± 0.1 K. The potential of the synchrotron-radiation Laue diffraction technique for studies of structural phase transitions is demonstrated. Experimental data on phase transitions in caesium periodate, potassium tetrachlorozincate and pentaerythritol are presented.

Study of thermal stability of CoSb3 skutterudite by Knudsen effusion mass spectrometry

Calphad ◽  
2019 ◽  
Vol 65 ◽  
pp. 1-7 ◽  
Author(s):  
Pavel Brož ◽  
František Zelenka ◽  
Zdeněk Kohoutek ◽  
Jan Vřešťál ◽  
Vít Vykoukal ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Thermal Stability ◽  
Knudsen Effusion ◽  
Knudsen Effusion Mass Spectrometry ◽  
Thermal Stability Of
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