Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic–inorganic hybrid
2015 ◽
Vol 70
(9)
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pp. 617-623
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Keyword(s):
X Ray
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AbstractA new copper(II)/lead(II) complex [(terpy)3CuPb5Br12] (1) (terpy = 2,2′:6′,2″-terpyridine) has been synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. The copper(II) and lead(II) ions in the title complex are in distorted six- (Cu(II), Pb(II)) and eight-fold (Pb(II)) coordination environments, in which the donor atoms are provided by bromide anions and nitrogen atoms of the 2,2′:6′,2″-terpyridine ligands. Complex 1 contains [(terpy)4Pb9Br20]2– building blocks. These bromoplumbate(II) clusters are connected by (terpy)2Cu2Br4 units along the crystallographic b axis and by PbBr6 units along the a axis, thereby forming an extended sheet structure.
2014 ◽
Vol 997
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pp. 260-263
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Keyword(s):
2005 ◽
Vol 66
(1)
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pp. 81-90
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1991 ◽
pp. 1-8
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