Two-Dimensional Oxides: Recent Progress in Nanosheets

2018 ◽  
Vol 233 (1) ◽  
pp. 117-165 ◽  
Author(s):  
Richard Hinterding ◽  
Armin Feldhoff

Abstract Two-dimensional (2D) materials have been widely investigated for the last few years, introducing nanosheets and ultrathin films. The often superior electrical, optical and mechanical properties in contrast to their three-dimensional (3D) bulk counterparts offer a promising field of opportunities. Especially new research fields for already existing and novel applications are opened by downsizing and improving the materials at the same time. Some of the most promising application fields are namely supercapacitors, electrochromic devices, (bio-) chemical sensors, photovoltaic devices, thermoelectrics, (photo-) catalysts and membranes. The role of oxides in this field of materials deserves a closer look due to their availability, durability and further advantages. Here, recent progress in oxidic nanosheets is highlighted and the benefit of 2D oxides for applications discussed in-depth. Therefore, different synthesis techniques and microstructures are compared more closely.

1987 ◽  
Vol 12 (3) ◽  
pp. 349-352
Author(s):  
J. ENGEL ◽  
M. SALAI ◽  
B. YAFFE ◽  
R. TADMOR

Three-dimensional computerized imaging is a new modality of radiological imaging. This new technique transforms the two-dimensional slices of bi-plane CT into a three-dimensional picture by a computer’s monitor adjusted to the system. This system enables the physician to rotate the angle of viewing of the desired region to any desired angle. Moreover, this system can delete certain features of different densities from the picture, such as silicone implants, thus improving visualization. Our preliminary results using this technique are presented. The advantages, pitfalls, and suggested future applications of this new technique in hand surgery are discussed.


2020 ◽  
Vol 22 (26) ◽  
pp. 14471-14479
Author(s):  
Kartik Sau ◽  
Tamio Ikeshoji ◽  
Supriya Roy

Influence of Ba2+ ordering on cationic diffusion: (a) three-dimensional low Li+ ion diffusion using randomly substituted Ba2+, and (b) two-dimensional layered type high Li+ ion diffusion using specifically ordered substitution of Ba2+.


1992 ◽  
Vol 17 (6) ◽  
pp. 702-702
Author(s):  
J. Engel ◽  
M. Salai ◽  
B. Yaffe ◽  
R. Tadmor

Three-dimensional computerized imaging is a new modality of radiological imaging. This new technique transforms the two-dimensional slices of bi-plane CT into a three-dimensional picture by a computer's monitor adjusted to the system. This system enables the physician to rotate the angle of viewing of the desired region to any desired angle. Moreover, this system can delete certain features of different densities from the picture, such as silicone implants, thus improving visualization. Our preliminary results using this technique are presented. The advantages, pitfalls, and suggested future applications of this new technique in hand surgery are discussed.


2000 ◽  
Vol 07 (05n06) ◽  
pp. 673-677
Author(s):  
E. LUNDGREN ◽  
M. SCHMID ◽  
G. LEONARDELLI ◽  
A. HAMMERSCHMID ◽  
B. STANKA ◽  
...  

Interlayer diffusion of Co over steps of vacancy islands on the Pt(111) surface as studied by scanning tunneling microscopy is presented. It is demonstrated that Co atoms descend Pt steps by an exchange diffusion process at the step edge with the Pt atoms. Further, the exchange diffusion process is observed to occur at the corners (kinks) of the vacancy islands. The importance of kinks concerning whether the growth mode of a heteropitaxial film is two-dimensional or three-dimensional is demonstrated for the case of thin Co films on Pt(111). We argue that the strain in the Co film is to a large extent responsible for the kink formation.


2014 ◽  
Vol 70 (5) ◽  
pp. 502-507
Author(s):  
Hong-Jie Fan ◽  
Qian-Qian Xu ◽  
Tie-Zhen Ren ◽  
Xiang-Ying Xing ◽  
Kirsten E. Christensen

Two novel polymers exhibiting metal–organic frameworks (MOFs) have been synthesized by the combination of a metal ion with a benzene-1,3,5-tricarboxylate ligand (BTC) and 1,10-phenanthroline (phen) under hydrothermal conditions. The first compound, poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4 O:O′:O′′:O′′′)(μ-hydroxido-κ2 O:O)bis(1,10-phenanthroline-κ2 N,N′)dizinc(II)] 0.32-hydrate], {[Zn2(C9H3O6)(OH)(C12H8N2)2]·0.32H2O} n , denoted Zn–MOF, forms a two-dimensional network in which a binuclear Zn2 cluster serves as a 3-connecting node; the BTC trianion also acts as a 3-connecting centre. The overall topology is that of a 63 net. The phen ligands serve as appendages to the network and interdigitate with phen ligands belonging to adjacent parallel sheets. The second compound, poly[[(μ6-benzene-1,3,5-tricarboxylato-κ7 O 1,O 1′:O 1:O 3:O 3′:O 5:O 5′)(μ3-hydroxido-κ2 O:O:O)(1,10-phenanthroline-κ2 N,N′)dimanganese(II)] 1.26-hydrate], {[Mn2(C9H3O6)(OH)(C12H8N2)]·1.26H2O} n , denoted Mn–MOF, exists as a three-dimensional network in which an Mn4 cluster serves as a 6-connecting unit, while the BTC trianion again plays the role of a 3-connecting centre. The overall topology is that of the rutile net. Phen ligands act as appendages to the network and form the `S-shaped' packing mode.


2021 ◽  
Vol 8 (12) ◽  
pp. 171
Author(s):  
Juan Manuel Monteagudo Ruiz ◽  
José Luis Zamorano Gómez

Mitral stenosis is an important cause of heart valve disease globally. Echocardiography is the main imaging modality used to diagnose and assess the severity and hemodynamic consequences of mitral stenosis as well as valve morphology. Transthoracic echocardiography (TTE) is sufficient for the management of most patients. The focus of this review is the role of current two-dimensional (2D) and three-dimensional (3D) echocardiographic imaging for the evaluation of mitral stenosis.


Author(s):  
Dmitry V. Chalikov

AbstractThe probability of extremely high waves is calculated by two methods. The first method is based on the direct numerical simulation of two-dimensional wave field using a three-dimensional nonlinear model. The second method consists in calculation of the probability of wave heights over ensemble of fields representing a superposition of linear waves with random phases and a spectrum similar to that obtained in the nonlinear model. It is shown that the integral probability of extreme waves are very close to each other in both cases. This implies that the role of nonlinearity in the generation of extreme waves is probably not so important as it was assumed in most papers considering this phenomenon.


Author(s):  
Barbara E. Barich

This chapter discusses the collection of objects, in clay and stone, from various pastoral Saharan sites whose original core area lay between Libya (Tadrart Acacus) and Algeria (Tassili- n-Ajjer). The chapter starts from the general theme of the relationship between the figurines and the subjects they represent, and the difference between two-dimensional and three-dimensional representation. It goes on to discuss the manufacturing process of the clay specimens (dating from between 7000 and 4000 years ago) and the significance of the changes introduced by the Neolithic. Most of the items studied fall into the category of zoomorphic figurines, with only two anthropomorphic examples, and find in the depiction of cattle their most striking subject. These representations possess an evident symbolic content which must be framed within the pastoral ideology of the Saharan Neolithic. In the anthropomorphic figurines the representation of the human body also plays the role of recapturing the sense of wholeness.


2019 ◽  
Author(s):  
Bradley Paul Lipovsky

Abstract. Understanding the processes that govern ice shelf extent are of fundamental importance to improved estimates of future sea level rise. In present-day Antarctica, ice shelf extent is most commonly determined by the propagation of through-cutting fractures called ice shelf rifts. Here, I present the first three-dimensional analysis of ice shelf rift propagation. I present a linear elastic fracture mechanical (LEFM) description of rift propagation. The model predicts that rifts may be stabilized when buoyant flexure results in contact at the tops of the near-tip rift walls. This stabilizing tendency may be overcome, however, by processes that act in the ice shelf margins. In particular, both marginal weakening and the advection of rifts into an ice tongue are shown to be processes that may trigger rift propagation. Marginal shear stress is shown to be the determining factor that governs these types of rift instability. I furthermore show that rift stability is closely related to the transition from uniaxial to biaxial extension known as the compressive arch. Although the partial contact of rift walls is fundamentally a three-dimensional process, I demonstrate that it may be parameterized within more numerically efficient two-dimensional calculations. This study provides a step towards a description of calving physics that is based in fracture mechanics.


Author(s):  
Azen Salim ◽  
Gulardi Hanifa Wiknjosastro ◽  
I Gede Putu Surya ◽  
Bambang Karsono ◽  
I Made Kornia Karkata ◽  
...  

Abstract Although three-dimensional ultrasound (3DUS) has been available for more than 10 years in Indonesia, there was no publishing article from our region which systematically evaluates our experiences in this most recent ultrasound technologies and its application to obstetric. 3DUS is revolving into a technology with various range of applications in numerous fields because it helps overcome some of the key limitations related to two-dimensional imaging. It is through this review that we attempt to develop a continuous line of understanding the current diagnostic benefits of 3D and 4DUS in diagnosis of fetal abnormalities and consider the utility and role of this type of imaging in the routine clinical practice.


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