scholarly journals On-line gas chromatographic studies of Rf, Zr, and Hf bromides

2000 ◽  
Vol 88 (12) ◽  
Author(s):  
E.R. Sylwester ◽  
K.E. Gregorich ◽  
D.M. Lee ◽  
B. Kadkhodayan ◽  
A. Türler ◽  
...  

The Heavy Element Volatility Instrument (HEVI), an on-line isothermal gas chromatography system, has been used to separate the volatile bromide compounds of the group 4 elements Zr and Hf and the transactinide Rf according to their volatilities, and to provide data on the gas phase chemical properties of very short-lived isotopes in amounts as low as a few atoms. For these studiesA Monte Carlo code was used to deduce the enthalpy of adsorption (ΔHVolatilities of the group 4 bromides support the conclusion from previous results for the group 4 chlorides that Rf deviates from the trend expected by simple extrapolation of the properties of its lighter homologs in the periodic table. The group 4 bromides are also observed to be less volatile than their respective chlorides, as predicted by relativistic calculations.

2012 ◽  
Vol 51 (3) ◽  
pp. 249-256
Author(s):  
A. Podjava ◽  
P. Mekss ◽  
A. Zicmanis ◽  
S. Krasnov

Gas-phase chemical properties of several (1-methylimidazol-3-io)-alkane-1-carboxylates (alkane=ethane, propane and butane) have been investigated in this study. These substances are synthesized using classical transformations and analyzed in positive ionization mode using collision-induced dissociation (0-50 eV). These experiments were carried out in both deuterated and undeuterated solvent media. The data obtained in this study show, that carboxylate group weakly influences fragmentation of zwitterionic imidazolium carboxylates in positive electrospray mode. On the other hand, these compounds exert a tendency to form various adducts with sodium and potassium ions and to participate in hydrogen/deuterium exchange in the gas phase.


2020 ◽  
Vol 225 ◽  
pp. 03011
Author(s):  
L. Loubet ◽  
P.G. Allinei ◽  
P. Schindler ◽  
V. Pointeau

The Tube Support Plate blockage, also named clogging, is a complex phenomenon that can occur in the steam generator of Pressurized Water Reactors. This deposit of iron oxides, that can reduce the coolant flux and constraint the primary tubes, could have significant consequences on heat exchanges and the integrity of the primary tubes. Since 2014, an experimental program carried out jointly by CEA-EDF, has been performed on a representative dedicated equipment, the COLENTEC loop at Cadarache. The physico-chemical properties of the deposit formed (chemical composition, thickness...) were determined at the end of each experimental campaign lead at thermohydraulic and chemical stable conditions. ... In order to determine the influence on clogging of parameters such as the chemistry, the temperature, the pressure in an on line process and without performing separate experimental campaigns, a method of measurement on radioactive tracer, the gamma emitter 59Fe, has been studied by our laboratory. First, a modelization with a monte carlo code, MCNP, has been carried out with the geometrical configuration of the Tube Support Plate zone of COLENTEC in order to determine the most adapted measuring station. These calculations had shown that a 30% efficiency, high purity, germanium detector, with a specific collimation would be able to detect the accumulation of 59Fe in the Tube Support Plate of COLENTEC. Then, in order to improve and ensure those important online measurements, our laboratory has proposed the installation of two additional measuring stations. One will be dedicated to a second on-line measurement, with a gamma detector of the same type, but positioned on a section of the loop remote from the previous area, to verify that there is no significant secondary deposit evolution elsewhere on the circuit. The last additional gamma measurement station will consist of a low background system able to carry out 59Fe concentration measurements of liquid samples taken from the loop during the test. This paper presents the context of this experiment and then focuses on the spectrometry measuring stations, modelizations and tests.


2019 ◽  
Vol 107 (9-11) ◽  
pp. 865-877 ◽  
Author(s):  
Robert Eichler

Abstract The fundamental principles of the periodic table guide the research and development of the challenging experiments with transactinide elements. This guidance is elucidated together with experimental results from gas phase chemical studies of the transactinide elements with the atomic numbers 104–108 and 112–114. Some deduced chemical properties of these superheavy elements are presented here in conjunction with trends established by the periodic table. Finally, prospects are presented for further chemical investigations of transactinides based on trends in the periodic table.


2010 ◽  
Vol 98 (6) ◽  
Author(s):  
Mao-Sheng Lin ◽  
Zhi Qin ◽  
Fu-An Lei ◽  
Jun-Sheng Guo ◽  
Li-Na Zhang ◽  
...  

AbstractIn order to study the gas-phase chemical behavior of transactinides, an on-line isothermal chromatography apparatus has been developed and applied to separate short-lived technetium isotopes in the form of TcO


2016 ◽  
Vol 26 (2) ◽  
pp. 157-159 ◽  
Author(s):  
Ning Luo ◽  
Hong Wen Jing ◽  
Zhan Guo Ma ◽  
Weidong Liu ◽  
Liangchi Zhang ◽  
...  

1988 ◽  
Vol 26 (2) ◽  
pp. 559-572 ◽  
Author(s):  
Youichi Nakayama ◽  
Takayuki Takahagi ◽  
Fusami Soeda ◽  
Kenji Hatada ◽  
Shoji Nagaoka ◽  
...  

1999 ◽  
Vol 68 (3) ◽  
pp. 171-181 ◽  
Author(s):  
Evgenii N Chesnokov ◽  
Viktor N Panfilov

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