scholarly journals Improved Water Resistance of Soybean Meal-based Adhesive with SDS and PAM

BioResources ◽  
2014 ◽  
Vol 9 (3) ◽  
Author(s):  
Haixin Xu ◽  
Jing Luo ◽  
Qiang Gao ◽  
Shifeng Zhang ◽  
Jianzhang Li
RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 62957-62965 ◽  
Author(s):  
Jing Luo ◽  
Chenchen Li ◽  
Xiaona Li ◽  
Jianlin Luo ◽  
Qiang Gao ◽  
...  

The primary goal of this study is to improve the water resistance of a soybean meal-based bioadhesive and its resultant plywood with water-soluble 5,5-dimethyl hydantoin polyepoxide (DMHP).


Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1352 ◽  
Author(s):  
Yi Zhang ◽  
Jieyu Zhang ◽  
Mingsong Chen ◽  
Jing Luo ◽  
Sheldon Q. Shi ◽  
...  

Soybean meal (SM)-based adhesive exhibited a great potential to replace petroleum-derived ones to alleviate the energy crisis and eliminate carcinogenic formaldehyde. However, the bad water resistance (caused by low crosslinking density) and inherent brittleness of SM adhesive severely hindered its application. However, improving crosslinking density is generally accompanied by a toughness reduction of the adhesive. Herein, we developed a flexible long-chain starch with a hyper-branched structure (HD), and incorporated it with SM and a crosslinking agent to prepare a novel SM adhesive. Results showed that this adhesive exhibited both excellent water resistance and enhanced toughness. The wet bond strength of plywood fabricated using this adhesive was 354.5% higher than that of SM adhesive. These achievements are because introducing HD with hyper-branched groups enhanced crosslinking density, while HD’s flexible long-chain structure improved toughness of the adhesive. This HD can promote the development of tough and hydrophobic bio-based composites.


RSC Advances ◽  
2015 ◽  
Vol 5 (122) ◽  
pp. 100849-100855 ◽  
Author(s):  
Jing Luo ◽  
Jianlin Luo ◽  
Cheng Yuan ◽  
Wei Zhang ◽  
Jianzhang Li ◽  
...  

The aim of this study was to improve the water resistance of a soybean meal-based adhesive with a low-cost lignin-based resin (LR).


Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 758
Author(s):  
Mingsong Chen ◽  
Yi Zhang ◽  
Yue Li ◽  
Sheldon Q. Shi ◽  
Jianzhang Li ◽  
...  

Bio-based adhesives have low water resistance and they are less durable than synthetic adhesives, which limits their exterior applications. In this study, a bio adhesive was developed from soybean meal and larch tannin that was designed for exterior use. Phenol hydroxymethylated tannin oligomer (PHTO) was synthesized and then mixed with soybean meal flour in order to obtain a soybean meal-based adhesive (SPA). The results showed that the moisture absorption rate, residual rate, and solid content of SPA with 10 wt % PHTO (mass ratio with respect to the entire adhesive) were improved by 22.8%, 11.6%, and 6.8%, respectively, as compared with that of pure SPA. The wet shear strength of plywood with SPA with 10 wt % PHTO (boiling in 100 °C water for 3 h) was 1.04 MPa when compared with 0 MPa of pure SPA. This met the bond strength requirement of exterior-use plywood (GB/T 9846.3-2004). This improved adhesive performance was mainly due to the formation of a crosslinked structure between the PHTO and the protein and also PHTO self-crosslinking. The formaldehyde emission of the resulting plywood was the same as that of solid wood. The PHTO-modified SPA can potentially extend the applications of SPAs from interior to exterior plywood.


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 967 ◽  
Author(s):  
Zhiwei Chang ◽  
Huiwen Pang ◽  
Anmin Huang ◽  
Jianzhang Li ◽  
Shifeng Zhang

Soybean meal-based adhesives are attractive potential environmentally friendly replacements for formaldehyde-based adhesives. However, the low strength and poor water resistance of soybean meal-based adhesives limit their practical application. This study was conducted to develop a natural fiber-reinforced soybean meal-based adhesive with enhanced water resistance and bonding strength. Pulp fiber (PF), poplar wood fiber (WF), and bagasse fiber (BF) were added as fillers into the soybean meal-based adhesive to enhance its performance via hydrogen bonding between the PF and the soybean meal system. The enhanced adhesive exhibited a strong crosslinking structure characterized by multi-interfacial interactions wherein PF served as a bridging ligament and released residual stress into the crosslinking network. The crosslinked structure and improved interfacial interactions were confirmed by Fourier transform infrared (FTIR) spectrophotometry, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) measurements. Plywood bonded with 4 wt % PF-containing soybean meal-based adhesive exhibited a wet shear strength (1.14 MPa) exceeding that of plywood bonded with the control group by 75.4% due to the stable crosslinking network having efficiently transformed stress and prevented the permeation of water molecules.


RSC Advances ◽  
2016 ◽  
Vol 6 (51) ◽  
pp. 45158-45165 ◽  
Author(s):  
Xiaona Li ◽  
Jianlin Luo ◽  
Qiang Gao ◽  
Jianzhang Li

In this study, the sepiolite was initially treated with KH-560 and then introduced into the soybean meal/triglycidylamine adhesive system to form a united cross-linked network to improve the water resistance of the resultant adhesive.


1908 ◽  
Vol 66 (1719supp) ◽  
pp. 373-373
Author(s):  
Karl Wallin
Keyword(s):  

Author(s):  
Arda Yıldırım ◽  
Ergin Öztürk

This study was conducted to determine the effect of cottonseed meal (CSM) incorporated into laying rations in place of soybean meal (SBM) at different ratios on yield traits. The birds began to lay at 6th week, 180 female and 45 male quails were used in laying period experiment. Birds were fed with rations containing 20% CP and 3000 Kcal/kg ME up to 20-week age (Laying period). CSM as a substitute, five different rations of the protein content (0, 30, 58, 86 and 100%) for SBM to basal diets based on corn-soybean meal were used. The results showed that there were no differences in terms of egg yield traits, cumulative feed consumptions and viabilities during the laying period. The highest dry shell rate and shell thickness were obtained from 5th group and 1st group, respectively. As a result, adding CSM instead of SBM in laying period were no significantly differences in terms of egg production and egg quality in laying period.


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