Lead Zirconate Titanate Thick Film Prepared by Electrophoretic Deposition from Oxide Mixture

2002 ◽  
Vol 17 (5) ◽  
pp. 933-935 ◽  
Author(s):  
R. F. Zhang ◽  
J. Ma ◽  
L. B. Kong

Lead zirconate titanate (PbZr0.52Ti0.48O3; PZT) thick film with a thickness of 70 µm was prepared by the electrophoretic deposition method from a raw oxide mixture of PbO, ZrO2, and TiO2. X-ray diffraction and scanning electron microscopy were used to characterize the sintered PZT thick film. Single phase PZT was observed in the films sintered at 900 °C and above. The film sintered at 1000 °C for 30 min exhibited a dielectric constant of 1050 with a dielectric loss of about 0.05 measured at 1 kHz, a maximum polarization of 29 µC/cm2, a remnant polarization of 19 µC/cm2, and a coercive field of 21 kV/cm. This simple process to form PZT thick films may also be applied to the preparation of other multicomponent ceramics and ceramic films.

2001 ◽  
Vol 84 (12) ◽  
pp. 2921-2929 ◽  
Author(s):  
Alexandre E. Glazounov ◽  
Hans Kungl ◽  
Jan-Thorsten Reszat ◽  
Michael J. Hoffmann ◽  
Arnd Kolleck ◽  
...  

2012 ◽  
Vol 620 ◽  
pp. 486-490
Author(s):  
Shafiza Afzan Sharif ◽  
Julie Juliewatty Mohamed ◽  
W.A.W. Yusoff

Lead zirconate titanate Pb (Zr0.52Ti0.48)O3, (PZT) ceramic was successfully prepared from the mixture of commercial PbO, TiO2and ZrO2powders using planetary ball mill at room temperature. The phase formation and microstructure of the milled powders were characterized using X-ray diffraction (XRD) and Scanning Electron Microscope (SEM). XRD results indicated that the perovskite phase of PZT was formed from the mixture of starting materials after milling for 40 h. The grain sizes of the powders have been estimated from the SEM images to be ~200 nm. The compacted PZT samples were then sintered at 950 °C for 1 h. The samples were characterized by XRD and SEM, meanwhile the density was measured by Archimedes principle. XRD analysis on the sintered samples revealed the formation of single phase Pb (Zr0.52Ti0.48)O3ceramics while the SEM images estimated the grain size to be ~2 µm. The relative density of the obtained sintered PZT ceramics was measured to be approximately 99.93 % of the theoretical density. The results hence indicate that planetary ball mill is an effective preparatory technique to improve the sinterability of PZT ceramics.


2007 ◽  
Vol 90 (26) ◽  
pp. 262905 ◽  
Author(s):  
Satoko Osone ◽  
Yoshiro Shimojo ◽  
Kyle Brinkman ◽  
Takashi Iijima ◽  
Keisuke Saito

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