In situ quasi-elastic scattering characterization of particle size effects on the hydration of tricalcium silicate

2004 ◽  
Vol 19 (11) ◽  
pp. 3242-3254 ◽  
Author(s):  
A.J. Allen ◽  
J.C. McLaughlin ◽  
D.A. Neumann ◽  
R.A. Livingston

The effects of different particle size distributions on the real-time hydration of tricalcium silicate cement paste were studied in situ by quasi-elastic neutron scattering. The changing state of water in the cement system was followed as a function both of cement hydration time and of temperature for different initial particle size distributions. It was found that the length of the initial, dormant, induction period, together with the kinetics of hydration product nucleation and growth, depends on the hydration temperature but not on the particle size distribution. However, initial particle size does affect the total amount of cement hydrated, with finer particle size producing more hydrated cement. Furthermore, the diffusion-limited rate of hydration at later hydration time is largely determined by the initial tricalcium silicate particle size distribution.

2015 ◽  
Vol 268 ◽  
pp. 209-215 ◽  
Author(s):  
M. Vicent ◽  
E. Bannier ◽  
P. Carpio ◽  
E. Rayón ◽  
R. Benavente ◽  
...  

2010 ◽  
Vol 177 ◽  
pp. 22-24
Author(s):  
Zheng Min Li ◽  
Zhi Wei Chen ◽  
Min Tan ◽  
Ke Jing Xu ◽  
Bing Jiang

Nano-TiO2 coating film is one of the efficient photocatalysts. The particle size distribution of TiO2 has important influence on photocatalytic activity. A new method to determine the particle size distribution of TiO2 nano-film coated on ceramic was developed, by which the images of film acquired by Atom force microscope (AFM) were processed, and TiO2 particles contacted with others were separated and detected. The particle size distributions of two TiO2 nano-films were determined.


1994 ◽  
Vol 74 (2) ◽  
pp. 383-385 ◽  
Author(s):  
R. Soofi-Siawash ◽  
G. W. Mathison

Two studies were conducted to assess the possibility of using particle size distribution following grinding as a routine procedure of forage evaluation. It was concluded that although differences in particle size distribution could be detected when different feeds were ground, it would be difficult to standardize the technique since particle size distributions were influenced by type of mill used for grinding, particle size of forage before grinding, and moisture content of the forage. Key words: Forages, grinding, particle size, moisture, mill


AIChE Journal ◽  
2019 ◽  
Vol 65 (8) ◽  
Author(s):  
Haoshu Shen ◽  
Yuxin Wu ◽  
Minmin Zhou ◽  
Sean T. Smith ◽  
Hai Zhang ◽  
...  

2020 ◽  
Vol 57 (11) ◽  
pp. 1684-1694
Author(s):  
Shijin Li ◽  
Adrian R. Russell ◽  
David Muir Wood

Internal erosion (suffusion) is caused by water seeping through the matrix of coarse soil and progressively transporting out fine particles. The mechanical strength and stress–strain behavior of soils within water-retaining structures may be affected by internal erosion. Some researchers have set out to conduct triaxial erosion tests to study the mechanical consequences of erosion. Prior to conducting a triaxial test they subject a soil sample, which has an initially homogeneous particle-size distribution and density throughout, to erosion by causing water to enter one end of a sample and wash fine particles out the other. The erosion and movement of particles causes heterogeneous particle-size distributions to develop along the sample length. In this paper, a new soil sample formation procedure is presented that results in homogeneous particle-size distributions along the length of an eroded sample. Triaxial tests are conducted on homogeneous samples formed using the new procedure as well as heterogeneous samples created by the more commonly used approach. Results show that samples with homogeneous post-erosion particle-size distributions exhibit slightly higher peak deviator stresses than those that were heterogeneous. The results highlight the importance of ensuring homogeneity of post-erosion particle-size distributions when assessing the mechanical consequences of erosion. Forming samples using the new procedure enables the sample’s response to triaxial loading to be interpreted against a measure of its initially homogenous state.


CrystEngComm ◽  
2018 ◽  
Vol 20 (38) ◽  
pp. 5672-5676 ◽  
Author(s):  
Run-Zhi Zhang ◽  
Yong-qing Huang ◽  
Wei Zhang ◽  
Ji-Min Yang

UiO-67 nano/microcrystals with different particle size distributions (PSDs) were successfully obtained by a simple solvothermal method.


2017 ◽  
Vol 898 ◽  
pp. 1717-1723 ◽  
Author(s):  
Xue Mei Yi ◽  
Shota Suzuki ◽  
Xiong Zhang Liu ◽  
Ran Guo ◽  
Tomohiro Akiyama

Combustion synthesis (CS) of β-SiAlON was conducted using a 3D ball mill, with a focus on the effect of the 2D/3D ball mill premixing conditions on the CS raw material particle size as well as on the yield and grain shape of the final products. The results showed that the particle size distribution of the raw materials was significantly affected by the premixing conditions. Various particle sizes and particle size distributions could easily be obtained by using a 3D mill instead of a 2D mill due to the complex biaxial rotation movement of 3D milling. The particle size was more sensitive to the rotation ratio (vertical spin/horizontal spin, Vv/Vh) than the rotation rate when using 3D milling. Finally, β-SiAlON with less than 5 mass% unreacted Si was obtained using premix milling conditions of 135×200 [vertical spin (rpm) × horizontal spin (rpm)]. The grain shapes of the final products were clearly influenced by the particle size distribution of the raw mixtures.


2019 ◽  
Vol 34 (7) ◽  
pp. 1380-1386 ◽  
Author(s):  
Guillaume Bucher ◽  
François Auger

Particle size distribution (PSD) of a highly polydisperse TiO2 sample determined by spICP-MS.


1984 ◽  
Vol 143 ◽  
pp. 387-411 ◽  
Author(s):  
I. A. Valioulis ◽  
E. J. List ◽  
H. J. Pearson

Hunt (1982) and Friedlander (1960a, b) used dimensional analysis to derive expressions for the steady-state particle-size distribution in aerosols and hydrosols. Their results were supported by the Monte Carlo simulation of a non-interacting coagulating population of suspended spherical particles developed by Pearson, Valioulis & List (1984). Here the realism of the Monte Carlo simulation is improved by accounting for the modification to the coagulation rate caused by van der Waals', electrostatic and hydrodynamic forces acting between particles. The results indicate that the major hypothesis underlying the dimensional reasoning, that is, collisions between particles of similar size are most important in determining the shape of the particle size distribution, is valid only for shear-induced coagulation. It is shown that dimensional analysis cannot, in general, be used to predict equilibrium particle-size distributions, mainly because of the strong dependence of the interparticle force on the absolute and relative size of the interacting particles.


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