Design Parameters for Superhydrophobicity and Superoleophobicity

MRS Bulletin ◽  
2008 ◽  
Vol 33 (8) ◽  
pp. 752-758 ◽  
Author(s):  
Anish Tuteja ◽  
Wonjae Choi ◽  
Gareth H. McKinley ◽  
Robert E. Cohen ◽  
Michael F. Rubner
Keyword(s):  
Surface Tension ◽  
Surface Topography ◽  
Leaf Surface ◽  
Contact Angles ◽  
Design Parameters ◽  
Lotus Leaf ◽  
General Design ◽  
Composite Interface

AbstractRecent experiments have revealed that the wax on the lotus leaf surface, by itself, is weakly hydrophilic, even though the lotus leaf is known to be superhydrophobic. Conventional understanding suggests that a surface of such waxy composition should not be able to support superhydrophobicity and high contact angles between a liquid and the surface. Here, we show that the unexpected superhydrophobicity is related to the presence of “reentrant texture” (that is, a multivalued surface topography) on the surface of the lotus leaf. We exploit this understanding to enable the development of superoleophobic surfaces (i.e., surfaces that repel extremely low-surface-tension liquids, such as various alkanes), where essentially no naturally oleophobic materials exist. We also develop general design parameters that enable the evaluation of the robustness of the composite interface on a particular surface. Based on these design parameters, we also rank various superhydrophobic and superoleophobic substrates discussed in the literature, with particular emphasis on surfaces developed from inherently hydrophilic or oleophilic materials.

Investigating the Wettability of Rapeseed Leaves

2021 ◽  
Vol 37 (3) ◽  
pp. 399-409
Author(s):  
Yong He ◽  
Jianjian Wu ◽  
Shupei Xiao ◽  
Hui Fang ◽  
Qishuai Zheng
Keyword(s):  
Surface Tension ◽  
Free Energy ◽  
Significant Influence ◽  
Leaf Surface ◽  
Contact Angles ◽  
List Type ◽  
Factors Affecting ◽  
Spray Droplets ◽  
Droplet Sizes ◽  
Leaf Wettability

HighlightsContact angles of spray droplets were positively correlated with their surface tension.Wettability of rape leaves was generally poor for most pesticides.Surface structure and free energy determine the hydrophobicity of rape leaves.The size of the spray droplets had no significant influence on rape leaf wettability.Abstract. In order to improve the deposition and adherence of spray droplets on leaf surfaces, the wettability of rapeseed leaves was investigated. We explored the effect of different pesticides and test surfaces on droplet contact angles, and analyzed the effects of leaf surface properties, droplet sizes and the addition of organosilicone adjuvant on wettability. The results indicated that contact angles of different liquids were positively correlated with their surface tension for rapeseed leaves. The wettability of rapeseed leaves was generally poor using different pesticides, but was highest for a fungicide mixture of difenoconazole and propiconazole. The hydrophobicity of rapeseed leaves is largely determined by the complex microstructure and the low surface free energy of the leaves. The size of the spray droplets had no significant influence on the wettability. Moreover, the addition of an organosilicone adjuvant significantly reduced the surface tension of all spray droplets, with the best result for a 50% procymidone solution. In conclusion, the factors affecting rapeseed leaf surface wettability should be considered comprehensively before selecting the appropriate pesticide, so as to improve its utilization rates. Keywords: Contact angle, Leaf surface, Pesticide application, Spray droplet.

scholarly journals Influence of moisture content on the contact angle and surface tension measured on birch wood surfaces

2021 ◽  
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Moisture Content ◽  
Solid Wood ◽  
Contact Angles ◽  
Surface Moisture ◽  
Wood Coatings ◽  
The Relationship ◽  
Wood Surfaces

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.

scholarly journals Superhydrophobicity in perfection: the outstanding properties of the lotus leaf

2011 ◽  
Vol 2 ◽  
pp. 152-161 ◽  
Author(s):  
Hans J Ensikat ◽  
Petra Ditsche-Kuru ◽  
Christoph Neinhuis ◽  
Wilhelm Barthlott
Keyword(s):  
Chemical Composition ◽  
Water Repellency ◽  
Contact Angles ◽  
Dense Layer ◽  
Lotus Effect ◽  
Nano Structure ◽  
Lotus Leaf ◽  
Water Drops ◽  
The Impact ◽  
Unique Chemical

Lotus leaves have become an icon for superhydrophobicity and self-cleaning surfaces, and have led to the concept of the ‘Lotus effect’. Although many other plants have superhydrophobic surfaces with almost similar contact angles, the lotus shows better stability and perfection of its water repellency. Here, we compare the relevant properties such as the micro- and nano-structure, the chemical composition of the waxes and the mechanical properties of lotus with its competitors. It soon becomes obvious that the upper epidermis of the lotus leaf has developed some unrivaled optimizations. The extraordinary shape and the density of the papillae are the basis for the extremely reduced contact area between surface and water drops. The exceptional dense layer of very small epicuticular wax tubules is a result of their unique chemical composition. The mechanical robustness of the papillae and the wax tubules reduce damage and are the basis for the perfection and durability of the water repellency. A reason for the optimization, particularly of the upper side of the lotus leaf, can be deduced from the fact that the stomata are located in the upper epidermis. Here, the impact of rain and contamination is higher than on the lower epidermis. The lotus plant has successfully developed an excellent protection for this delicate epistomatic surface of its leaves.

scholarly journals Experimental Investigation of Coal Dust Wettability Based on Surface Contact Angle

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Gang Zhou ◽  
Han Qiu ◽  
Qi Zhang ◽  
Mao Xu ◽  
Jiayuan Wang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Specific Surface ◽  
Coal Dust ◽  
Single Point ◽  
Contact Angles ◽  
Critical Surface ◽  
Volume Percentage ◽  
Surface Areas ◽  
Specific Surface Areas

Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.

Contact Angles of Submillimeter Particles:  Connecting Wettability to Nanoscale Surface Topography

Langmuir ◽  
2007 ◽  
Vol 23 (10) ◽  
pp. 5255-5258 ◽  
Author(s):  
Keith M. Forward ◽  
Amanda L. Moster ◽  
Daniel K. Schwartz ◽  
Daniel J. Lacks
Keyword(s):  
Surface Topography ◽  
Contact Angles

Surface tension and contact angles of molten cadmium telluride

1990 ◽  
Vol 11 (1) ◽  
pp. 25-35 ◽  
Author(s):  
R. Balasubramanian ◽  
W. R. Wilcox
Keyword(s):  
Surface Tension ◽  
Cadmium Telluride ◽  
Contact Angles

Investigation of Pool Boiling Critical Heat Flux Enhancement on a Modified Surface Through the Dynamic Wetting of Water Droplets

2012 ◽  
Vol 134 (7) ◽  
Author(s):  
Ho Seon Ahn ◽  
Joonwon Kim ◽  
Moo Hwan Kim
Keyword(s):  
Surface Tension ◽  
Heat Flux ◽  
Contact Angle ◽  
Critical Heat Flux ◽  
Pool Boiling ◽  
Water Layer ◽  
Contact Angles ◽  
Water Droplets ◽  
Dynamic Wetting ◽  
Modified Surface

Dynamic wetting behaviors of water droplet on the modified surface were investigated experimentally. Dynamic contact angles were measured as a characterization method to explain the extraordinary pool boiling critical heat flux (CHF) enhancement on the zirconium surface by anodic oxidation modification. The sample surface is rectangular zirconium alloy plates (20 × 25 × 0.7 mm), and 12 μl of deionized water droplets were fallen from 40 mm of height over the surface. Dynamic wetting movement of water on the surface showed different characteristics depending on static contact angle (49.3 deg–0 deg) and surface temperature (120 °C–280 °C). Compared with bare surface, wettable and spreading surface had no-receding contact angle jump and seemed stable evaporating meniscus of liquid droplet in dynamic wetting condition on hot surface. This phenomenon could be explained by the interaction between the evaporation recoil and the surface tension forces. The surface tension force increased by micro/nanostructure of the modified zirconium surface suppresses the vapor recoil force by evaporation which makes the water layer unstable on the heated surface. Thus, such increased surface force could sustain the water layer stable in pool boiling CHF condition so that the extraordinary CHF enhancement could be possible.

Precisely Controlling Assembly Angle of Surface Tension Powered Self-Assembly for MEMS Microstructures

2007 ◽  
Author(s):  
Kai-Lin Pan ◽  
Yi-Lin Yan ◽  
Bin Zhou
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Self Assembly ◽  
Current Model ◽  
Three Dimensional ◽  
Design Parameters ◽  
Solder Paste ◽  
Surface Evolver ◽  
Final Assembly ◽  
The Relationship

How to integrate the microstructures which are made by various micro manufacturing methods into a functional system or device is the key to the application of MEMS technology. Solder self-assembly is based on surface tension with the properties of “self-organization”, low cost, batch processes and the compatibility with surface mount technology, which makes it be a challenging alternate technique. Solder self-assembly is based on the principle of surface energy minimization of molten solder material. During the process of minimizing the surface energy, surface tension can pull the horizontal hinged or hingeless plate up to a particular angle to achieve the minimal system energy. Finite element method is applied in this paper. MEMS self-assembly three-dimensional dynamic simulation model is developed by SURFACE EVOLVER. First, the model in this paper dynamically simulate the angle change of hinged plate during the process of evolvement of solder; second, the comparisons among the results from the current model and those from analytical two-dimensional model and three-dimensional static model are carried out; third, through Design of Experiments (DoE) with the application of the current model, the influences of design parameters such as pad size, pad geometry, and solder paste volume to the assembly angle are compared and discussed. Through changing the pad size, pad geometry and solder paste volume in SURFACE EVOLVER model, the corresponding final assembly angel from dynamic three-dimensional models are obtained. The relationship between design parameters to the assembly angle is concluded by the application of statistical analyses. The final angle can be controlled more effectively through synthetically optimize these parameters. It can provide effective guidance to the practical manufacturing of MEMS. Further research should focuses on the MEMS self-assembly experiment to intensively understand the relationship between the pad sizes, pad position, solder paste volume, hinge position, lock position and intermetallic compounds and the final assembly angle.

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