LaF3-BaF2-KF derived electrolyte in solid state fluoride-ion battery

2010 ◽  
Vol 1266 ◽  
Author(s):  
Dechao Wang ◽  
Anji Reddy Munnangi ◽  
Horst Hahn ◽  
Max Fichtner
Keyword(s):  
Solid State ◽  
High Performance ◽  
Low Cost ◽  
Electrical Energy ◽  
Composite Cathode ◽  
Fluoride Anion ◽  
Cubic Symmetry ◽  
Group A ◽  
Battery Technology ◽  
Preparation Techniques

AbstractSolid-state based battery technology offers, in principle, the largest temperature range (from room temperature to 500 °C) of any battery technology. In fluoride based batteries, the chemical reaction used to create electrical energy is a solid-state reaction of a metal with fluoride anion [1]. Among the various types of solid preparation techniques, the mechanochemical synthesis has been recognized as a powerful route to novel, high-performance, and low-cost materials [2]. Thus, a mixed and highly disordered fluoride phase with retained cubic symmetry can be obtained with a very high Fˉ diffusivity [3].In our group, a series of new electrolytes was developed, namely LaF3-BaF2-KF solid solutions, using mechanosynthesis method. The cubic structure of the product was confirmed by XRD. The nanoscale nature and morphology of the samples were characterized by SEM and TEM. First Solid-state electrochemical cells were built with LiF based composite cathode, LaF3-BaF2-KF derived electrolyte and Fe based composite anode.

scholarly journals Synthesis, Structure and Diffusion Pathways of Fast Lithium-Ion Conductors in the Polymorphs α- and β-Li8SnP4

2021 ◽  
Author(s):  
Thomas F Fässler ◽  
Stefan Strangmüller ◽  
Henrik Eickkhoff ◽  
Wilhelm Klein ◽  
Gabriele Raudaschl-Sieber ◽  
...  
Keyword(s):  
High Performance ◽  
Low Cost ◽  
Lithium Ion ◽  
Conducting Materials ◽  
Increasing Demand ◽  
Battery Technology ◽  
Lithium Ion Conductors ◽  
And Diffusion ◽  
Ion Conductors

The increasing demand for a high-performance and low-cost battery technology promotes the search for Li+-conducting materials. Recently, phosphidotetrelates and aluminates were introduced as an innovative class of phosphide-based Li+-conducting materials...

Organic electrode materials for non-aqueous, aqueous, and all-solid-state Na-ion batteries

2021 ◽  
Author(s):  
Kathryn Holguin ◽  
Motahareh Mohammadiroudbari ◽  
Kaiqiang Qin ◽  
Chao Luo
Keyword(s):  
Solid State ◽  
High Performance ◽  
Electrode Materials ◽  
Low Cost ◽  
Li Ion Batteries ◽  
Organic Electrode ◽  
Li Ion

Na-ion batteries (NIBs) are promising alternatives to Li-ion batteries (LIBs) due to the low cost, abundance, and high sustainability of sodium resources. However, the high performance of inorganic electrode materials...

Applying multi-scale silica-like three-dimensional networks in PEO matrix via in-situ crosslinking for high-performance solid composite electrolyte

2021 ◽  
Author(s):  
Jiawei Wu ◽  
Jing Chen ◽  
Xiaodong Wang ◽  
An'an Zhou ◽  
Zhenglong Yang
Keyword(s):  
Solid State ◽  
High Performance ◽  
Low Cost ◽  
Three Dimensional ◽  
Electrochemical Stability ◽  
Composite Electrolyte ◽  
Solid State Electrolyte ◽  
Multi Scale ◽  
In Situ Crosslinking

For the higher safety and energy density, solid-state electrolyte with better mechanical strength, thermal and electrochemical stability is a perfect choice. To improve the performance of PEO, usage of low-cost...

Low-Cost High-Performance Solid-State Asymmetric Supercapacitors Based on MnO2 Nanowires and Fe2O3 Nanotubes

Nano Letters ◽  
2014 ◽  
Vol 14 (2) ◽  
pp. 731-736 ◽  
Author(s):  
Peihua Yang ◽  
Yong Ding ◽  
Ziyin Lin ◽  
Zhongwei Chen ◽  
Yuzhi Li ◽  
...  
Keyword(s):  
Solid State ◽  
High Performance ◽  
Low Cost ◽  
Asymmetric Supercapacitors ◽  
Fe2o3 Nanotubes ◽  
Mno2 Nanowires

A Low Cost Rejuvenation of Old G.E. and Picker X-Ray Generators

1983 ◽  
Vol 27 ◽  
pp. 293-297
Author(s):  
G. Raykhtsaum ◽  
P. Georgopoulos
Keyword(s):  
Solid State ◽  
High Voltage ◽  
High Performance ◽  
Low Cost ◽  
The United States ◽  
Control Device ◽  
State Control ◽  
X Ray ◽  
Tube Current ◽  
Control Devices

General Electric (G.E.) and Picker generators are currently installed in many research laboratories all over the United States. These units are old and do not satisfy the modern requirements for X-ray generators. Instabilities of high voltage and tube current complicate the experiment. To maintain G.E. and Picker generators is becoming more and more expensive due to the high cost of vacuum tubes and replacement parts. To replace old generators with new high performance commercial units can cost even more and requires additional adaptations. In the present paper another alternative is proposed, which assumes the replacement of vacuum tube mA and KV controls with solid state circuits using the old G.E. or Picker high voltage transformers. This alternative allows rejuvenation of old generators without difficulties of reinstallation and does not require adaptations to the existing experimental X-ray equipment. The combination of old high voltage transformers with modern solid state control devices provides high performance at low cost. For this purpose the control device was designed and is described below.

Modeling the Selective Laser Melting of Multi-Component Thermoelectric Powders

2018 ◽  
Author(s):  
Yongjia Wu ◽  
Lei Zuo ◽  
Kan Sun
Keyword(s):  
Selective Laser Melting ◽  
High Performance ◽  
Low Cost ◽  
Electrical Energy ◽  
Device Fabrication ◽  
Thermoelectric Device ◽  
Laser Melting ◽  
Thermoelectric Modules ◽  
Powder Bed ◽  
Unique Method

Thermoelectrics enables thermal and electrical energy conversion or device cooling without any moving parts. It has remained a significant challenge to manufacture compact and high performance thermoelectric modules in a large volume using the conventional methods because of their drawbacks in practice, such as the long processing time and misalignment of individual thermoelectric elements. Selective laser melting (SLM) based additive manufacturing approach might offer a unique method to fabricate the low cost, reliable, highly efficient, scalable, and environmentally friendly thermoelectric modules. To understand the thermodynamic and hydrodynamic phenomenon during the SLM processing is of critical importance to ensure high quality products. In this paper, we developed a model which can be used to guide the SLM manufacturing of thermoelectric material with other nanoparticles embedded for higher thermoelectric performance. This physical model based on the continuous equations had the ability to analyze the fluid flow driven by buoyancy force and surface tension, which can be used to analyze the influence of the process parameters on the pool size, particle segregation, as well as temperature distribution within the powder bed. This information is very useful for developing robust SLM for thermoelectric device fabrication.

High Performance Supercapacitors Electrode Derived from the Pine Needles

2014 ◽  
Vol 1035 ◽  
pp. 385-391
Author(s):  
Pei Yu Wang ◽  
Guo Heng Zhang ◽  
Hai Yan Jiao ◽  
Xiao Ping Zheng
Keyword(s):  
High Performance ◽  
Low Cost ◽  
Active Material ◽  
Electrical Energy ◽  
Pine Needles ◽  
Porous Structures ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Surface Areas ◽  
Amorphous Character

In this paper, Pine needles (PNs) were used to synthesize porous activated carbon by the carbonization and activation processes. The material for PNs were carbonized at 600 °C and activated at 800 °C(denoted as AC-800) show typical amorphous character, and display porous structures with high specific surface areas 2729 m2/g via XRD and BET measurements. As the electro-active material, AC-800 electrode exhibit ideal capacitive behaviors in aqueous electrolytes, and the maximal specific capacitance is as high as 286 F/g at the current density of 1 A/g. Furthermore, AC-800 electrode shows excellent electrochemical cycle stability with ~94 % initial capacitance being retained after 2000 cycles. The desirable capacitive performances enable the PNs to act as a new biomass source of carbonaceous materials for high performance supercapacitors and low-cost electrical energy storage devices.

High-performance, ultra-flexible and transparent embedded metallic mesh electrodes by selective electrodeposition for all-solid-state supercapacitor applications

2017 ◽  
Vol 5 (19) ◽  
pp. 9032-9041 ◽  
Author(s):  
Yan-Hua Liu ◽  
Jian-Long Xu ◽  
Su Shen ◽  
Xin-Lei Cai ◽  
Lin-Sen Chen ◽  
...  
Keyword(s):  
Solid State ◽  
High Performance ◽  
Low Cost ◽  
Processing Methods ◽  
Electrodeposition Process ◽  
Metallic Mesh ◽  
Film Processing ◽  
First Time ◽  
Supercapacitor Applications

High-performance, ultra-flexible and transparent embedded metallic mesh electrodes were fabricatedvialow-cost selective electrodeposition process combined with inverted film-processing methods for the first time. Flexible and transparent all-solid-state supercapacitors were thus successfully constructed.

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