High Performance Supercapacitors Electrode Derived from the Pine Needles

2014 ◽  
Vol 1035 ◽  
pp. 385-391
Author(s):  
Pei Yu Wang ◽  
Guo Heng Zhang ◽  
Hai Yan Jiao ◽  
Xiao Ping Zheng

In this paper, Pine needles (PNs) were used to synthesize porous activated carbon by the carbonization and activation processes. The material for PNs were carbonized at 600 °C and activated at 800 °C(denoted as AC-800) show typical amorphous character, and display porous structures with high specific surface areas 2729 m2/g via XRD and BET measurements. As the electro-active material, AC-800 electrode exhibit ideal capacitive behaviors in aqueous electrolytes, and the maximal specific capacitance is as high as 286 F/g at the current density of 1 A/g. Furthermore, AC-800 electrode shows excellent electrochemical cycle stability with ~94 % initial capacitance being retained after 2000 cycles. The desirable capacitive performances enable the PNs to act as a new biomass source of carbonaceous materials for high performance supercapacitors and low-cost electrical energy storage devices.

2019 ◽  
Vol 7 (1) ◽  
pp. 191-201 ◽  
Author(s):  
Jianglin Ye ◽  
Patrice Simon ◽  
Yanwu Zhu

Abstract Tremendous efforts have been dedicated to developing high-performance energy storage devices based on the micro- or nano-manipulation of novel carbon electrodes, as certain nanocarbons are perceived to have advantages such as high specific surface areas, superior electric conductivities, excellent mechanical properties and so on. In typical electrochemical electrodes, ions are intercalated/deintercalated into/from the bulk (for batteries) or adsorbed/desorbed on/from the surface (for electrochemical capacitors). Fast ionic transport, significantly determined by ionic channels in active electrodes or supporting materials, is a prerequisite for the efficient energy storage with carbons. In this report, we summarize recent design strategies for ionic channels in novel carbons and give comments on the promising features based on those carbons towards tailorable ionic channels.


2017 ◽  
Vol 5 (28) ◽  
pp. 14838-14846 ◽  
Author(s):  
Wenda Qiu ◽  
Yu Li ◽  
Ao You ◽  
Zemin Zhang ◽  
Guangfu Li ◽  
...  

Aqueous Zn–MnO2 batteries have great potential as flexible energy storage devices owing to their low cost, high energy density, safety, and environmental friendliness.


2019 ◽  
pp. 1801041 ◽  
Author(s):  
Shujun Wang ◽  
Jiadong Qin ◽  
Yubai Zhang ◽  
Fang Xia ◽  
Minsu Liu ◽  
...  

Author(s):  
Tahereh Sadeghian ◽  
Mehdi Khoshfetrat ◽  
Jalal Arjomandi ◽  
HU SHI ◽  
Sadegh Khazalpour

Great efforts have been made to design and fabricate low-cost, high efficiency advanced electrode materials for energy storage devices such as batteries and high-performance supercapacitors. Choosing organic and redox active...


Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 340 ◽  
Author(s):  
Yuanwei Li ◽  
Xueyang Zhao ◽  
Hui Liu ◽  
Wei Li ◽  
Xiaojian Wang

In this paper, nanoporous copper (NPC) was prepared by dealloying ZrCuAl metallic glass ribbons with HF acid solutions. The effect of dealloying time on the porous structures and thickness of the obtained NPC films was investigated. It was found that the ligament sizes of the NPC could be tuned in a range from 20 to 300 nm, and the thicknesses of the NPC films from 3.1 to 14.4 μm, with properly selected dealloying times. Furthermore, nanoporous composites made of NPC and nanoporous Cu2O were prepared by oxidizing the NPC with ethanol. The nanoporous composite electrodes exhibited superior charge-discharge performance and would have broad potential applications in flexible high-performance energy storage devices.


2018 ◽  
Vol 11 (9) ◽  
pp. 2560-2568 ◽  
Author(s):  
Jiarui He ◽  
Yuanfu Chen ◽  
Arumugam Manthiram

Lithium–sulfur (Li–S) batteries have been regarded as one of the most promising next-generation energy-storage devices, due to their low cost and high theoretical energy density (2600 W h kg−1).


2017 ◽  
Vol 5 (33) ◽  
pp. 17293-17301 ◽  
Author(s):  
Zhao Jun Han ◽  
Shafique Pineda ◽  
Adrian T. Murdock ◽  
Dong Han Seo ◽  
Kostya (Ken) Ostrikov ◽  
...  

Solid-state supercapacitors can be fabricated by uniformly coating RuO2onto vertical graphene (VG) using a simple, scalable, low-cost and solution-free method. The binder-free RuO2/VG hybrid electrodes possess a high areal capacitance, low electrical resistance, good frequency response, and excellent stability, shedding light on the commercialisation of Ru-based energy storage devices.


2019 ◽  
Vol 3 (2) ◽  
pp. 499-507 ◽  
Author(s):  
Yubing Li ◽  
Deyi Zhang ◽  
Jingjing He ◽  
Yulin Wang ◽  
Xiai Zhang ◽  
...  

The utilization of electrode materials with high-performance and low-cost is crucial for the development of electrochemical energy storage devices.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Jingdong Huang ◽  
Jing Zeng ◽  
Kunjie Zhu ◽  
Ruizhi Zhang ◽  
Jun Liu

AbstractThere is an urgent need for low-cost, high-energy-density, environmentally friendly energy storage devices to fulfill the rapidly increasing need for electrical energy storage. Multi-electron redox is considerably crucial for the development of high-energy-density cathodes. Here we present high-performance aqueous zinc–manganese batteries with reversible Mn2+/Mn4+ double redox. The active Mn4+ is generated in situ from the Mn2+-containing MnOx nanoparticles and electrolyte. Benefitting from the low crystallinity of the birnessite-type MnO2 as well as the electrolyte with Mn2+ additive, the MnOx cathode achieves an ultrahigh energy density with a peak of 845.1 Wh kg−1 and an ultralong lifespan of 1500 cycles. The combination of electrochemical measurements and material characterization reveals the reversible Mn2+/Mn4+ double redox (birnessite-type MnO2 ↔ monoclinic MnOOH and spinel ZnMn2O4 ↔ Mn2+ ions). The reversible Mn2+/Mn4+ double redox electrode reaction mechanism offers new opportunities for the design of low-cost, high-energy-density cathodes for advanced rechargeable aqueous batteries.


Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2053 ◽  
Author(s):  
Jia Hui ◽  
Daoxin Wei ◽  
Jing Chen ◽  
Zhou Yang

Carbon materials have been widely used in designing supercapacitors (SCs) but the capacitance is not ideal. Herein, we synthesize polyaniline (PANI) nanotubes on the basis of a carbon cloth (CC) through a one-step self-degradation template method, and fabricate a CC@PANI NTs-H (CC@PANI nanotubes doping at high temperature) composite electrode by thermal acid doping. The CC@PANI NTs-H electrode obviously exhibits better electrochemical performance with a gravimetric capacitance of 438 F g−1 and maintains 86.8% after 10,000 cycles than the CC@PANI NTs-R (CC@PANI nanotubes doping at room temperature) electrode. Furthermore, we assemble a flexible solid state supercapacitor (FSSC) device with the as-prepared CC@PANI NTs-H composite electrodes, showing good flexibility and outstanding electrochemical performances with a high gravimetric capacitance of 247 F g−1, a large energy density of 21.9 Wh kg−1, and a capacitance retention of 85.4% after 10,000 charge and discharge cycles. Our work proposes a novel and easy pathway to fabricate low-cost FSSCs for the development of energy storage devices.


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