Cation Disordering in the Tl-2122 Superconductors

1989 ◽  
Vol 169 ◽  
Author(s):  
B. Morosin ◽  
D. S. Ginley ◽  
E. L. Venturini ◽  
R. J. Baughman ◽  
J. E. Schirber ◽  
...  
Keyword(s):  
Solid Solution ◽  
Structure Type ◽  
Lattice Parameters ◽  
Transition Temperatures ◽  
Superconducting Transition ◽  
Substantial Variation ◽  
Cation Disorder ◽  
Cation Disordering

AbstractWe have examined several crystals belonging to the Tl‐2122 structure type (Tl2CaBa2Cu2O8 with c=29Å), and have shown that cation solid solution occurs. Such cation disorder appears to be responsible for the observed small differences in lattice parameters reported by various investigators and to contribute towards the substantial variation in the superconducting transition temperatures.

A Systematic Study of the Effects of Metal Substitutions for Cu in Yba2(Cu1-XMX)3O7-δ, M=Fe, Co, Al, Ga, Cr, Ni, and Zn

1989 ◽  
Vol 169 ◽  
Author(s):  
Youwen Xu ◽  
A. R. Moodenbaugh ◽  
Y. L. Wang ◽  
M. Suenaga ◽  
R. L. Sabatini
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Systematic Study ◽  
Lattice Parameters ◽  
Phase Solubility ◽  
Transition Temperatures ◽  
Superconducting Transition ◽  
Individual Grains ◽  
Ga Content

AbstractA series of polycrystalline YBa2(Cu1‐xMx)3O7‐δ (1:2:3) samples with a typical grain size > 10μm was prepared using well controlled and reproducible precedures. This relatively large grain size allowed microprobe studies of individual grains to determine M content of the 1:2:3 phase. Solubility limits of substitutions for Cu in these samples are estimated. Superconducting transition temperatures and lattice parameters are presented. In the case of Ga, microprobe studies show no evidence for Ga content of 1:2:3 above x=0.01. Preliminary studies show no evidence for solid solution above x=0.01 when substituting Mn, Cr, Zr, and Ti for Cu in 1:2:3.

scholarly journals Fe-based superconducting transition temperature modeling by machine learning: A computer science method

PLoS ONE ◽  
2021 ◽  
Vol 16 (8) ◽  
pp. e0255823
Author(s):  
Zhiyuan Hu
Keyword(s):  
Machine Learning ◽  
High Temperature ◽  
Transition Temperature ◽  
High Temperature Superconductors ◽  
Strong Relationship ◽  
Lattice Parameters ◽  
Transition Temperatures ◽  
Superconducting Transition ◽  
Temperature Modeling ◽  
High Transition

Searching for new high temperature superconductors has long been a key research issue. Fe-based superconductors attract researchers’ attention due to their high transition temperature, strong irreversibility field, and excellent crystallographic symmetry. By using doping methods and dopant levels, different types of new Fe-based superconductors are synthesized. The transition temperature is a key indicator to measure whether new superconductors are high temperature superconductors. However, the condition for measuring transition temperature are strict, and the measurement process is dangerous. There is a strong relationship between the lattice parameters and the transition temperature of Fe-based superconductors. To avoid the difficulties in measuring transition temperature, in this paper, we adopt a machine learning method to build a model based on the lattice parameters to predict the transition temperature of Fe-based superconductors. The model results are in accordance with available transition temperatures, showing 91.181% accuracy. Therefore, we can use the proposed model to predict unknown transition temperatures of Fe-based superconductors.

Prediction of phonon-mediated superconductivity in two-dimensional Mo2B2

2019 ◽  
Vol 7 (9) ◽  
pp. 2589-2595 ◽  
Author(s):  
Luo Yan ◽  
Tao Bo ◽  
Peng-Fei Liu ◽  
Bao-Tian Wang ◽  
Yong-Guang Xiao ◽  
...  
Keyword(s):  
Two Dimensional ◽  
Transition Temperatures ◽  
Superconducting Transition ◽  
Molybdenum Boride

We predict two new molybdenum boride monolayers as phonon-mediated superconductors with superconducting transition temperatures of 3.9 and 0.2 K.

scholarly journals Structural, Superconducting and Magnetic Properties of La3-XRxNi2B2N3-δ with R = Ce, Pr, Nd

2011 ◽  
Vol 170 ◽  
pp. 165-169 ◽  
Author(s):  
Tahir Ali ◽  
Ernst Bauer ◽  
Gerfried Hilscher ◽  
Herwig Michor
Keyword(s):  
Magnetic Properties ◽  
Structure Type ◽  
The Body ◽  
Spin Reorientation ◽  
Superconducting Transition ◽  
X Ray Diffraction ◽  
Range Magnetic Order ◽  
Long Range Magnetic Order ◽  
First Time ◽  
Magnetic Pair

We report on structural and superconducting properties of La3-xRxNi2B2N3- where La is substituted by the magnetic rare-earth elements Ce, Pr, Nd. The compounds Pr3Ni2B2N3- and Nd3Ni2B2N3- are characterized for the first time. Powder X-ray diffraction confirmed all samples R3Ni2B2N3- with R = La, Ce, Pr, Nd and their solid solutions to crystallize in the body centered tetragonal La3Ni2B2N3 structure type. Superconducting and magnetic properties of La3-xRxNi2B2N3- were studied by resistivity, specific heat and susceptibility measurements. While La3Ni2B2N3- has a superconducting transition temperature Tc ~ 14 K, substitution of La by Ce, Pr, and Nd leads to magnetic pair breaking and, thus, to a gradual suppression of superconductivity. Pr3Ni2B2N3- exibits no long range magnetic order down to 2 K, Nd3Ni2B2N3- shows ferrimagnetic ordering below TC =17 K and a spin reorientation transition to a nearly antiferromagnetic state at 10 K.

Superstructure formation in the solid solution Sc3Pt3−xIn3 (x = 0–0.93)

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Nataliya L. Gulay ◽  
Rolf-Dieter Hoffmann ◽  
Jutta Kösters ◽  
Yaroslav M. Kalychak ◽  
Stefan Seidel ◽  
...  
Keyword(s):  
Solid Solution ◽  
Diffraction Data ◽  
High Frequency ◽  
Lattice Parameters ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
Platinum Content ◽  
Arc Melting ◽  
Modulation Vector

Abstract The equiatomic indide ScPtIn (ZrNiAl type, space group P 6 ‾ $‾{6}$ 2m) shows an extended solid solution Sc3Pt3–xIn3. Several samples of the Sc3Pt3–xIn3 series were synthesized from the elements by arc-melting and subsequent annealing, or directly in a high frequency furnace. The lowest platinum content was observed for Sc3Pt2.072(3)In3. All samples were characterized by powder X-ray diffraction and their lattice parameters and several single crystals were studied on the basis of precise single crystal X-ray diffractometer data. The correct platinum occupancy parameters were refined from the diffraction data. Decreasing platinum content leads to decreasing a and c lattice parameters. Satellite reflections were observed for the Sc3Pt3–xIn3 crystals with x = 0.31–0.83. These satellite reflections could be described with a modulation vector ( 1 3 , 1 3 , γ ) $\left(\frac{1}{3},\frac{1}{3},\gamma \right)$ ( γ = 1 2 $\gamma =\frac{1}{2}$ c* for all crystals) and are compatible with trigonal symmetry. The interplay of platinum filled vs. empty In6 trigonal prisms is discussed for an approximant structure with space group P3m1.

Sign in / Sign up

Export Citation Format

Share Document