Determination of the Internal Electric Field in the Electrooptic Active Layer of Multilayer Polymer Stacks

1997 ◽  
Vol 488 ◽  
Author(s):  
S. Grossmann ◽  
T. Weyrauch ◽  
W. Haase

AbstractWe report on a method to investigate the inhomogeneous distribution of an electric dc field in multilayer polymer stacks. In situ electroabsorption (EA) measurements are applied in order to estimate the local electric fields in double layer polymer films. The observed time dependent behaviour is compared with a model equivalent circuit. The results indicate that besides the relation of ohmic resistivities and capacities of the different polymer layers in the investigated systems also the influence of the electric properties of polymer/electrode and polymer/polymer interfaces must be considered.

1983 ◽  
Vol 26 ◽  
Author(s):  
Jan Prij ◽  
Leo H. Vons

ABSTRACTResults are presented of in-situ measurements, performed in a 300 m deep dry-drilled borehole, in the ASSEmine. Convergence measurements at ambient as well as elevated temperatures and pressure measurements at elevated temperatures are discussed. Creep equations derived from these experiments are used for the numerical analysis of the time dependent behaviour of a salt dome with a HLW repository. The analyses show that the total stresses in the salt remain compressive with deviatoric components smaller than 3 MPa.


2018 ◽  
Vol 7 (3) ◽  
pp. 1826
Author(s):  
Heyam H. Shaalan ◽  
Mohd Ashraf Mohamad Ismail ◽  
Romziah Azit

Shotcrete is ordinary concrete applied to the surface under high pressure. It demonstrates a highly time-dependent behaviour after few hours of application. Traditional approaches assume a simple linear elastic behaviour using a hypothetical young modulus to investigate the time-dependency and creep effects. In this paper, a new constitutive model of shotcrete is applied to evaluate the time-dependent behaviour of a TBM tunnel lining and investigate the parameters that can influence this behaviour. The Shotcrete model is based on the framework of Elasto-plasticity and designed to model shotcrete linings more realistically. The basic data of Pahang-Selangor Raw Water Transfer Project is used for the analysis study. An attempt is made to investigate the influence of some input parameters of the shotcrete model on the time-dependent behaviour of the shotcrete lining. These parameters include the time-dependent stiffness/strength parameters, creep and shrinkage parameters and steel fibre parameters. The variation in shotcrete strength classes causes a noticeable influence on the development of shotcrete compressive strength with time, particularly during the first days of application. The creep and shrinkage strain cause a considerable reduction in the development of the shotcrete stress with time. The impact of steel fibre content is determined, and the result indicated that the development of plain shotcrete stresses with time is lower than that of the reinforced shotcrete. In addition, a comparison study is performed to analyse the tunnel lining behaviour using both shotcrete model and an elastic analysis. Significant differences in shotcrete lining stresses are achieved when using the elastic analysis while the shotcrete model results in a reasonable result that can be used for the design requirements. 


2021 ◽  
Vol 3 (5) ◽  
Author(s):  
Rajeswara R. Resapu ◽  
Roger D. Bradshaw

Abstract In-vitro mechanical indentation experimentation is performed on bulk liver tissue of lamb to characterize its nonlinear material behaviour. The material response is characterized by a visco-hyperelastic material model by the use of 2-dimensional inverse finite element (FE) analysis. The time-dependent behaviour is characterized by the viscoelastic model represented by a 4-parameter Prony series, whereas the large deformations are modelled using the hyperelastic Neo-Hookean model. The shear response described by the initial and final shear moduli and the corresponding Prony series parameters are optimized using ANSYS with the Root Mean Square (RMS) error being the objective function. Optimized material properties are validated using experimental results obtained under different loading histories. To study the efficacy of a 2D model, a three dimensional (3D) model of the specimen is developed using Micro-CT of the specimen. The initial elastic modulus of the lamb liver obtained was found to 13.5 kPa for 5% indentation depth at a loading rate of 1 mm/sec for 1-cycle. These properties are able to predict the response at 8.33% depth and a loading rate of 5 mm/sec at multiple cycles with reasonable accuracy. Article highlights The visco-hyperelastic model accurately models the large displacement as well as the time-dependent behaviour of the bulk liver tissue. Mapped meshing of the 3D FE model saves computational time and captures localized displacement in an accurate manner. The 2D axisymmetric model while predicting the force response of the bulk tissue, cannot predict the localized deformations.


2021 ◽  
Vol 11 (8) ◽  
pp. 3317
Author(s):  
C.S. Quintans ◽  
Denis Andrienko ◽  
Katrin F. Domke ◽  
Daniel Aravena ◽  
Sangho Koo ◽  
...  

External electric fields (EEFs) have proven to be very efficient in catalysing chemical reactions, even those inaccessible via wet-chemical synthesis. At the single-molecule level, oriented EEFs have been successfully used to promote in situ single-molecule reactions in the absence of chemical catalysts. Here, we elucidate the effect of an EEFs on the structure and conductance of a molecular junction. Employing scanning tunnelling microscopy break junction (STM-BJ) experiments, we form and electrically characterize single-molecule junctions of two tetramethyl carotene isomers. Two discrete conductance signatures show up more prominently at low and high applied voltages which are univocally ascribed to the trans and cis isomers of the carotenoid, respectively. The difference in conductance between both cis-/trans- isomers is in concordance with previous predictions considering π-quantum interference due to the presence of a single gauche defect in the trans isomer. Electronic structure calculations suggest that the electric field polarizes the molecule and mixes the excited states. The mixed states have a (spectroscopically) allowed transition and, therefore, can both promote the cis-isomerization of the molecule and participate in electron transport. Our work opens new routes for the in situ control of isomerisation reactions in single-molecule contacts.


Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 638
Author(s):  
Sanam SaeidNahaei ◽  
Hyun-Jun Jo ◽  
Sang Jo Lee ◽  
Jong Su Kim ◽  
Sang Jun Lee ◽  
...  

For examining the carrier movements through tunnel junction, electrically and optically-biased photoreflectance spectroscopy (EBPR and OBPR) were used to investigate the internal electric field in the InGaP/GaAs dual junction solar cell at room temperature. At InGaP and GaAs, the strength of p-n junction electric fields (Fpn) was perturbed by the external DC bias voltage and CW light intensity for EBPR and OBPR experiments, respectively. Moreover, the Fpn was evaluated using the Fast Fourier Transform (FFT) of the Franz—Keldysh oscillation from PR spectra. In the EBPR, the electric field decreased by increasing the DC bias voltage, which also decreased the potential barrier. In OBPR, when incident CW light is absorbed by the top cell, the decrement of the Fpn in the GaAs cell indicates that the photogenerated carriers are accumulated near the p-n junction. Photogenerated carriers in InGaP can pass through the tunnel junction, and the PR results show the contribution of the modification of the electric field by the photogenerated carriers in each cell. We suggest that PR spectroscopy with optical-bias and electrical-bias could be analyzed using the information of the photogenerated carrier passed through the tunnel junction.


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