Ultra-Low Dielectric Permitfivity Ceramics and Composites for Packaging Applications

1986 ◽  
Vol 72 ◽  
Author(s):  
L. E. Cross ◽  
T. R. Gururaja

AbstractTo accomplish the interconnect systems which will be required in the next generation of very high speed Ga:As digital ICs, it will be necessary to use strip line techniques for signal traces which must be deposited over very low permittivity dielectric substration. Materials with relative dielectric permittivities k 〈 3.0 and very low loss tangent up to microwave frequencies will be required. For ceramic systems such values are impossible to achieve in single phase monoliths, and composite approaches are required. Techniques for processing ceramic insulators which permit the introduction of controlled pore structures are discussed. The introduction of pores degrades some other desirable properties of the ceramic such as mechanical strength and thermal conductivity so that control of both scale and location of pores is desirable.Materials investigated include sol-gel processed silica films and monoliths, reactively sputtered silica, etched glass compositions and Macro-Defect-Free (MDF) cements.

ChemInform ◽  
2001 ◽  
Vol 32 (10) ◽  
pp. no-no
Author(s):  
Seana Seraji ◽  
Yun Wu ◽  
Michael Forbess ◽  
Steven J. Limmer ◽  
Tammy Chou ◽  
...  

1999 ◽  
Vol 594 ◽  
Author(s):  
Mengcheng Lu ◽  
C. Jeffrey Brinker

AbstractLow dielectric constant silica films are made using a surfactant templated sol-gel process (K∼2.5) or an ambient temperature and pressure aerogel process (K∼1.5). This paper will present the in-situ measurement and analysis of stress development during the making of these films, from the onset of drying till the end of heating. The drying stress is measured by a cantilever beam technique; the thermal stress is measured by monitoring the wafer curvature using a laser deflection method. During the course of drying, the surfactant templated films experience a low drying stress due to the influence of the surfactant on surface tension and extent of siloxane condensation. The aerogel films first develop a biaxial tensile stress due to solidification and initial drying. At the final stage of drying where the drying stress vanishes, dilation of the film recreates the porosity of the wet gel state, reducing the residual stress to zero. For the surfactant templated films, very small residual tensile stress remains after the heat treatment is finished (∼30MPa). Aerogel film has almost no measurable stress developed in the calcination process. In situ spectroscopic ellipsometry analysis during drying and heating, and TGA/DTA are all used to help understand the stress development.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000305-000309 ◽  
Author(s):  
Shiro Tatsumi ◽  
Shohei Fujishima ◽  
Hiroyuki Sakauchi

Abstract Build-up process is a highly effective method for miniaturization and high density integration of printed circuit boards. Along with increasing demands for high transmission speed of electronic devices with high functionality, packaging substrates installed with semiconductors in such devices are strongly required to reduce the transmission loss. Our insulation materials are used in a semi-additive process (SAP) with low dielectric loss tangent, smooth resin surface after desmear, and good insulation reliability. Actually, the transmission loss of strip line substrates and Cu surface roughness impact on transmission loss were measured using our materials. Furthermore, low dielectric molding film with low coefficient of thermal expansion (CTE) and low Young's modulus are introduced.


2008 ◽  
Vol 47-50 ◽  
pp. 973-976 ◽  
Author(s):  
Yi He Zhang ◽  
Qing Song Su ◽  
Li Yu ◽  
Hong Zheng ◽  
Hai Tao Huang ◽  
...  

A sol-gel process was used to prepare polyimide-silica hybrid films from the polyimide precursors and TEOS in N,N- dimethyl acetamide, then the hybrid film was treated with hydrofluoric acid to remove the dispersed silica particles, leaving pores with diameters between 80nm to 1µm, depending on the size of silica particles. The structure and dielectric constant of the hybrid and porous films were characterized by FTIR,SEM. The porous films displayed relatively low dielectric constant compared to the hybrid polyimide-silica films.


2011 ◽  
Vol 47 (4) ◽  
pp. 1958-1963 ◽  
Author(s):  
Yihe Zhang ◽  
Li Yu ◽  
Qingsong Su ◽  
Hong Zheng ◽  
Haitao Huang ◽  
...  

1986 ◽  
Vol 72 ◽  
Author(s):  
Amitabh Das ◽  
R. Messier ◽  
T. R. Gururaja ◽  
L. E. Cross

AbstractA novel approach for preparing porous SiO2 thin films by sputter deposi-tion is being developed. The porosity is introduced to reduce the dielectric permittivity of the film to less than 3 for potential use in packaging high speed VLSIs. In the first approach, amorphous silicon is initially deposited to produce a columnar structure with a thickness of 25μm, followed by etching and thermal oxidation to result in closely spaced SiO2 pillars. Capping the structure by a thin film (0.1μm), silica gel layer provides the support for strip line traces. In the second approach, porous SiO2 films are prepared by reactive sputtering. The dielectric properties of the sputter deposited SiO2 films are presented.


2004 ◽  
Vol 462-463 ◽  
pp. 311-315 ◽  
Author(s):  
Suzhu Yu ◽  
Terence K.S. Wong ◽  
Xiao Hu ◽  
Kantisara Pita

2003 ◽  
Vol 788 ◽  
Author(s):  
Nobuyuki Kawakami ◽  
Takayuki Hirano ◽  
Yoshito Fukumoto ◽  
Yoshiyuki Nagase

ABSTRACTSupercritical fluid extraction (SFE) technique which enables to fabricate mesoporous film at low temperature has been developed. Meso-structure silica films are prepared by sol-gel process based on the self-organization of surfactant templates, and the organic templates are successfully extracted from the films by supercritical CO2 (sc-CO2) modified with hydrogen peroxide at 80 °C and 19.6 MPa. The extraction process is analyzed by X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy of the films. In order to discuss the feasibility of such films obtained at low temperature for electronics applications with low dielectric and low dielectric loss, the mechanical properties and the densities of the films are compared with various silica films prepared by different method.


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