Advanced Lateral Crystal Growth of a-Si Thin Films by Double-Pulsed Irradiation of All Solid-State Lasers

2003 ◽  
Vol 762 ◽  
Author(s):  
Toshio Kudo ◽  
Koji Seike ◽  
Kazunori Yamazaki ◽  
Hirohito Komori ◽  
Sachi Yawaka ◽  
...  

AbstractA compact annealing machine with all solid-state green lasers has been developed, which has the advantage of widely adjustable solidification rate through the delay time control of two long pulses (pulse width ~100ns). Advanced lateral crystal growth (ALCG) process has been proved by the double-pulsed all solid-state laser annealing. The laser beam has a line shape 0.1mm wide and 17mm long, and the beam profile on the short axis is quasi-Gaussian (FWHM 0.1mm). Scanning the line beam along the short axis at the 86% overlapping ratio, the lateral crystal growth area of width 14μm, parallel to the long axis, is sequentially formed at the pitch of 14μm towards the scanning direction. The advanced lateral growth mechanism is easily explained as follows: (1) At the first irradiation, twin seed lines of width 4μm, parallel to the long axis, generates at a boundary between a near-complete melting region and a complete melting region. (2) At the second irradiation of scanning step 14μm, the front seed line in the scanning direction grows symmetrically toward both sides. (3) At the third irradiation of scanning step 2x14μm, the seeds laterally grow until stopped by the growing of seeds on both sides. Finally the ALCG process by the scanning line-beam technique like the current ELA enables us to produce the laterally grown Si thin-films sequentially arranging the belt-shaped texture at the pitch of 14μm. The quality of the laterally grown Si films is quite well except for the projections generated by the bump of lateral growing seeds.

2009 ◽  
Vol 94 (26) ◽  
pp. 261908 ◽  
Author(s):  
A. J. Birnbaum ◽  
Y. Lawrence Yao ◽  
U.-J. Chung ◽  
James. S. Im ◽  
X. Huang ◽  
...  

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Lynn Lee ◽  
Jangmi Baek ◽  
Kyung Sun Park ◽  
Yong-EunKoo Lee ◽  
Nabeen K. Shrestha ◽  
...  

2018 ◽  
Vol 18 (7) ◽  
pp. 4103-4110 ◽  
Author(s):  
Jaroslav Barták ◽  
Diego Valdés ◽  
Jiří Málek ◽  
Veronika Podzemná ◽  
Stanislav Slang ◽  
...  

Author(s):  
F. Ma ◽  
S. Vivekanand ◽  
K. Barmak ◽  
C. Michaelsen

Solid state reactions in sputter-deposited Nb/Al multilayer thin films have been studied by transmission and analytical electron microscopy (TEM/AEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The Nb/Al multilayer thin films for TEM studies were sputter-deposited on (1102)sapphire substrates. The periodicity of the films is in the range 10-500 nm. The overall composition of the films are 1/3, 2/1, and 3/1 Nb/Al, corresponding to the stoichiometric composition of the three intermetallic phases in this system.Figure 1 is a TEM micrograph of an as-deposited film with periodicity A = dA1 + dNb = 72 nm, where d's are layer thicknesses. The polycrystalline nature of the Al and Nb layers with their columnar grain structure is evident in the figure. Both Nb and Al layers exhibit crystallographic texture, with the electron diffraction pattern for this film showing stronger diffraction spots in the direction normal to the multilayer. The X-ray diffraction patterns of all films are dominated by the Al(l 11) and Nb(l 10) peaks and show a merging of these two peaks with decreasing periodicity.


Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1494
Author(s):  
Mustapha El Hariri El Nokab ◽  
Khaled O. Sebakhy

Solid-state NMR has proven to be a versatile technique for studying the chemical structure, 3D structure and dynamics of all sorts of chemical compounds. In nanotechnology and particularly in thin films, the study of chemical modification, molecular packing, end chain motion, distance determination and solvent-matrix interactions is essential for controlling the final product properties and applications. Despite its atomic-level research capabilities and recent technical advancements, solid-state NMR is still lacking behind other spectroscopic techniques in the field of thin films due to the underestimation of NMR capabilities, availability, great variety of nuclei and pulse sequences, lack of sensitivity for quadrupole nuclei and time-consuming experiments. This article will comprehensively and critically review the work done by solid-state NMR on different types of thin films and the most advanced NMR strategies, which are beyond conventional, and the hardware design used to overcome the technical issues in thin-film research.


JOM ◽  
2021 ◽  
Author(s):  
Evgeny T. Moiseenko ◽  
Sergey M. Zharkov ◽  
Roman R. Altunin ◽  
Oleg V. Belousov ◽  
Leonid A. Solovyov ◽  
...  

2020 ◽  
Vol 2 (12) ◽  
pp. 3880-3888
Author(s):  
Jian Hui ◽  
Qingyun Hu ◽  
Yuxi Luo ◽  
Tianxing Lai ◽  
Zhan Zhang ◽  
...  

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Cheng Li ◽  
Yu Hui Huang ◽  
Jian-Jun Wang ◽  
Bo Wang ◽  
Yong Jun Wu ◽  
...  

AbstractSolid-state refrigeration which is environmentally benign has attracted considerable attention. Mechanocaloric (mC) materials, in which the phase transitions can be induced by mechanical stresses, represent one of the most promising types of solid-state caloric materials. Herein, we have developed a thermodynamic phenomenological model and predicted extraordinarily large elastocaloric (eC) strengths for the (111)-oriented metal-free perovskite ferroelectric [MDABCO](NH4)I3 thin-films. The predicted room temperature isothermal eC ΔSeC/Δσ (eC entropy change under unit stress change) and adiabatic eC ΔTeC/Δσ (eC temperature change under unit stress change) for [MDABCO](NH4)I3 are −60.0 J K−1 kg−1 GPa−1 and 17.9 K GPa−1, respectively, which are 20 times higher than the traditional ferroelectric oxides such as BaTiO3 thin films. We have also demonstrated that the eC performance can be improved by reducing the Young’s modulus or enhancing the thermal expansion coefficient (which could be realized through chemical doping, etc.). We expect these discoveries to spur further interest in the potential applications of metal-free organic ferroelectrics materials towards next-generation eC refrigeration devices.


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