Shear thinning of the bulk metallic glass forming alloy Zr41.2 Ti13.8 Cu12.5 Ni10.0 Be22.5 close to the liquidus temperature.

2003 ◽  
Vol 806 ◽  
Author(s):  
Tyler Shaw ◽  
Christopher Way ◽  
Ralf Busch

ABSTRACTThe viscous properties of the multi component Zr41.2 Ti13.8 Cu12.5 Ni10.0 Be22.5 bulk metallic glass forming alloy was studied above the liquidus temperature. A shear thinning behavior for the molten alloy has been discovered. The shear thinning behavior can be characterized as a power law fluid with a power-law index of -0.5. Additionally, at low shear rates and temperatures near the liquidus temperature a visco-elastic type response in the flow behavior is observed.

Author(s):  
Hossam M. Metwally ◽  
Raj M. Manglik

The enhanced heat transfer in laminar viscoplastic, shear thinning, Herschel-Bulkley fluid flows in sinusoidal corrugated-plate channels is investigated. With uniform-temperature plate walls, periodically developed flows are considered for a wide range of flow rates (10 ≤ Reg ≤ 700) and pseudoplastic flow behavior indices (n = 0.54, 0.8, and 1.0; the latter representing a Bingham plastic). The effects of fluid yield stress are simulated for the case where τy = 1.59 N/m2, representing a 0.5% xantham gum aqueous solution. Typical velocity and temperature distributions, along with extended results for isothermal friction factor ƒ and Colburn factor j are presented. The effect of the yield stress is found to be most dominant at low Reg regardless of the power law index n, and the recirculation or swirl in the wall trough regions is weaker than in the cases of Newtonian and power-law liquids. At higher Reg, the performance of the Herschel-Bulkley fluid asymptotically approaches that of the non-yield-stress power-law fluid. At low Reg, the yield stress increases ƒ by an order of magnitude and j is enhanced because of the higher wall gradients imposed by the plug-like flow field. The relative heat transfer enhancement, represented by the ratio (j/ƒ), and the role of the fluid yield stress and shear-thinning (or pseudoplastic) behaviors are also discussed.


Author(s):  
Khaled J. Hammad

Abstract The flow structure and decay characteristics of submerged annular yield-pseudoplastic jets are investigated. Numerical solutions to the governing mass and momentum conservation equations, along with the Herschel-Bulkley rheological model, are obtained using a finite-difference scheme. A parametric study is implemented to investigate the effects of annular nozzle diameter ratio, κ, the power-law index, n, and yield number, Y, over the following range: κ = {0, 0.5}; n = {1, 0.6}; and Y = {0, 1, 5}. The Reynolds number was fixed at Re = 100, which ensured steady and laminar jet flow conditions throughout the whole flow field. The selected yield number and power-law index values allowed for the investigation of the presence of yield stress and shear-thinning effects on the resulting structure and evolution of the flow field. The results demonstrate the substantial impact of the inflow conditions and rheology on the annular jet evolution, and on the extent of the outer recirculation region and recirculation strength of both the outer and central regions.


2003 ◽  
Vol 18 (9) ◽  
pp. 2039-2049 ◽  
Author(s):  
Jun Lu ◽  
Guruswami Ravichandran

An experimental study of the inelastic deformation of bulk metallic glass Zr41.2Ti13.8Cu12.5Ni10Be22.5 under multiaxial compression using a confining sleeve technique is presented. In contrast to the catastrophic shear failure (brittle) in uniaxial compression, the metallic glass exhibited large inelastic deformation of more than 10% under confinement, demonstrating the nature of ductile deformation under constrained conditions in spite of the long-range disordered characteristic of the material. It was found that the metallic glass followed a pressure (p) dependent Tresca criterion τ = τ0 + βp, and the coefficient of the pressure dependence β was 0.17. Multiple parallel shear bands oriented at 45° to the loading direction were observed on the surfaces of the deformed specimens and were responsible for the overall inelastic deformation.


1996 ◽  
Vol 455 ◽  
Author(s):  
Ralf Busch ◽  
Andreas Masuhr ◽  
Eric Bakke ◽  
William L. Johnson

ABSTRACTThe viscosities of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 and the Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass forming liquids was determined from the melting point down to the glass transition in the entire temperature range of the supercooled liquid. The temperature dependence of the viscosity in the supercooled liquid obeys the Vogel-Fulcher-Tammann (VFT) relation. The fragility index D is about 20 for both alloys and the ratio between glass transition temperature and VFT temperature is found to be 1.5. A comparison with other glass forming systems shows that these bulk metallic glass formers are strong liquids comparable to sodium silicate glass. Furthermore, they are the strongest among metallic glass forming liquids. This behavior is a main contributing factor to the glass forming ability since it implicates a higher viscosity from the melting point down to the glass transition compared to other metallic liquids. Thus, the kinetics in the supercooled liquid is sluggish and yields a low critical cooling rate for glass formation. The relaxation behavior in the glass transition region of the alloys is consistent with their strong glassy nature as reflected by a stretching exponent that is close to 0.8. The microscopic origin of the strong liquid behavior of bulk metallic glass formers is discussed.


2010 ◽  
Vol 24 (15n16) ◽  
pp. 2320-2325 ◽  
Author(s):  
JIANSHENG GU ◽  
BINGCHEN WEI ◽  
TAIHUA ZHANG ◽  
YIHUI FENG ◽  
YANPING HU ◽  
...  

Structural relaxation by isothermal annealing below the glass transition temperature is conducted on a Zr 64.13 Cu 15.75 Ni 10.12 Al 10 bulk metallic glass. The effect of structural relaxation on thermal and mechanical properties was investigated by differential scanning calorimetry and instrumented nanoindentation. The recovery of the enthalpy in the DSC curves indicates that thermally unstable defects were annihilated through structural relaxation. During nanoindentation, the structural relaxation did not have a significant influence on the serrated plastic flow behavior. However, Structural relaxation shows an obvious effect in increasing both the hardness and elastic modulus, which is attributed to the annihilation of thermally unstable defects that resulted from the relaxation.


2014 ◽  
Vol 105 (20) ◽  
pp. 201906 ◽  
Author(s):  
Si Lan ◽  
Xiaoya Wei ◽  
Jie Zhou ◽  
Zhaoping Lu ◽  
Xuelian Wu ◽  
...  

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