scholarly journals In-situ study of crystallization kinetics in ternary bulk metallic glass alloys with different glass forming abilities

2014 ◽  
Vol 105 (20) ◽  
pp. 201906 ◽  
Author(s):  
Si Lan ◽  
Xiaoya Wei ◽  
Jie Zhou ◽  
Zhaoping Lu ◽  
Xuelian Wu ◽  
...  
2021 ◽  
pp. 111001
Author(s):  
Lunyong Zhang ◽  
B.T. Jiang ◽  
Y.F. Liang ◽  
Y.J. Huang ◽  
J.F. Sun

2019 ◽  
Vol 112 ◽  
pp. 106523 ◽  
Author(s):  
Songshan Jiang ◽  
Shu Guo ◽  
Yongjiang Huang ◽  
Zhiliang Ning ◽  
Peng Xue ◽  
...  

2002 ◽  
Vol 17 (12) ◽  
pp. 3015-3018 ◽  
Author(s):  
G. He ◽  
W. Löser ◽  
J. Eckert ◽  
L. Schultz

A bulk metallic glass-forming Ti–Cu–Ni–Sn alloy with in situ formed composite microstructure prepared by both centrifugal and injection casting presents more than 6% plastic strain under compressive stress at room temperature. The in situ formed composite contains dendritic hexagonal-close-packed-Ti solid solution precipitates and a few Ti3Sn, β –(Cu, Sn) grains dispersed in a glassy matrix. The composite microstructure can avoid the development of the highly localized shear bands typical for the room-temperature deformation of monolithic glasses. Instead, highly developed shear bands with evident protuberance are observed, resulting in significant yielding and homogeneous plastic deformation over the entire sample.


1998 ◽  
Vol 554 ◽  
Author(s):  
Ralf Busch ◽  
Andreas Masuhr ◽  
Eric Bakke ◽  
T. Andy Waniuk ◽  
William L. Johnson

AbstractThe high thermal stability of bulk metallic glass (BMG) forming liquids in the undercooled state allows for measurements of thermophysical properties in a large time and temperature window. In this contribution, results on viscous flow, relaxation and crystallization of Zr-Ti-Cu- Ni-Be BMG forming alloys are presented. The data are compared with the kinetics of other metallic and non-metallic liquids. BMG formers are relatively strong liquids with melt viscosities that are about three orders of magnitude larger than in pure metals and other alloys. The strong liquid behavior of these alloys is also reflected by a small entropy of fusion and a weak temperature dependence of the thermodynamic functions upon undercooling. The high viscosity and small driving force for crystallization are major contributing factors to the high glass forming ability and low critical cooling rate. The upper portions of experimental timetemperature- transformation diagrams down to the crystallization nose can be described well using the kinetics deduced from the viscosity data. For lower temperature the viscosity can not describe the crystallization kinetics. The time scale for structural relaxation becomes larger than for diffusive hopping processes. Diffusion stays relatively fast, whereas viscosity and structural relaxation time upon undercooling follow a Vogel-Fulcher-Tammann relation.


Sign in / Sign up

Export Citation Format

Share Document