Materials Characteristics and Dissolution Behavior of Spent Nuclear Fuel

MRS Bulletin ◽  
1994 ◽  
Vol 19 (12) ◽  
pp. 24-27 ◽  
Author(s):  
L.H. Johnson ◽  
L.O. Werme
Keyword(s):  
Nuclear Fuel ◽  
Nuclear Waste ◽  
Nuclear Power ◽  
Spent Nuclear Fuel ◽  
Fission Products ◽  
Waste Form ◽  
Dissolution Behavior ◽  
Spent Fuel ◽  
Power Stations ◽  
Geologic Disposal

The geologic disposal of spent nuclear fuel is currently under consideration in many countries. Most of this fuel is in the form of assemblies of zirconium-alloy-clad rods containing enriched (1–4% 235U) or natural (0.71% 235U) uranium oxide pellets. Approximately 135,000 Mg are presently in temporary storage facilities throughout the world in nations with commercial nuclear power stations.Safe geologic disposal of nuclear waste could be achieved using a combination of a natural barrier (the host rock of the repository) and engineered barriers, which would include a low-solubility waste form, long-lived containers, and clay- and cement-based barriers surrounding the waste containers and sealing the excavations.A requirement in evaluating the safety of disposal of nuclear waste is a knowledge of the kinetics and mechanism of dissolution of the waste form in groundwater and the solubility of the waste form constituents. In the case of spent nuclear fuel, this means developing an understanding of fuel microstructure, its impact on release of contained fission products, and the dissolution behavior of spent fuel and of UO2, the principal constituent of the fuel.

Distribution of Palladium During Spent Fuel Reprocessing

2003 ◽  
Author(s):  
Yu. Pokhitonov ◽  
V. Romanovski ◽  
P. Rance
Keyword(s):  
Nuclear Fuel ◽  
Nuclear Power ◽  
Spent Nuclear Fuel ◽  
Fission Products ◽  
Platinum Group Metals ◽  
Spent Fuel ◽  
Platinum Metals ◽  
Spent Fuel Reprocessing ◽  
Platinum Group ◽  
Fuel Reprocessing

The principal purpose of spent fuel reprocessing consists in the recovery of the uranium and plutonium and the separation of fission products so as to allow re-use of fissile and fertile isotopes and facilitate disposal of waste elements. Amongst the fission products present in spent nuclear fuel of Nuclear Power Plants (NPPs,) there are considerable quantities of platinum group metals (PGMs): ruthenium, rhodium and palladium. Given current predictions for nuclear power generation, it is predicted that the quantities of palladium to be accumulated by the middle of this century will be comparable with those of the natural sources, and the quantities of rhodium in spent nuclear fuel may even exceed those in natural sources. These facts allow one to consider spent nuclear fuel generated by NPPs as a potential source for creation of a strategic stock of platinum group metals. Despite of a rather strong prediction of growth of palladium consumption, demand for “reactor” palladium in industry should not be expected because it contains a long-lived radioactive isotope 107Pd (half-life 6,5·105 years) and will thus be radioactive for a very considerable period, which, naturally, restricts its possible applications. It is presently difficult to predict all the areas for potential use of “reactor” palladium in the future, but one can envisage that the use of palladium in radwaste reprocessing technology (e.g. immobilization of iodine-129 and trans-plutonium elements) and in the hydrogen energy cycle may play a decisive role in developing the demand for this metal. Realization of platinum metals recovery operation before HLW vitrification will also have one further benefit, namely to simplify the vitrification process, because platinum group metals may in certain circumstances have adverse effects on the vitrification process. The paper will report data on platinum metals (PGM) distribution in spent fuel reprocessing products and the different alternatives of palladium separation flowsheets from HLW are presented. It is shown, that spent fuel dissolution conditions can affect the palladium distribution between solution and insoluble precipitates. The most important factors, which determine the composition and the yield of residues resulting from fuel dissolution, are the temperature and acid concentration. Apparently, a careful selection of fuel dissolution process parameters would make it possible to direct the main part of palladium to the 1st cycle raffinate together with the other fission products. In the authors’ opinion, the development of an efficient technology for palladium recovery requires the conception of a suitable flow-sheet and the choice of optimal regimes of “reactor” palladium recovery concurrently with the resolution of the problem of HLW partitioning when using the same facilities.

Developing a Concept for a National Used Fuel Interim Storage Facility in the United States

2013 ◽  
Author(s):  
Donald Wayne Lewis
Keyword(s):  
United States ◽  
Nuclear Fuel ◽  
Nuclear Waste ◽  
Spent Nuclear Fuel ◽  
The United States ◽  
Yucca Mountain ◽  
Storage Facility ◽  
Spent Fuel ◽  
Geological Repository ◽  
Interim Storage

In the United States (U.S.) the nuclear waste issue has plagued the nuclear industry for decades. Originally, spent fuel was to be reprocessed but with the threat of nuclear proliferation, spent fuel reprocessing has been eliminated, at least for now. In 1983, the Nuclear Waste Policy Act of 1982 [1] was established, authorizing development of one or more spent fuel and high-level nuclear waste geological repositories and a consolidated national storage facility, called a “Monitored Retrievable Storage” facility, that could store the spent nuclear fuel until it could be placed into the geological repository. Plans were under way to build a geological repository, Yucca Mountain, but with the decision by President Obama to terminate the development of Yucca Mountain, a consolidated national storage facility that can store spent fuel for an interim period until a new repository is established has become very important. Since reactor sites have not been able to wait for the government to come up with a storage or disposal location, spent fuel remains in wet or dry storage at each nuclear plant. The purpose of this paper is to present a concept developed to address the DOE’s goals stated above. This concept was developed over the past few months by collaboration between the DOE and industry experts that have experience in designing spent nuclear fuel facilities. The paper examines the current spent fuel storage conditions at shutdown reactor sites, operating reactor sites, and the type of storage systems (transportable versus non-transportable, welded or bolted). The concept lays out the basis for a pilot storage facility to house spent fuel from shutdown reactor sites and then how the pilot facility can be enlarged to a larger full scale consolidated interim storage facility.

Centralization of Canada’s Spent Nuclear Fuel

2013 ◽  
Author(s):  
Krista Nicholson ◽  
John McDonald ◽  
Shona Draper ◽  
Brian M. Ikeda ◽  
Igor Pioro
Keyword(s):  
Nuclear Fuel ◽  
Site Selection ◽  
Nuclear Power ◽  
Power Plants ◽  
Spent Nuclear Fuel ◽  
Selection Process ◽  
Spent Fuel ◽  
Geologic Repository ◽  
Candu Reactors ◽  
High Level

Currently in Canada, spent fuel produced from Nuclear Power Plants (NPPs) is in the interim storage all across the country. It is Canada’s long-term strategy to have a national geologic repository for the disposal of spent nuclear fuel for CANada Deuterium Uranium (CANDU) reactors. The initial problem is to identify a means to centralize Canada’s spent nuclear fuel. The objective of this paper is to present a solution for the transportation issues that surround centralizing the waste. This paper reviews three major components of managing and the transporting of high-level nuclear waste: 1) site selection, 2) containment and 3) the proposed transportation method. The site has been selected based upon several factors including proximity to railways and highways. These factors play an important role in the site-selection process since the location must be accessible and ideally to be far from communities. For the containment of the spent fuel during transportation, a copper-shell container with a steel structural infrastructure was selected based on good thermal, structural, and corrosion resistance properties has been designed. Rail has been selected as the method of transporting the container due to both the potential to accommodate several containers at once and the extensive railway system in Canada.

Leaching of Spent Fuel under Anaerobic and Reducing Conditions

2002 ◽  
Vol 757 ◽  
Author(s):  
Yngve Albinsson ◽  
Arvid Ödegaard-Jensen ◽  
Virginia M. Oversby ◽  
Lars O. Werme
Keyword(s):  
Spent Nuclear Fuel ◽  
Fission Products ◽  
Bentonite Clay ◽  
Fluid Phase ◽  
Inert Atmosphere ◽  
Dissolution Behavior ◽  
Spent Fuel ◽  
Geologic Repository ◽  
Reducing Conditions ◽  
Reaction Vessels

ABSTRACTSweden plans to dispose of spent nuclear fuel in a deep geologic repository in granitic rock. The disposal conditions allow water to contact the canisters by diffusion through the surrounding bentonite clay layer. Corrosion of the canister iron insert will consume oxygen and provide actively reducing conditions in the fluid phase. Experiments with spent fuel have been done to determine the dissolution behavior of the fuel matrix and associated fission products and actinides under conditions ranging from inert atmosphere to reducing conditions in solutions. Data for U, Pu, Np, Cs, Sr, Tc, Mo, and Ru have been obtained for dissolution in a dilute NaHCO3 groundwater for 3 conditions: Ar atmosphere, H2 atmosphere, and H2 atmosphere with Fe(II) in solution. Solution concentrations forU, Pu, and Mo are all significantly lower for the conditions that include Fe(II) ions in the solutions together with H2 atmosphere, while concentrations of the other elements seem to be unaffected by the change of atmospheres or presence of Fe(II). Most of the material that initially dissolved from the fuel has reprecipitated back onto the fuel surface. Very little material was recovered from rinsing and acid stripping of the reaction vessels.

scholarly journals Approaches to Safety Justification for Loading of VSC-VVER Containers in ZNPP DSFSF

2019 ◽  
pp. 82-87
Author(s):  
Ya. Kostiushko ◽  
O. Dudka ◽  
Yu. Kovbasenko ◽  
A. Shepitchak
Keyword(s):  
Nuclear Fuel ◽  
Nuclear Power ◽  
Safety Assessment ◽  
Power Plants ◽  
Spent Nuclear Fuel ◽  
Operating Conditions ◽  
Spent Fuel ◽  
Fuel Assemblies ◽  
Fuel Storage ◽  
The Government

The introduction of new fuel for nuclear power plants in Ukraine is related to obtaining a relevant license from the regulatory authority for nuclear and radiation safety of Ukraine. The same approach is used for spent nuclear fuel (SNF) management system. The dry spent fuel storage facility (DSFSF) is the first nuclear facility created for intermediate dry storage of SNF in Ukraine. According to the design based on dry ventilated container storage technology by Sierra Nuclear Corporation and Duke Engineering and Services, ventilated storage containers (VSC-VVER) filled with SNF of VVER-1000 are used, which are located on a special open concrete site. Containers VSC-VVER are modernized VSC-24 containers customized for hexagonal VVER-1000 spent fuel assemblies. The storage safety assessment methodology was created and improved directly during the licensing process. In addition, in accordance with the Energy Strategy of Ukraine up to 2035, one of the key task is the further diversification of nuclear fuel suppliers. Within the framework of the Executive Agreement between the Government of Ukraine and the U.S. Government, activities have been underway since 2000 on the introduction of Westinghouse fuel. The purpose of this project is to develop, supply and qualify alternative nuclear fuel compatible with fuel produced in Russia for Ukrainian NPPs. In addition, a supplementary approach to safety analysis report is being developed to justify feasibility of loading new fuel into the DSFSF containers. The stated results should demonstrate the fulfillment of design criteria under normal operating conditions, abnormal conditions and design-basis accidents of DSFSF components.  Thus, the paper highlights both the main problems of DSFSF licensing and obtaining permission for placing new fuel types in DSFSF.

Thermal Analysis for Geologic Codisposal of SNF Packages

2002 ◽  
Author(s):  
Si Y. Lee
Keyword(s):  
Thermal Analysis ◽  
Nuclear Fuel ◽  
Spent Nuclear Fuel ◽  
Peripheral Region ◽  
Waste Form ◽  
Temperature History ◽  
High Level Waste ◽  
Geologic Repository ◽  
Geologic Disposal ◽  
High Level

The engineering viability of disposal of aluminum-clad, aluminum-based spent nuclear fuel (Al-SNF) in a geologic repository requires a thermal analysis to provide the temperature history of the waste form. Calculated temperatures are used to demonstrate compliance with criteria for waste acceptance into the geologic disposal system and as input to assess the chemical and physical behavior of the waste form within the Waste Package (WP). The leading codisposal WP design proposes that a central DOE Al-SNF canister be surrounded by five Defense Waste Process Facility (DWPF) glass log canisters, that is, High-level Waste Glass Logs (HWGL’s), and placed into a WP in a geologic disposal system. A DOE SNF canister having about 0.4318m diameter is placed along the central horizontal axis of the WP. The five HWGL’s will be located around the peripheral region of the DOE SNF canister within the cylindrical WP container. The codisposal WP will be laid down horizontally in a drift repository. In this situation, two waste form options for Al-SNF disposition are considered using the codisposal WP design configurations. They are the direct Al-SNF form and the melt-dilute ingot. In the present work, the reference geologic and design conditions are assumed for the analysis even though the detailed package design is continuously evolved. This paper primarily dealt with the thermal performance internal to the codisposal WP for the qualification study of the WP containing Al-SNF. Thermal analysis methodology and decay heat source terms have been developed to calculate peak temperatures and temperature profiles of Al-SNF package in the DOE spent nuclear fuel canister within the geologic codisposal WP.

Measurement of Atmospheric Sea Salt Concentration in the Dry Storage Facility of the Spent Nuclear Fuel

2006 ◽  
Author(s):  
Masumi Wataru ◽  
Hisashi Kato ◽  
Satoshi Kudo ◽  
Naoko Oshima ◽  
Koji Wada ◽  
...  
Keyword(s):  
Nuclear Fuel ◽  
Nuclear Power ◽  
Spent Nuclear Fuel ◽  
Sea Salt ◽  
Storage Facility ◽  
Japan Society ◽  
Spent Fuel ◽  
Dry Storage ◽  
Storage Methods ◽  
Interim Storage

Spent nuclear fuel coming from a Japanese nuclear power plant is stored in the interim storage facility before reprocessing. There are two types of the storage methods which are wet and dry type. In Japan, it is anticipated that the dry storage facility will increase compared with the wet type facility. The dry interim storage facility using the metal cask has been operated in Japan. In another dry storage technology, there is a concrete overpack. Especially in USA, a lot of concrete overpacks are used for the dry interim storage. In Japan, for the concrete cask, the codes of the Japan Society of Mechanical Engineers and the governmental technical guidelines are prepared for the realization of the interim storage as well as the code for the metal cask. But the interim storage using the concrete overpack has not been in progress because the evaluation on the stress corrosion cracking (SCC) of the canister is not sufficient. Japanese interim storage facilities would be constructed near the seashore. The metal casks and concrete overpacks are stored in the storage building in Japan. On the other hand, in USA they are stored outside. It is necessary to remove the decay heat of the spent nuclear fuel in the cask from the storage building. Generally, the heat is removed by natural cooling in the dry storage facility. Air including the sea salt particles goes into the dry storage facility (Figure 1). Concerning the concrete overpack, air goes into the cask body and cools the canister. Air goes along the canister surface and is in contact with the surface directly. In this case, the sea salt in the air attaches to the surface and then there is the concern about the occurrence of the SCC. For the concrete overpack, the canister including the spent fuel is sealed by the welding. The loss of sealability caused by the SCC has to be avoided. To evaluate the SCC for the canister, it is necessary to make clear the amount of the sea salt particles coming into the storage building and the concentration on the canister. In present, the evaluation on that point is not sufficient. In this study, the concentration of the sea salt particles in the air and on the surface of the storage facility are measured inside and outside of the building. For the measurement, two sites of the dry storage facility using the metal cask are chosen. This data is applicable for the evaluation on the SCC of the canister to realize the interim storage using the concrete overpack.

scholarly journals Minimizing the Standard Deviation of the Thermal Load in the Spent Nuclear Fuel Cask Loading Problem

Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4869
Author(s):  
Joaquín Bautista-Valhondo ◽  
Lluís Batet ◽  
Manuel Mateo
Keyword(s):  
Standard Deviation ◽  
Nuclear Fuel ◽  
Thermal Load ◽  
Nuclear Power ◽  
Spent Nuclear Fuel ◽  
Search Algorithm ◽  
Deterministic Algorithm ◽  
Mixed Integer ◽  
Spent Fuel ◽  
Fuel Assemblies

The paper assumes that, at the end of the operational period of a Spanish nuclear power plant, an Independent Spent Fuel Storage Installation will be used for long-term storage. Spent fuel assemblies are selected and transferred to casks for dry storage, with a series of imposed restrictions (e.g., limiting the thermal load). In this context, we present a variant of the problem of spent nuclear fuel cask loading in one stage (i.e., the fuel is completely transferred from the spent fuel pool to the casks at once), offering a multi-start metaheuristic of three phases. (1) A mixed integer linear programming (MILP-1) model is used to minimize the cost of the casks required. (2) A deterministic algorithm (A1) assigns the spent fuel assemblies to a specific region of a specific cask based on an MILP-1 solution. (3) Starting from the A1 solutions, a local search algorithm (A2) minimizes the standard deviation of the thermal load among casks. Instances with 1200 fuel assemblies (and six intervals for the decay heat) are optimally solved by MILP-1 plus A1 in less than one second. Additionally, A2 gets a Pearson’s coefficient of variation lower than 0.75% in less than 260s CPU (1000 iterations).

Simulation and Analysis: The Dose Distribution of KBS-3 Spent Nuclear Fuel Canister by MCNP

2010 ◽  
Author(s):  
Bo Yang ◽  
He-xi Wu ◽  
Yi-bao Liu
Keyword(s):  
Cast Iron ◽  
Radioactive Waste ◽  
Nuclear Fuel ◽  
Nuclear Power ◽  
Power Plants ◽  
Spent Nuclear Fuel ◽  
Ductile Cast Iron ◽  
Nuclear Industry ◽  
Spent Fuel ◽  
High Level

With the sustained and rapid development of the nuclear power plants, the spent fuel which is produced by the nuclear power plants will be rapidly rising. Spent fuel is High-level radioactive waste and should be disposed safely, which is important for the environment of land, public safety and health of the nuclear industry, the major issues of sustainable development and it is also necessary part for the nuclear industry activities. It is important to study and resolve the high-level radioactive waste repository problem. Spent nuclear fuel is an important component in the radioactive waste, The KBS-3 canister for geological disposal of spent nuclear fuel in Sweden consists of a ductile cast iron insert and a copper shielding. The ductile cast iron insert provides the mechanical strength whereas the copper protects the canister from corrosion. The canister inserts material were referred to as I24, I25 and I26, Spent nuclear fuel make the repository in high radiant intensity. The radiation analysis of canister insert is important in canister transport, the dose analysis of repository and groundwater radiolysis. Groundwater radiolysis, which produces oxidants (H2O2 and O2), will break the deep repository for spent nuclear fuel. The dose distribution of canister surface with different kinds of canister inserts (I24, I25 and I26) is calculated by MCNP (Ref. 1). Analysing the calculation results, we offer a reference for selecting canister inserts material.

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