scholarly journals Development of rapid-hardening ultra-high strength cementitious composites using superzeolite and N-C-S-H-PCE alkaline nanomodifier

2021 ◽  
Vol 5 (6 (113)) ◽  
pp. 62-72
Author(s):  
Myroslav Sanytsky ◽  
Tetiana Kropyvnytska ◽  
Iryna Нeviuk ◽  
Pawel Sikora ◽  
Serhii Braichenko

It is shown that high operational reliability of structural materials, in particular at high temperatures, is achieved through the use of ultra-high strength cement composites. Studies of various types of Portland cements with mineral additives of the CEM II/A type have established that a stone based on Portland cement with superzeolite is the most resistant to high temperatures. It has been proven that due to the "self-autoclaving" effect, the strength of a stone based on CEM II/A-P 42.5 R is 1.2–1.3 times higher than a stone based on other types of CEM II/A. To obtain fast-hardening cement composites, a nanotechnological approach based on the use of sol-gel technology has been implemented. Using the methods of IR spectroscopy, electron microscopy, the fact of obtaining, by the chemical method of synthesis, an alkaline nanomodifier N-C-S-H-PCE, which is a nano–liquid based on nano-core seeds of sodium/calcium hydrosilicates, has been proved. It has been confirmed that the introduction of the alkaline nanomodifier N-C-S-H-PCE provides a significant intensification of the early structure formation processes in the paste based on Portland cement with superzeolite (after 12 hours, 24 hours and 28 days, the strength is 16.9; 30.5 and 104.1 MPa). It has been established that the complex combination of Portland cement with superzeolite, corundum aggregate, basalt fiber and alkaline nanomodifier provides rapid-hardening of ultra-high strength cement composites (T=400 °C) with improved operational properties. Thus, there is reason to assert the feasibility of developing rapid-hardening ultra-high strength cementitious composites. This solves the problems associated with the need to increase their early strength and performance. As a result, it is possible to carry out repair work to protect equipment from abrasive wear at elevated temperatures

Alloy Digest ◽  
1984 ◽  
Vol 33 (8) ◽  

Abstract EASTERN STAINLESS TYPE 310S has high resistance to corrosion and oxidation at high temperatures. It also has high strength at elevated temperatures. Thus it is especially suitable for service at high temperatures. It is very ductile and can be welded readily. Among the many applications for Type 310S, a few typical uses include annealing boxes, chemical plant equipment, fire box sheets, furnace linings, heat exchangers, oil-refining equipment, kiln linings and tube hangers. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-450. Producer or source: Eastern Stainless Steel Company.


2015 ◽  
Vol 824 ◽  
pp. 121-125
Author(s):  
Veronika Špedlová ◽  
Dana Koňáková

In this paper, there are summarized the results of an experimental program focused on basic, mechanical and thermal properties of cement composites according to the high – temperature loading. Four different materials were studied, which differed in used kind of cement and amount of fibers. As a matrix for studied composites the aluminous cement was chosen because of its resistance in high temperature. For a comparison the Portland cement was also tested. The second main ingredient used to provide better resistance in high temperatures - the basalt aggregate, was mixed in every specimen. The basalt fibers were chosen for two of the measured samples, remaining two ones were tested without fibers. The obtained data in this presented analyses show that the application of the aluminous cement leads to increase (depending on temperature) of porosity, which is the cause of decreasing of the coefficient of thermal conductivity. It can seems, that these cement composites will have low mechanical strength in high temperatures, but because of better sintering, the aluminous cement keeps its strength in high temperatures better than Portland cement.


2011 ◽  
Vol 374-377 ◽  
pp. 2456-2460
Author(s):  
Guo Can Chen ◽  
Zhi Sheng Xu ◽  
Wei Hong Tang

This paper presents the results of experimental studies on the residual compressive strength of concrete produced with stone-chip as fine aggregates with the compressive strengths of unheated specimen ranging from 45.8 to 129.5MPa after exposure to high temperatures and the experimental parameters being the temperature, admixtures, and PP fiber. Specimens were heated in an electric furnace for 4h to high temperatures ranging from 150 to 960°C. Experimental results showed that the compressive strengths of super high strength concrete used stone-chip (abbreviated to SHSCUS) and normal strength concrete used stone-chip (abbreviated to NSCUS) after exposure to elevated temperatures changed in the manners different from that of normal strength concrete, which reached their peak at about 400°C, and the presence of pp fibers in SHSCUS concrete could reduce the risk of spalling at the high temperatures and the peak value after fire.


Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5313 ◽  
Author(s):  
Nao Lv ◽  
Hai-bo Wang ◽  
Qi Zong ◽  
Meng-xiang Wang ◽  
Bing Cheng

In view of the devastating outcomes of fires and explosions, it is imperative to research the dynamic responses of concrete structures at high temperatures. For this purpose, the effects of the strain rate and high temperatures on the dynamic tension behavior and energy characteristics of high-strength concrete were investigated in this paper. Dynamic tests were conducted on high-strength concrete after exposure to the temperatures of 200, 400, and 600 °C by utilizing a 74 mm diameter split Hopkinson pressure bar (SHPB) apparatus. We found that the quasi-static and dynamic tensile strength of high-strength concrete gradually decreased and that the damage degree rose sharply with the rise of temperature. The dynamic tensile strength and specific energy absorption of high-strength concrete had a significant strain rate effect. The crack propagation law gradually changed from directly passing through the coarse aggregate to extending along the bonding surface between the coarse aggregate and the mortar matrix with the elevation of temperature. When designing the material ratio, materials with high-temperature resistance and high tensile strength should be added to strengthen the bond between the mortar and the aggregate and to change the failure mode of the structure to resist the softening effect of temperature.


2000 ◽  
Vol 652 ◽  
Author(s):  
Wei Zhao ◽  
David E. Luzzi

ABSTRACTPolysynthetically-twinned titanium aluminide (PST-TiAl), a fully lamellar γTiAl + α2-Ti3Al dual-phase alloy, is under evaluation for applications in rotary components in aircraft and automobile industries due to its high specific strength, and a high strength-retention capability at elevated-temperatures. However, the low ductility at room- to mid-high temperatures of the material hinders its application. Additions of certain tertiary elements to the binary TiAl system appear to improve the ductility at room- to mid-high temperatures, thus a balance among strength, ductility, and fracture toughness can be expected. In this article, segregation of tertiary elements to the lamellar interfaces is investigated. Single crystals of a TiAl with 0.6% atomic percentage tertiary additions are grown by an optical float-zone method. Segregation to the lamellar interfaces and the microstructure of the interfaces are investigated. Structures of the lamellar interfaces are characterized, and microchemistry and distribution habits of these elements along the γ+α2 lamellar boundaries as well as the γ-γ lamellar and domain boundaries are analyzed.


Author(s):  
Rukmini Srikant Revuru ◽  
Vamsi Krishna Pasam ◽  
Nageswara Rao Posinasetti

Rapid advances in materials science have prompted the development of materials and alloys of enhanced properties like high strength, hardness, etc. Though these alloys are beneficial in their applications, their machining is difficult. For instance, Inconel 718, a nickel-based alloy, is used in several aerospace applications. This alloy can retain its strength at high temperatures up to 750℃. However, machining Inconel is a problem due to its poor machinability. Similarly, titanium alloys are not very hard but react with tools at high temperatures and lead to their premature failure. Carbide inserts are commonly used as cutting tools in the industry. Carbide tools are manufactured using powder metallurgy technique and possess high strength and hardness, even at elevated temperatures. However, these tools are not effective in machining of “difficult-to-machine” materials and have very short life. In light of this, coated tools have evolved. The cutting tools are coated using very hard, non-reacting material and sometimes a solid lubricant. The coatings are made usually by using PVD or CVD techniques. Often, intermediate layers are provided to improve adhesion between the substrate and the actual coating. Coated tools have better resistance to temperatures and hence, better tool life compared to the regular cutting tools. This paper deals with the evolution of the technology of coated tools. Different types of coatings, their advantages/limitations and efficacy of coated tools in machining are reviewed and discussed.


2021 ◽  
Vol 378 ◽  
pp. 647-658
Author(s):  
Xingguo Zhang ◽  
Xiayu Zhang ◽  
Yonggang Li ◽  
Kaili Hu ◽  
Desen Mao ◽  
...  

2013 ◽  
Vol 688 ◽  
pp. 158-164 ◽  
Author(s):  
Jiří Bydžovský ◽  
Ámos Dufka ◽  
Tomáš Melichar

The paper informs on partial results of the research focused on improvement of resistance of cement composites towards actuation of high temperatures invoked by formation of fire. Specifically it is an optimisation of cement composites with use of alternative raw material resources. These cement composites are primarily designed for reconstructions of reinforced concrete constructions. Basic characteristics were tested with specimens exposed in laboratory conditions to an ambient characterized with increased temperatures simulating fire in real construction.


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