scholarly journals PREPARATON OF MASTERBATCH CONTAINING ANTI-OXIDATION ADDITIVE: EFFECT OF CARRIER RESIN RATIO AND ADDITIVES CONTENT

2018 ◽  
Vol 56 (2A) ◽  
pp. 56-62
Author(s):  
Nguyen Van Khoi

In this article, we investigated effect of carrier resin ratio and anti-oxidation additives content on properties of anti-oxidant additives Masterbatchs (MBs). The characteristics were measured by: melt flow index (MFI), morphology (SEM), tensile strength and elongation at break. The results indicated that: increasing LLDPE content in carrier resin led to decreasing mechanical properties, MFI weren’t uniform in MBs. With 80/20 of LDPE/LLDPE ratio, the tensile strength and elongation at break values were highest (21.0 MPa, 680.5 %). In addition, when increased anti-oxidant additives content, mechanical properties increased to upper limit value, then decreased. With 25 wt.% of anti-oxidant additives, the tensile strength and elongation at break values were highest (21.0 MPa, 654.7 %), MFI were uniform in MBs (12 g/10 m). SEM images were evidence of greatly distribution in sample containing 25 wt.% additives. Consequently, the 90/10 of LDPE/LLDPE ratio, 25 wt.% anti-oxidant additives were selected to prepare MBs. 

2005 ◽  
Vol 21 (3) ◽  
pp. 219-230 ◽  
Author(s):  
Arup Choudhury ◽  
Mandira Mukherjee ◽  
Basudam Adhikari

The present investigation deals with the viability of the use of recycled milk pouch material, which is a 50:50 mixture of LDPE and LLDPE, and the scope for improvement of its properties by combining it with virgin LDPE-LLDPE (50/50). Melt flow index (MFI), rheological properties, thermal and mechanical properties of the pure materials and their formulated blends containing recycled milk pouches were studied. The properties of the recycled materials were not as satisfactory as those of the corresponding virgin materials. But a significant improvement in viscosity, crystallinity, tensile strength and elongation at break of the recycled LDPE-LLDPE material was achieved by blending it with the corresponding virgin LDPE-LLDPE blend.


2013 ◽  
Vol 701 ◽  
pp. 42-46 ◽  
Author(s):  
Abd Aziz Noor Zuhaira ◽  
Rahmah Mohamed

This research is to identify the difference in melt flow and mechanical properties in hybrid composites between kenaf and rice husk that each of the filler was compounded with composite material of calcium carbonate (CaCO3) and high density polyethylene (HDPE) in different loading amount. Different filler loading up to 30 parts of kenaf fibers and rice husk particulate were mixed with the fixed 30% amount of CaCO3. Compounded hybrid composite were prepared and tested for melt flow index, tensile and impact strength. Addition of both fillers had decreased melt flow index (MFI). MFI of rice husk/CaCO3 was higher than kenaf/CaCO3 in HDPE composites. Tensile strength, elongation at break and impact properties of both hybrid composites had decreased with increasing filler content. Tensile strength of kenaf/CaCO3 was higher than rice husk/CaCO3 due to intrinsic fiber structure of kenaf which has some reinforcing effect compared to rice husk. While, impact strength of rice husk/CaCO3 was improved with addition of filler but drastically decrease as the rice husk content were increased up to 30% due to high silica content in rice husk. The Youngs Modulus was increased with addition of natural fibers in CaCO3/HDPE composite.


Author(s):  
С. В. Сайтарли ◽  
В. П. Плаван ◽  
Л. С. Дзюбенко ◽  
О. С. Керенівський ◽  
Д. М. Євдокименко

To develop filled polymer compositions based on polypropylene with different contents of calcite concentrate as a filler and the newest polyolefin elastomer as a modifier; to define the influence of the compositions on their rheological and physico-mechanical properties for production injection molded goods. The values of viscosity, melt flow index, tensile strength, elongation, and impact strength and frost resistance of the compositions depending on their composition are determined by standard methods. The influence of calcite concentrate as a filler and polyolefin elastomer as a modifier on the rheological and mechanical properties of compositions has been determined. With an increase in the amount of filler the physical and mechanical properties of the filled compositions are reduce that is offset by introducing the newest polyolefin elastomer as a modifier in amount of 5 wt. %. Addition of 5 wt. % of polyolefin elastomer in the filled composition gives them frost resistance, wherein the impact strength is higher than for compositions without the modifier even after freezing for 30 days at -18°С. It has been determined that adding of the filler does not increase the viscosity of the compositions, which contradicts the traditional behavior of filled systems. The addition of 5 wt. % of polyolefin elastomer to the filled compositions with calcite concentrate up to 20 wt.% does not change the tensile strength of the compositions which is 24 MPa, but increases elongation by 2 times, impact strength by an average of 8,5 % and frost resistance after freezing compositions at -18 °C for 30 days by an average of 12,6 %. The research results of rheological and physic-mechanical properties allow choosing the rational composition to achieve the desired characteristics of the polymer material for production goods by injection molding. Melt flow index of the compositions increases with increasing amount of filler to 50 wt. %. which does not increase the production costs of the injection molding process in comparison with unfilled compositions.


2015 ◽  
Vol 1107 ◽  
pp. 125-130 ◽  
Author(s):  
Muhammad Safwan Hamzah ◽  
M. Mariatti ◽  
M. Kamarol

In this article, we report three nanofillers filled polymer composite systems. Nanofillers composed of alumina, titania and organoclay were embedded separately in 50% polypropylene (PP) and 50% ethylene propylene diene monomer (EPDM) blends. The nanocomposites were prepared using an internal mixer and were molded using a compression mold to form test samples. Effect of filler loading (2, 4, 6, and 8 vol.%) on the tensile properties and melt flow index (MFI) were determined. The mechanical properties of alumina are the highest compared to titania and organoclay. Alumina and organoclay shows an ascending trend in tensile strength with the increase of nanofiller loading. In contrast, the increment of titania filler loading reduces the tensile strength of the nanocomposites. The Young's modulus of the nanocomposites increases with the addition of filler loading. Elongation at break of the nanocomposites shows a descending trend with the addition of filler loading. The addition of 8 vol. % titania and organoclay slightly changes the MFI of the PP/EPDM nanocomposites whereas the addition of 8 vol. % alumina drastically decreased the MFI values. Further addition of nanofillers up to 8 vol. % decreases the MFI values of the PP/EPDM nanocomposites.


2019 ◽  
Vol 394 ◽  
pp. 85-89
Author(s):  
Kęstutis Beleška ◽  
Virgilijus Valeika ◽  
Virginija Jankauskaite ◽  
Violeta Valeikiene

Natural biopolymers were studied for their possible role as biodegradable fillers forlow-density polyethylene (LDPE) films. LDPE/biopolymer blends and films were prepared andcharacterized by the melt flow index (MFI) and tensile test. The addition of biopolymer to LDPEreduced the MFI values, the tensile strength and modulus, whereas the elongation at break increased.Interfacial interaction was better for LDPE/biopolymer blends containing soybean oil. Blendsprepared with oil showed the same behaviour as LDPE/biopolymer blends, indicating thatbiopolymer was the main factor that influenced the properties of blend.


2013 ◽  
Vol 658 ◽  
pp. 19-24
Author(s):  
Chamaiporn Yamoum ◽  
Rathanawan Magaraphan

Polylactide (PLA) was plasticized by two types of plasticizers, glycerol and triacetin. These plasticized PLA were mixed with carboxymethylcellulose (CMC). It was found that with only small amount of CMC, 4.5 wt%, it is effectively to lower glass transition, cold crystallization and melting temperatures of glycerol-plasticized PLA (PLA-g) but not much affected on tensile properties. Moreover, increasing amount of CMC twice could not much affect thermal properties but largely reduced tensile strength, modulus and elongation. The melt flow index of the PLA-g increased largely with the amount of CMC. When 4.5 wt% CMC was added to the glycerol-triacetin plasticized PLA, only glass transition temperature became lower than that of 4.5 wt% CMC filled PLA-g but melting temperature and crystallinity were rather increased with poorer mechanical properties. Increasing amount of CMC tended to enhance melting temperature but still rather poor mechanical properties and high melt flow index. So, the CMC had strong positive effect on melt and negative effect on solid properties of plasticized PLA.


2013 ◽  
Vol 701 ◽  
pp. 202-206
Author(s):  
Ahmad Aroziki Abdul Aziz ◽  
Sakinah Mohd Alauddin ◽  
Ruzitah Mohd Salleh ◽  
Mohammed Iqbal Shueb

Effect of nanoMagnesium Hydroxide (MH) nloading amount to the mechanical and physical properties of Low Density Polyethylene (LDPE)/ Poly (ethylene-co vinyl acetate)(EVA) nanocomposite has been described and investigated in this paper. The tensile strength results show that increased amount of nanofiller will decrease and deteriorate the mechanical properties. The elongation at break decreased continuously with increasing loading of nanofiller. Generally, mechanical properties become poorer as loading amount increase. Melt Flow Index values for physical properties also provide same trend as mechanical properties results. Increase filler amount reduced MFI values whereby increased resistance to the flow.


Molecules ◽  
2020 ◽  
Vol 25 (14) ◽  
pp. 3236
Author(s):  
Peng Yin ◽  
Wen Zhou ◽  
Xin Zhang ◽  
Bin Guo ◽  
Panxin Li

In order to improve the mechanical properties and water resistance of thermoplastic starch (TPS), a novel reinforcement of dialdehyde lignocellulose (DLC) was prepared via the oxidation of lignocellulose (LC) using sodium periodate. Then, the DLC-reinforced TPS composites were prepared by an extrusion and injection process using glycerol as a plasticizer. The DLC and LC were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the effects of DLC content on the properties of the DLC/TPS composites were investigated via the evaluation of SEM images, mechanical properties, thermal stability, and contact angles. XRD showed that the crystallinity of the DLC decreased due to oxidation damage to the LC. SEM showed good dispersion of the DLC in the continuous TPS phase at low amounts of DLC, which related to good mechanical properties. The tensile strength of the DLC/TPS composite reached a maximum at a DLC content of 3 wt.%, while the elongation at break of the DLC/TPS composites increased with increasing DLC content. The DLC/TPS composites had better thermal stability than the neat TPS. As the DLC content increased, the water resistance first increased, then decreased. The highest tensile strength and elongation at break reached 5.26 MPa and 111.25%, respectively, and the highest contact angle was about 90.7°.


Author(s):  
Ibrahim Hamarat ◽  
Emel Kuram ◽  
Babur Ozcelik

In this study, acrylonitrile butadiene styrene polymer was exposed to 12 injection cycles to investigate the influence of recycling number on the mechanical, rheological, and morphological properties. Also, binary and ternary blends including different weight percentages and recycling number of virgin–recycled polymers were prepared. A slight decrement was found in the tensile strength values with recycling number. All blends including recycled polymer (binary or ternary) gave lower tensile strength values with respect to 100% virgin polymer. Strain at break value was decreased after twelve times recycling; however, no clear tendency was observed with the presence of different ratios of virgin polymer to recycled polymer. Impact strength of the polymer decreased with recycling number. There was relatively large drop in the third recycling, from 72 kJ/m2 to 38.5 kJ/m2; however, further recycling induced in a slower drop in the impact strength to 32.5 kJ/m2. All blends including recycled material gave lower impact strength values as compared to 100% virgin polymer. It was observed that the melt flow index values increased with the recycling number, a total of 26.53% after twelve times recycling. All blends containing recycled material showed higher melt flow index values as compared to 100% virgin polymer.


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