scholarly journals THE STUDY ON SOME PARAMETERS AFFECTING THE DEGRADATION OF METHYLENE BLUE IN WATER BY ELECTRO-FENTON USING TI/PBO2 ANODE

2021 ◽  
Vol 59 (5) ◽  
Author(s):  
Son Thanh Le ◽  
Dung Tran Nguyen ◽  
Huong Thu Tran ◽  
Dien Tran Nguyen ◽  
Uyen Phuong Dao

In this work, the combination of two advanced oxidation processes, electro-Fenton (hydroxyl radical ●OH generated by reactions on cathode) and anodic oxidation (●OH produced directly on anode), in the same reactor was studied to evaluate the treatment of methylene blue (MB) dye in aqueous solutions. This electrochemical system was equipped with a commercial carbon felt cathode (9.5cm 12cm), lead dioxide-coated titanium anode (10 12cm), direct current (DC) and continuously aerated. The effects of operating parameters such as pH, applied current (I), catalyst concentration ([Fe2+]) and MB concentration (C0) on MB removal efficiency were investigated through monitoring MB concentration at different times by spectrophotometric method. An optimal process was achieved at the condition of [Fe2+] = 0.1 mM; pH 3.0; [Na2SO4] = 0.05 M; i = 2.5 mA.cm-2 and after 60 minutes of electrolysis, 92.19% of MB was removed which was far higher than the figure obtained by using individually electro-Fenton (73.77%) or anodic oxidation (58.04%). These experimental results have demonstrated that the combination of electro-Fenton and anodic oxidation using Ti/PbO2 electrode is a prospective method for destruction of persistent dyes.

2009 ◽  
Vol 24 (4) ◽  
pp. 680-684 ◽  
Author(s):  
Yi CHEN ◽  
Li-Yi SHI ◽  
Shuai YUAN ◽  
Jun WU ◽  
Mei-Hong ZHANG ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 9911-9920
Author(s):  
Gabriele Capilli ◽  
Damian Rodríguez Sartori ◽  
Monica C. Gonzalez ◽  
Enzo Laurenti ◽  
Claudio Minero ◽  
...  

Under UV-Vis irradiation, the metallic impurities embedded in non-purified commercial carbon nanotubes generate radicals suitable for advanced oxidation processes. Semiconducting PPY membranes enhance the photo activity of a supported catalyst.


1981 ◽  
Vol 34 (2) ◽  
pp. 247 ◽  
Author(s):  
DB Matthews ◽  
MA Habib ◽  
SPS Badwal

The variation of discharge capacity during charge-discharge cycling of a PbO2 electrode, prepared by pressing PbO2 powder onto a smooth lead disc, in sulfuric acid and acidic ammonium sulfate solutions of various concentrations was investigated by the potentiodynamic technique. The discharge capacity was found to increase with cycle number in 0.05-4.3 H2SO4; this was explained in terms of the increase in porosity of the electrode with cycling. The rate of increase was highest in a 1 mol dm-3 solution. The presence of ammonium sulfate decreased the discharge capacity at all concentrations of sulfuric acid except for the 1 mol dm-3 solution where it caused a small increase in capacity. The morphology of the electrode was studied by scanning electron microscopy and the results are correlated with the discharge capacity. These results indicated that a solution of composition 0.5 mol dm-3 ammonium sulfate and 1.0 mol dm-3 sulfuric acid will produce a greater utilization of positive plate active material (PbO2) during discharge. This result, taken together with the results of earlier studies on lead in acidic sulfate electrolytes, points to the possibility of a Pb/H2SO4,/PbO2 battery for electric-vehicle propulsion.


2018 ◽  
pp. 655 ◽  
Author(s):  
Wei Chien ◽  
Chi-Yu Lin ◽  
Shang-Te Tsai ◽  
Cheng-Fu Yang ◽  
Chiu-Chen Chang ◽  
...  

1936 ◽  
Vol 14b (4) ◽  
pp. 127-137
Author(s):  
L. M. Pidgeon

The production of carbon black in an experimental plant of the channel type is described. Carbon black has been produced from Turner Valley dry gas in yields as high as 1.3 lb. per 1000 cu. ft. The rubber reinforcing properties, methylene blue sorption, and per cent extractable are similar to those of the commercial carbon blacks available at present. The presence of hydrogen sulphide in the gas has been examined, but little effect on yields and properties was noticed with concentrations as high as 1% by volume.


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