Titanium dioxide (TiO2) has widely been applied in various fields of industry and technology. To improve the corrosion resistance of TiO2, many manufacturing processes have been researched. MAO is a new method of the TiO2 manufacturing process, of which titanium dioxide is coated on titanium substrate. According to electrochemistry researches, there is a more superior level for Pulse-MAO than traditional MAO. Parameters of on-time were significant in the Pulse-MAO process. The results show that on-time affects reactant shape, morphologies, thickness of films, and corrosion resistance. When on-time increased, the size of reactants was bigger and the shape of reactants was changed from sphere to lump. Meanwhile, the corrosion resistance and thickness of the film increased.