Herbicidal Ionic Liquids with 2,4-D

Weed Science ◽  
2012 ◽  
Vol 60 (2) ◽  
pp. 189-192 ◽  
Author(s):  
Tadeusz Praczyk ◽  
Przemysław Kardasz ◽  
Ewa Jakubiak ◽  
Anna Syguda ◽  
Katarzyna Materna ◽  
...  

Three herbicidal ionic liquids (HILs)—alkyldi(2-hydroxyethyl)methylammonium (2,4-dichlorophenoxy)acetate, dialkyldimethylammonium (2,4-dichlorophenoxy)acetate, and alkyltrimethylammonium (2,4-dichlorophenoxy)acetate—were synthesized and their activity against broad-leaved weeds was investigated under field conditions. HILs as [cation][2,4-D] used in winter wheat were much more active compared to 2,4-D-dimethylammonium salt and demonstrated efficacy similar to 2,4-D 2-ethylhexyl ester. HILs exhibited desirable surface properties such as low contact angle of droplets and low surface tension. Moreover, the HILs may be safer to operators and neighboring plants due to their nonvolatile nature. HILs at 450 g ha−1 of 2,4-D did not injure wheat.

Author(s):  
Anpalaki J. Ragavan ◽  
Cahit A. Evrensel ◽  
Peter Krumpe

Altered surface and viscoelastic material properties of mucus during respiratory diseases have a strong influence on its clearance by cilia and cough. Combined effects of the surface properties (contact angle and surface tension) and storage modulus with relatively unchanged viscosity on displacement of the simulated mucus aliquot during simulated cough through a model adult human trachea is investigated. For the mucus simulants used in this study contact angle and surface tension increase significantly as storage modulus increase while viscosity remains practically unchanged. Displacement of mucus simulant aliquots increased significantly with increasing storage modulus (and contact angle) at a given cough velocity in the range between 5 meters/second (m/s) and 30 m/s with duration 0.3 s. Results suggest that the interactive effects of elasticity and surface properties may help facilitate mucus displacement at low cough velocities.


Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3542
Author(s):  
Lulu Liang ◽  
Yu Zheng ◽  
Yitian Wu ◽  
Jin Yang ◽  
Jiajie Wang ◽  
...  

The high-efficiency development and utilization of bamboo resources can greatly alleviate the current shortage of wood and promote the neutralization of CO2. However, the wide application of bamboo-derived products is largely limited by their unideal surface properties with adhesive as well as poor gluability. Herein, a facile strategy using the surfactant-induced reconfiguration of urea-formaldehyde (UF) resins was proposed to enhance the interface with bamboo and significantly improve its gluability. Specifically, through the coupling of a variety of surfactants, the viscosity and surface tension of the UF resins were properly regulated. Therefore, the resultant surfactant reconfigured UF resin showed much-improved wettability and spreading performance to the surface of both bamboo green and bamboo yellow. Specifically, the contact angle (CA) values of the bamboo green and bamboo yellow decreased from 79.6° to 30.5° and from 57.5° to 28.2°, respectively, with the corresponding resin spreading area increasing from 0.2 mm2 to 7.6 mm2 and from 0.1 mm2 to 5.6 mm2. Moreover, our reconfigured UF resin can reduce the amount of glue spread applied to bond the laminated commercial bamboo veneer products to 60 g m−2, while the products prepared by the initial UF resin are unable to meet the requirements of the test standard, suggesting that this facile method is an effective way to decrease the application of petroleum-based resins and production costs. More broadly, this surfactant reconfigured strategy can also be performed to regulate the wettability between UF resin and other materials (such as polypropylene board and tinplate), expanding the application fields of UF resin.


1961 ◽  
Vol 14 (3) ◽  
pp. 409 ◽  
Author(s):  
DH Bradhurst ◽  
AS Buchanan

The wetting of uranium dioxide by liquid bismuth has been investigated by means of measurements of surface tension of the liquid and contact angle of the liquid on the solid. Bismuth chloride in low concentration was found to be a very effective surface active agent in improving the wetting of the solid by the metal.


2019 ◽  
Vol 288 ◽  
pp. 110995 ◽  
Author(s):  
D. Blanco ◽  
N. Rivera ◽  
P. Oulego ◽  
M. Díaz ◽  
R. González ◽  
...  

2015 ◽  
Vol 1130 ◽  
pp. 515-518
Author(s):  
Edy Sanwani ◽  
Tri Wahyuningsih ◽  
Siti Khodijah Chaerun

The objective of the present work was to assess the surface properties of silica-cell complexes formed by Bacillus pumilus strain SKC-2 for bioflotation purposes. This bacterial strain was employed in this study because it is a Gram-positive, mixotrophic bacterium whose metal binding capacity extends to many different metals and circumstances as well as a biosurfactant producer. The strain was found to promote the formation of silica-cell complexes due to the generation of surface-active agents (i.e., extracellular polymeric substrances (EPS)) as represented by scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM-EDS) observation. Surface properties of the complexes was assessed by water contact angle and surface tension measurements, demonstrating that bacterial cells reduced the surface tension of the solutions and increased the contact angle of the silica surfaces, representing a larger hydrophobic property. Therefore, the findings of this study provide clear evidence for the potential application of the bacterium Bacillus pumilus strain SKC-2 for silicate bioflotation processes (i.e., as frother and collector).


Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.


2010 ◽  
Vol 158 (12) ◽  
pp. 3539-3545 ◽  
Author(s):  
Zhaozhong Feng ◽  
Jing Pang ◽  
Isamu Nouchi ◽  
Kazuhiko Kobayashi ◽  
Takashi Yamakawa ◽  
...  

2010 ◽  
Vol 42 (3) ◽  
pp. 323-329 ◽  
Author(s):  
Jaroslav Klomfar ◽  
Monika Součková ◽  
Jaroslav Pátek

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