scholarly journals EOR Technologies: Physico-Chemical Aspects

2017 ◽  
Vol 3 (3) ◽  
pp. 179
Author(s):  
L.K. Altunina ◽  
V.A. Kuvshinov

<p>The application of self-regulating oil-displacing systems is considered to be a promising trend in the development of physico-chemical EOR methods. Technologies intended to increase conformance predominate. EOR technologies, where heat energy of the formation is used to generate alkaline buffer systems, CO<sub>2</sub> and gels increasing oil displacement and conformance, have wide potentialities. Such methods have been realized in the technologies developed at the Institute of Petroleum Chemistry SB RAS (IPC). Hydrolysis, hydrolytic polycondensation and coagulation in the system carbamide – aluminum salt – surfactant – water is the physico-chemical base for the technologies involving alkaline buffer systems, CO<sub>2</sub> and inorganic gels. To prepare thermoreversible polymer gels one uses change of phase from solution to gel in the system: cellulose ether with a lower critical dissolution point – water. Presented are the results obtained on the application of physico-chemical EOR methods and technologies developed at IPC in oil fields of Russia. The technologies proved to be economically effective and environmentally safe. The period of payback is 5-12 months.</p>

2021 ◽  
pp. 86-98
Author(s):  
V. Yu. Ogoreltsev ◽  
S. A. Leontiev ◽  
A. S. Drozdov

When developing hard-to-recover reserves of oil fields, methods of enhanced oil recovery, used from chemical ones, are massively used. To establish the actual oil-washing characteristics of surfactant grades accepted for testing in the pore space of oil-containing reservoir rocks, a set of laboratory studies was carried out, including the study of molecular-surface properties upon contact of oil from the BS10 formation of the West Surgutskoye field and model water types with the addition of surfactants of various concentrations, as well as filtration tests of surfactant technology compositions on core models of the VK1 reservoir of the Rogozhnikovskoye oil field. On the basis of the performed laboratory studies of rocks, it has been established that conducting pilot operations with the use of Neonol RHP-20 will lead to higher technological efficiency than from the currently used at the company's fields in the compositions of the technologies of physical and chemical EOR Neonol BS-1 and proposed for application of Neftenol VKS, Aldinol-50 and Betanol.


Author(s):  
S. Goshovskyi ◽  
O. Zurian

The article contains the results of scientific research and design work related to environmentally safe usage of hydropower potential of the small rivers of the Dnieper basin. The innovative design solutions for extraction of low-grade heat energy of water and systems for its transformation into energy convenient for consumption were offered. It was established that use of renewable low-grade energy of soil is widely used in environmentally safe and economically sound power systems. At the same time hydropower potential is not widely used in hydrothermal heat pump systems. It was proved that existing hydrothermal systems are not always adjusted to actual operating conditions and object location. The evidence was provided that the scientific approach to development of appropriate configuration of hydrothermal collector, to methodology of their optimal mounting and to efficiency determination depending on operating conditions is quite topical issue. The scientific novelty of the new process approach is use of special design of water collector that has modular configuration and consists of several functionally related water sondes. The efficiency of hydrothermal system was scientifically proved. The paper describes the results of experimental research of efficiency of hydrothermal heat pump system where the low-grade heat energy of water is used as a renewable primary heating energy source for functioning of the heat pump. The authors have developed experimental hydrothermal and geothermal heat pump systems to conduct the research. Both collector and ground section of the system have mounted sensors of temperature, pressure and coolant flow velocity. The software for archiving and visualization of obtained data was developed. The research procedure was developed. As part of study, observation data were received and performance efficiency of geothermal and hydrothermal systems was calculated. The comparative analysis of energy systems depending on used renewable energy source was carried out. The conclusion was made that use of hydrothermal heat pump systems is environmentally safe. The data obtained as part of study have great scientific and applied significance for engineering of heat pump energy systems using hydropower potential of the small rivers.


2021 ◽  
Author(s):  
Qi Xiong ◽  
Zhenghe Yan ◽  
Li Li ◽  
Yong Yang ◽  
Yahui Wang ◽  
...  

Abstract Under the natural energy development of Marine sandstone oil fields in the east of the South China Sea, the recovery degree of some oil fields has exceeded 65%, and the production capacity is still strong. The high-speed development model does not seem to have an adverse effect on oil recovery. Based on the existing knowledge and technical conditions, it is difficult to analyze and predict the final recovery rate of oil field. The reasonable boundary between the oil rate and recovery is also unclear. In this study, we investigate the correlation between oil rate and recovery rate by experiment and field practice. Based on the microscopic displacement experiment, the variation rules of phase permeability, wettability, residual oil, displacement efficiency and sweep volume of different displacement multiples are studied. The variation law of oil rate and recovery under different fluidity and well control conditions is studied by mathematical statistics according to the production dynamic data. Thus, the influencing factors and percolation mechanism of the optimal recovery under high multiples water flooding are clarified, and the relationship between the reasonable oil rate and optimal recovery under different reservoir conditions is formed. Micro experiments show that high multiples water flooding can improve the reservoir property, change wettability of rocks, reduce the residual oil saturation, improve oil displacement efficiency and the final oil displacement efficiency can reach 80%. Statistical research shows that when the oil recovery rate is less than 10%, the recovery rate increases with the increase of oil rate. For bottom water reservoirs, the recovery rate is recommended to be no more than 8%. The paper innovatively studies the correlation between the reasonable oil rate and optimal recovery in Marine sandstone oilfield from microscopic experimental analysis and macroscopic statistical research. The research results effectively guide the oil field production practice of more than 200 Wells in more than 20 oil fields in the eastern South China Sea in 2019, with a cumulative oil increase of more than 5 million barrels. And it has important guiding significance to the efficient and economical development of Marine sandstone oilfield.


2021 ◽  
Vol 1 ◽  
Author(s):  
Giulia Bondi ◽  
Owen Fenton ◽  
Parikshit Sawdekar ◽  
Hilda Keane ◽  
David P. Wall

Strategies for the use of amendments on agricultural soils are needed to help build resilience against potential soil threats. Gypsum is commonly applied to improve soil quality and nutrient supply. However, the sustainability and environmental safety of some gypsum sources is uncertain. This study aims to i. characterize a new by-product, lacto-gypsum, derived from a dairy whey side stream over a 1 year pilot production cycle and ii. assess the temporal variability of the raw form of lacto-gypsum and the stability of its physico-chemical and compositional properties when stored under three potential storage regimes. Results showed that lacto-gypsum compares favorably with conventional equivalents in terms of nutrient and trace element concentrations and represents an environmentally safe material free of contaminants. Storage form did not affect its main physico-chemical characteristics over time and the raw lacto-gypsum remained stable up to 20 days when stored at 4°C. In contrast to conventional gypsum, the lacto-gypsum had very low pH. In general this new lacto-gypsum shows potential as a suitable product for use as a soil amendment or as an acidification agent for animal slurry to reduce ammonia gas emissions during storage. However, further evaluation of this by-product in real life scenarios is required.


2016 ◽  
Vol 10 (1) ◽  
pp. 173-183 ◽  
Author(s):  
Elisabetta Loffredo ◽  
Andreina Traversa

In the last decades an increasing number of natural and synthetic compounds have been recognized as endocrine disruptors (EDs) because of their hormone-like activity and capacity to alter the normal hormonal functions of animals and humans. Among EDs, there are phenolic compounds widely present in terrestrial and aquatic systems, such as bisphenol A, 4-nonylphenol (NP), 4-tert-octylphenol, estrone, ethynilestradiol and so on. Estrogenic effects of these molecules have been ascertained on mollusks, crustaceans, fishes, amphibians and mammals starting from concentrations of 1 μgL−1. Thus, the removal of EDs from polluted media is a priority goal in order to avoid risks for the ecosystem health. Nowadays, several physico-chemical methods are mainly used for the removal of EDs from liquid and solid matrices. Nevertheless, these methods are expensive, difficult to apply and may produce a negative impact on the environment. Recently, most of studies on soil and water remediation from EDs address more sustainable techniques using bacteria, fungi, microbial enzymes and plants. Phytoremediation uses photoautotrophic organisms to uptake, transform, volatilize or stabilize pollutants present in waters, sediments, soils and atmosphere. As this technology is solar driven and exploits natural sources, it is consequently environmentally safe and cost-effective. A fundamental role in the phytoremediation process is played by natural organic molecules, mainly dissolved organic matter and humic substances. These compounds are ubiquitous in all terrestrial and aquatic environments and they interact at various extent with all contaminants deriving from agricultural, industrial and urban activities. Natural organic matter has a relevant biological activity and may also regulate the decontamination capacity of plants and other organisms, such as algae and fungi. In this review, some results of phytodecontamination studies conducted using herbaceous plant species which are presented and discussed. Further, the modulation role of natural organic matter on the phytodecontamination process is highlighted.


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