Microwave sample preparation of chrome for determination of contaminants by method of IСP-MS

2015 ◽  
Vol 0 (11) ◽  
pp. 12-12
Author(s):  
A.V. Alekseyev ◽  
◽  
P.V. Yakimovich ◽  
Keyword(s):  
Sample Preparation ◽  
Microwave Sample Preparation

Controlled-Potential Coulometric Determination of Iridium in Hexanitroiridate(III) with Microwave Sample Preparation

2004 ◽  
Vol 59 (11) ◽  
pp. 1097-1101
Author(s):  
N. A. Ezerskaya ◽  
E. S. Toropchenova ◽  
V. B. Kaprielov ◽  
I. N. Kiseleva ◽  
S. F. Belov
Keyword(s):  
Sample Preparation ◽  
Coulometric Determination ◽  
Microwave Sample Preparation ◽  
Controlled Potential

IMPROVEMENT OF SAMPLE PREPARATION IN ICP-AES ANALYSIS OF FERROALLOYS

2019 ◽  
Vol 85 (5) ◽  
pp. 11-17
Author(s):  
I. I. Chernikova ◽  
K. Y. Tumneva ◽  
T. Y. Bakaldina ◽  
T. N. Ermolaeva
Keyword(s):  
Sample Preparation ◽  
Internal Standard ◽  
Analytical Signal ◽  
Precise Determination ◽  
Standard Samples ◽  
Microwave Sample Preparation ◽  
Wide Range ◽  
Significant Difference ◽  
Temperature Time

A set of ICP-AES techniques has been developed for determination of rated elements: Ti, Si, R Al, Cu, Mo, V, Sn, and Zr in ferrotitanium; Ni, Fe, Cu, Co, and As in ferronickel; Si, Cr, and P in ferrochrome silicon; Zr, Si, Al, R and Cu in zirconium ferrosilicon; Mn, Si, and P in manganese ferrosilicon. Combination of the multi-element ICP-AES method which allows precise determination of the elements in ferroalloys in a wide range of concentrations and microwave sample preparation in closed autoclaves which excludes the loss of the components to be determined provides the rapidity of the analysis procedure. The composition of solutions for opening samples of ferroalloys and temperature-time modes of microwave sample preparation in an autoclave are substantiated. Conditions for ICP-AES determination of the rated elements in ferroalloys are studied. Analytical lines of the elements to be determined free from significant spectral overlaps are chosen. The dilution rates of the solutions are determined. The method of internal standard was used to improve the reproducibility of the analytical signal for Ti determination in ferrotitanium, Si and Cr in ferrochrome silicon, as well as all rated elements in manganese ferrosilicon and ferronickel. The spectrometer was calibrated using model solutions and solutions of standard samples added with the certified solutions of the elements to be determined. To determine Ti, Si, FJ Al, Cu, У and Zr in ferrotitanium; Ni, Fe, Cu, and Co in ferronickel; Si, Cr, and P in ferrochrome silicon; Zr, Si, Al, P, and Cu in zirconium ferrosilicon; Si and P in manganese ferrosilicon a multidimensional graduation by two analytical lines was used. The correctness of the determination was evaluated in analysis of standard samples of ferroalloys and comparative analysis of the obtained results with the data of standard methods: comparison of the variances according to the Fisher criterion did not reveal any significant difference between them, whereas the use of the modified Student test showed the absence of the systematic error.

Recent Trends in the Development of Green Microextraction Techniques for the Determination of Hazardous Organic Compounds in Wine

2019 ◽  
Vol 15 (7) ◽  
pp. 788-800 ◽  
Author(s):  
Natasa P. Kalogiouri ◽  
Victoria F. Samanidou
Keyword(s):  
Sample Preparation ◽  
Solid Phase Extraction ◽  
Organic Compounds ◽  
Method Development ◽  
Solid Phase ◽  
Stir Bar Sorptive Extraction ◽  
Phase Extraction ◽  
Microextraction Techniques ◽  
Hazardous Organic Compounds

Background:The sample preparation is the most crucial step in the analytical method development. Taking this into account, it is easily understood why the domain of sample preparation prior to detection is rapidly developing. Following the modern trends towards the automation, miniaturization, simplification and minimization of organic solvents and sample volumes, green microextraction techniques witness rapid growth in the field of food quality and safety. In a globalized market, it is essential to face the consumers need and develop analytical methods that guarantee the quality of food products and beverages. The strive for the accurate determination of organic hazards in a famous and appreciated alcoholic beverage like wine has necessitated the development of microextraction techniques.Objective:The objective of this review is to summarize all the recent microextraction methodologies, including solid phase extraction (SPE), solid phase microextraction (SPME), liquid-phase microextraction (LPME), dispersive liquid-liquid microextraction (DLLME), stir bar sorptive extraction (SBSE), matrix solid-phase dispersion (MSPD), single-drop microextraction (SDME) and dispersive solid phase extraction (DSPE) that were developed for the determination of hazardous organic compounds (pesticides, mycotoxins, colorants, biogenic amines, off-flavors) in wine. The analytical performance of the techniques is evaluated and their advantages and limitations are discussed.Conclusion:An extensive investigation of these techniques remains vital through the development of novel strategies and the implication of new materials that could upgrade the selectivity for the extraction of target analytes.

scholarly journals A Toolbox for the Determination of Nitroaromatic Explosives in Marine Water, Sediment, and Biota Samples on Femtogram Levels by GC-MS/MS

Toxics ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 60
Author(s):  
Tobias Hartwig Bünning ◽  
Jennifer Susanne Strehse ◽  
Ann Christin Hollmann ◽  
Tom Bötticher ◽  
Edmund Maser
Keyword(s):  
Sample Preparation ◽  
Freeze Drying ◽  
Solid Phase ◽  
Phase Extraction ◽  
Direct Extraction ◽  
Time Saving ◽  
Marine Samples ◽  
Volume Method ◽  
Biota Samples

To determine the amount of the explosives 1,3-dinitrobenzene, 2,4-dinitrotoluene, 2,4,6-trinitrotoluene, and its metabolites in marine samples, a toolbox of methods was developed to enhance sample preparation and analysis of various types of marine samples, such as water, sediment, and different kinds of biota. To achieve this, established methods were adapted, improved, and combined. As a result, if explosive concentrations in sediment or mussel samples are greater than 10 ng per g, direct extraction allows for time-saving sample preparation; if concentrations are below 10 ng per g, techniques such as freeze-drying, ultrasonic, and solid-phase extraction can help to detect even picogram amounts. Two different GC-MS/MS methods were developed to enable the detection of these explosives in femtogram per microliter. With a splitless injector, limits of detection (LODs) between 77 and 333 fg/µL could be achieved in only 6.25 min. With the 5 µL programmable temperature vaporization—large volume method (PTV-LVI), LODs between 8 and 47 fg/µL could be achieved in less than 7 min. The detection limits achieved by these methods are among the lowest published to date. Their reliability has been tested and confirmed by measuring large and diverse sample sets.

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