scholarly journals Evaluación de irreversibilidades en un sistema de refrigeración por absorción amoniaco-agua empleando tres modelos matemáticos diferentes para calcular las propiedades termodinámicas

2018 ◽  
Vol 27 (47) ◽  
Author(s):  
Iván Vera-Romero ◽  
Christopher Lionel Heard-Wade
Keyword(s):  
Individual Component ◽  
Operating Conditions ◽  
Coefficient Of Performance ◽  
Second Law ◽  
Base Case ◽  
Water Mixture ◽  
Absorption Refrigeration ◽  
Second Law Analysis ◽  
Exergy Analyses

Second Law or Exergy Analyses of Absorption Refrigeration Systems (ARS) are very important for optimisations based on available work; these analyses are derived from the operating conditions and property calculations. There are several methods available for calculating the thermodynamic properties used in modelling these systems. A thermodynamic study on an ARS with the ammonia-water mixture (base case) was carried out with the objective of analysing the sensitivity of the overall and individual component irreversibility to the thermodynamic property. To this end, three existing methods were used: (M1), a model proposed by Ibrahim and Klein (1993) and used in the Engineering Equation Solver (EES) commercial software; (M2), a model proposed by Tillner-Roth and Friend (1998) and embodied in REFPROP v.8.0 developed by the National Institute of Standards and Technology (NIST); and (M3), a method proposed by Xu and Goswami (1999) that was programmed for this analysis. The obtained differences in the properties and the first law performance of the ARS are insignificant in the determination of the coefficient of performance (COP) (base case: 0.595, M1: 0.596, M2: 0.594, M3: 0.599). For the second law analysis, the overall irreversibility was the same (123.339kW) despite the irreversibilities per component had important differences: the solution heat exchanger (M1: 5.783kW, M2: 6.122kW, M3: 8.701kW), the desorber (generator) (M1: 51.302kW, M2: 45.713kW, M3: 49.098kW) and the rectifier (M1: 0.766kW, M2: 3.565kW, M3: 0.427kW). The components that destroy exergy the most are the desorber, the absorber and the condenser.

THERMODYNAMIC ANALYSIS OF SINGLE- AND DOUBLE-EFFECT ABSORPTION REFRIGERATION SYSTEMS FOR COOLING ETHANOL FERMENTATION PROCESS

2014 ◽  
Vol 22 (04) ◽  
pp. 1450020 ◽  
Author(s):  
HUGO VALENÇA DE ARAÚJO ◽  
JOSÉ VICENTE HALLAK D'ANGELO
Keyword(s):  
Thermodynamic Analysis ◽  
Fermentation Process ◽  
Alcoholic Fermentation ◽  
Double Effect ◽  
Operating Conditions ◽  
Coefficient Of Performance ◽  
Second Law ◽  
Base Case ◽  
Absorption Refrigeration ◽  
Single Effect

Alcoholic fermentation is one of the most important stages in industrial ethanol production process, involving a biochemical and exothermic reaction. Sometimes cooling towers are not capable of supplying a cold utility with a temperature low enough to maintain the fermentative medium temperature in a desirable range. Absorption Refrigeration Systems (ARS) appears to be a good alternative to obtain the necessary refrigeration for the fermentation process. The aim of the present paper was to carry out a thermodynamic analysis of ARS, evaluating their performance through the First and Second Laws of Thermodynamics. ARS with different configurations were studied (single-effect and double-effect with series, parallel and reverse parallel flows), all of them operating with water/lithium bromide mixture as working pair, under different operating conditions in order to satisfy the cooling load required by an industrial alcoholic fermentation process. Another objective of this paper was to investigate the risk of LiBr crystallization, which can result in scaling formation, with the aid of the solid–liquid phase equilibrium curve of H 2 O / LiBr mixture. Among the double-effect configurations studied, it was observed that series flow presents the more significant crystallization risk, which represents a limit to improve its First and Second Law performances. It was verified that the Second Law performance for the single-and double-effect ARS analyzed are similar, but their First Law performance are considerably different. This is due to the amount and quality of the heat consumed in the first effect generators of these systems. For a base case studied, First Law performance measured by coefficient of performance (COP) of double-effect ARS is 72% greater than the one for single-effect, while for Second Law performance, measured by exergetic efficiency, an increase of 5% was observed.

Second Law Analysis of Solid Desiccant Rotary Dehumidifiers

1988 ◽  
Vol 110 (1) ◽  
pp. 2-9 ◽  
Author(s):  
E. Van den Bulck ◽  
S. A. Klein ◽  
J. W. Mitchell
Keyword(s):  
Local Maximum ◽  
Operating Conditions ◽  
Second Law ◽  
Transfer Coefficients ◽  
Adiabatic Flow ◽  
Transfer Processes ◽  
Air Stream ◽  
Second Law Analysis ◽  
Pass Through ◽  
Air Streams

This paper presents a second law analysis of solid desiccant rotary dehumidifiers. The equations for entropy generation for adiabatic flow of humid air over a solid desiccant are developed. The generation of entropy during operation of a rotary dehumidifier with infinite transfer coefficients is investigated and the various sources of irreversibility are identified and quantified. As they pass through the dehumidifier, both the process and regeneration air streams acquire nonuniform outlet states, and mixing both of these air streams to deliver homogeneous outlet streams is irreversible. Transfer of mass and energy between the regeneration air stream and the desiccant matrix occurs across finite differences in vapor pressure and temperature and these transfer processes generate entropy. The second law efficiency of the dehumidifier is given as a function of operating conditions and the effect of finite transfer coefficients for an actual dehumidifier is discussed. It is shown that operating the rotary dehumidifier at conditions that minimize regeneration energy also yields a local maximum for the second law efficiency.

Second-Law Analysis on Wavy Plate Fin-and-Tube Heat Exchangers

1998 ◽  
Vol 120 (3) ◽  
pp. 797-800 ◽  
Author(s):  
W. W. Lin ◽  
D. J. Lee
Keyword(s):  
Entropy Generation ◽  
Operating Conditions ◽  
Generation Rate ◽  
Entropy Generation Rate ◽  
Second Law ◽  
Spanwise Direction ◽  
Minimum Entropy ◽  
Tube Heat Exchanger ◽  
Second Law Analysis ◽  
Minimum Entropy Generation

Second-law analysis on the herringbone wavy plate fin-and-tube heat exchanger was conducted on the basis of correlations of Nusselt number and friction factor proposed by Kim et al. (1997), from which the entropy generation rate was evaluated. Optimum Reynolds number and minimum entropy generation rate were found over different operating conditions. At a fixed heat duty, the in-line layout with a large tube spacing along streamwise direction was recommended. Furthermore, within the valid range of Kim et al.’s correlation, effects of the fin spacing and the tube spacing along spanwise direction on the second-law performance are insignificant.

Analysis of Throttle Opening Variation Impact on a Diesel Engine Performance Using Second Law of Thermodynamics

2009 ◽  
Author(s):  
B. B. Sahoo ◽  
U. K. Saha ◽  
N. Sahoo ◽  
P. Prusty
Keyword(s):  
Diesel Engine ◽  
Direct Injection ◽  
Fuel Efficiency ◽  
Engine Performance ◽  
Second Law Of Thermodynamics ◽  
Operating Conditions ◽  
Second Law ◽  
Engine Fuel ◽  
Availability Analysis ◽  
Second Law Analysis

The fuel efficiency of a modern diesel engine has decreased due to the recent revisions to emission standards. For an engine fuel economy, the engine speed is to be optimum for an exact throttle opening (TO) position. This work presents an analysis of throttle opening variation impact on a multi-cylinder, direct injection diesel engine with the aid of Second Law of thermodynamics. For this purpose, the engine is run for different throttle openings with several load and speed variations. At a steady engine loading condition, variation in the throttle openings has resulted in different engine speeds. The Second Law analysis, also called ‘Exergy’ analysis, is performed for these different engine speeds at their throttle positions. The Second Law analysis includes brake work, coolant heat transfer, exhaust losses, exergy efficiency, and airfuel ratio. The availability analysis is performed for 70%, 80%, and 90% loads of engine maximum power condition with 50%, 75%, and 100% TO variations. The data are recorded using a computerized engine test unit. Results indicate that the optimum engine operating conditions for 70%, 80% and 90% engine loads are 2000 rpm at 50% TO, 2300 rpm at 75% TO and 3250 rpm at 100% TO respectively.

Second Law Analysis of a Stirling Cryocooler With Optimal Design of the Regenerator and Losses

2001 ◽  
Author(s):  
E. D. Rogdakis ◽  
N. A. Bormpilas
Keyword(s):  
Gas Flow ◽  
Optimization Technique ◽  
Internal Heat ◽  
Thermodynamic Characteristics ◽  
Coefficient Of Performance ◽  
Solid Matrix ◽  
Second Law ◽  
External Temperature ◽  
Technical Requirements ◽  
Second Law Analysis

Abstract The aim of the research in this paper is a second law analysis of a Stirling cryocooler. A one-dimensional model is proposed for the simulation of the gas flow in the expansion space, the regenerator, the warm-end, the compression space and the compressor. Helium gas is selected as the working medium. An algorithm has been developed considering parametrically the most from the main operational tasks of the thermodynamic cycle. Performance indices such as heat input, efficiency, external dimensions of the engine and technical requirements are taken into account as constraints. Engine operating parameters i.e. speed, external temperature, mean pressure are fixed. The regenerator loss has a critical influence on the cryocooler efficiency and the reduction of this kind of internal irreversibilities is extremely difficult due to the generator is subject to rapidly cycling flows accompanied by steep temperature gradients and large pressure variations. The second flow analysis of the regenerator identifies two principal losses, the irreversible internal heat transfer into the solid matrix and the hydraulic resistance. An optimization technique leads to entropy generation charts, extremely useful for a good design of the regenerator. Finally the main thermodynamic characteristics (net refrigeration, power input and the coefficient of performance) of the cryocooler are given both cases with and without external and internal irreversibilities.

A Parametric Study on a Subcritical CO2/NH3 Cascade Refrigeration System for Low Temperature Applications

2018 ◽  
Vol 140 (9) ◽  
Author(s):  
Baris Yilmaz ◽  
Ebru Mancuhan ◽  
Nasuh Erdonmez
Keyword(s):  
Performance Analysis ◽  
Large Scale ◽  
Operating Conditions ◽  
Coefficient Of Performance ◽  
Optimum Operating ◽  
Second Law Analysis ◽  
The Common ◽  
Cascade Refrigeration System ◽  
Cascade Refrigeration ◽  
Thermo Physical Properties

Adverse effects of synthetic refrigerants on the environment have led to replacing them with natural refrigerants. The common candidates are ammonia, carbon dioxide, and several hydrocarbon compounds and their mixtures. Ammonia has been used mainly in large-scale cooling purposes such as large-scale supermarkets and climatic rooms. However, in such systems, leakage of ammonia may arise severe results on human health and may damage products in the cooled space. Recently, in last decade, a well-known refrigerant, CO2, has gained more attention to be applied in refrigeration systems due to having prominent thermo-physical properties. The performance analysis of a CO2/NH3 cascade (CAS) system has been theoretically examined in the current study. The detailed performance analysis of the system and optimization of the operating parameters have been studied extensively. In addition, the second-law analysis of the system with both cycles has been performed. Optimum operating conditions of the system are also determined and correlations are developed. Finally, the coefficient of performance (COP) correlations developed by several researchers in literature and those of current study are compared against available experimental COP results. The comparisons showed that the proposed correlations can be utilized for the accurate prediction of the COP of a cascade CO2/NH3 system within the studied range of operating conditions.

First and second law analysis of ammonia/salt absorption refrigeration systems

2014 ◽  
Vol 40 ◽  
pp. 111-121 ◽  
Author(s):  
L. Garousi Farshi ◽  
C.A. Infante Ferreira ◽  
S.M.S. Mahmoudi ◽  
M.A. Rosen
Keyword(s):  
Second Law ◽  
Absorption Refrigeration ◽  
Salt Absorption ◽  
Second Law Analysis ◽  
Ammonia Salt

Assessment of the Effectiveness of Gas Path Diagnostic Schemes

2004 ◽  
Vol 128 (1) ◽  
pp. 57-63 ◽  
Author(s):  
K. Mathioudakis ◽  
Ph. Kamboukos
Keyword(s):  
Gas Turbines ◽  
Individual Component ◽  
Uncertainty Propagation ◽  
Data Retrieval ◽  
Operating Conditions ◽  
Small Deviations ◽  
Component Identification ◽  
Operating Points ◽  
Selection Of

A variety of methods can be used for the diagnosis of faults in gas path components of gas turbines. Problems that are common for diagnostic method implementation are the choice of measured quantities, choice of health parameters, and choice of operating conditions for data retrieval. The present paper introduces some general principles for evaluation of the effectiveness of different diagnostic schemes. They encompass criteria proposed in past publications, while they offer additional possibilities for assessment of diagnostic effectiveness in various situations. The method is based on the evaluation of the behavior of linear systems, which are a good approximation of the nonlinear ones for small deviations and employs the concept of system condition number to formulate criteria. The determination of limits for this number for establishing system condition criteria and quantification of observability is examined, on the basis of uncertainty propagation. Sample problems evaluated are: maximizing effectiveness of individual component identification from a multiplicity of available measurements, selection of individual operating points for multipoint applications.

Second Law Analysis of Condensing Steam Flows

2018 ◽  
Author(s):  
Marius Grübel ◽  
Markus Schatz ◽  
Damian M. Vogt
Keyword(s):  
Entropy Production ◽  
Turbulent Flows ◽  
Operating Conditions ◽  
Second Law ◽  
Test Case ◽  
Relaxation Processes ◽  
Minor Importance ◽  
Two Phase ◽  
Second Law Analysis ◽  
Aerodynamic Losses

A numerical second law analysis is performed to determine the entropy production due to irreversibilities in condensing steam flows. In the present work the classical approach to calculate entropy production rates in turbulent flows based on velocity and temperature gradients is extended to two-phase condensing flows modeled within an Eulerian-Eulerian framework. This requires some modifications of the general approach and the inclusion of additional models to account for thermodynamic and kinematic relaxation processes. With this approach, the entropy production within each mesh element is obtained. In addition to the quantification of thermodynamic and kinematic wetness losses, a breakdown of aerodynamic losses is possible to allow for a detailed loss analysis. The aerodynamic losses are classified into wake mixing, boundary layer and shock losses. The application of the method is demonstrated by means of the flow through a well known steam turbine cascade test case. Predicted variations of loss coefficients for different operating conditions can be confirmed by experimental observations. For the investigated test cases, the thermodynamic relaxation contributes the most to the total losses and the losses due to droplet inertia are only of minor importance. The variation of the predicted aerodynamic losses for different operating conditions is as expected and demonstrates the suitability of the approach.

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