Evaluation of Selected Physico-Chemical Properties and Anti-Trypsin Activity of Fluted Pumpkin Telfairia Occidentalis Hooker (Cucurbitaceae: Cucurbitales) Seed and Seed Oil

The physico-chemical properties of the extracted oil were studied by the conventional methods. It was observed that Siyal Kanta grown under the soil and climatic condition of Bangladesh contains about 35% of pale yellow coloured oil. The total lipids were fractionated into three major lipid groups, neutral lipids, glycolipid and phospholipids by silicic acid column chromatography. Among the lipids, the neutral lipids were varied from 92.1-92.3%, glycolipid 5.5-5.8% and phospholipid 1.5-1.7% of the total oil of the lipid applied. The oil was also fractionated into mono-, di- and triglyceride by silicic acid column chromatography. The triglycerides were varied from 90.1-90.3%, diglycerides from 2.3-2.8% and monoglycerides from 1.5-1.8%. The saturated and unsaturated fatty acids present in the oil were separated and found to be 14.2-14.5% and 84.2-84.8% respectively depending on the areas in which the plant grows. The fatty acid compositions of the oil were analyzed by Gas Liquid Chromatography (GLC). The major fatty acids found in the oil were oleic acid (23%), linoleic acid (58%), palmetic acid (7%) and ricinoleic acid (10%). Key words: Siyal kanta seed oil; Glyceride; Lipid; Fatty acid. DOI: http://dx.doi.org/10.3329/bjsir.v46i4.9607 BJSIR 2011; 46(4): 561-564

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Loss of seed viability in onion (Allium cepa L.) in relation to degradation of lipids during storage

Journal of Applied and Natural Science ◽

10.31018/jans.v12i4.2431 ◽

2020 ◽

Vol 12 (4) ◽

pp. 635-640

Author(s):

Vishwanath Rohidas Yalamalle ◽

Nilesh Nivrutt Gaikwad ◽

Dinesh Manohar Ithape ◽

Ashok Kumar ◽

Kalyani Gorrepati ◽

...

Keyword(s):

Allium Cepa ◽

Oil Content ◽

Seed Oil ◽

Membrane Integrity ◽

Seed Viability ◽

Chemical Properties ◽

Ambient Storage ◽

Physico Chemical ◽

Allium Cepa L ◽

One Year

Onion seeds have one of the lowest longevity among the cultivated crops as it loses viability within a year. The unmarketable seeds have no reported food value or feed value. Onion seeds contain considerable oil content which has potential industrial utility. The present study reports the changes in the quality of seed oil extracted from seeds stored for one year (2019-2020), after which the seeds were unmarketable due to low germination. The physico-chemical properties of seed oil were studied in four onion (Allium cepa L.) varieties (Bhima Safed, Bhima Super, Bhima Dark Red and Bhima Shakti) by standard analytical test. The per cent oil content varied from 12.94% - 16.02% and storage resulted in 0.64% loss in seed oil content. The mean seed germination in freshly harvested seeds was 80.50%, which declined to 52.33% after one year of ambient storage. The electrical conductivity, which measures the membrane integrity increased by 108.60% in one-year-old seeds. The physico-chemical properties of the seed oil deteriorated with the age of the seed. In comparison to the control, the acid values and peroxide values of the seed oil increased by 51.11% and 12.90% respectively, while saponification value decreased by 36.18%. Among the varieties, Bhima Dark Red had the highest degradation in the seed storability and vigour, which also had the highest deterioration in the lipid quality. The present study reports for the first time the degradation of seed lipids during ageing in onion which might be contributing to the poor storability of onion seeds.

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ONE-POT-TWO-STEP SYNTHESIS OF BIOLUBRICANT BASE STOCK FROM RUBBER SEED OIL

Journal of Chemical Society of Nigeria ◽

10.46602/jcsn.v45i5.533 ◽

2020 ◽

Vol 45 (5) ◽

Author(s):

G.O . Madojemu ◽

E.A. Elimian ◽

M.C. Ejimadu ◽

C.O. Okieimen ◽

F.E. Okieimen

Keyword(s):

Hydrogen Peroxide ◽

Acetic Acid ◽

Response Surface ◽

Seed Oil ◽

Chemical Properties ◽

Base Stock ◽

One Pot ◽

Rubber Seed Oil ◽

Rubber Seed ◽

Physico Chemical

Biolubricant base stock was synthesized in this work from rubber seed oil in a one-pot-two-step process of epoxidation and hydroxylation. Rubber seed oil was extracted using a Soxhlet apparatus. The in situ epoxidation of the rubber seed oil with peracid (hydrogen peroxide and acetic acid) was analysed and optimized considering three process variables with their range of values given as temperature of 35-50 , time of 60-180 mins and mole ratio of hydrogen peroxide to acetic acid of 1:0.25-1:1 by applying the central composite design of response surface methodology. The ring opening reaction (hydroxylation) of the epoxide to polyhydroxylated oil (lubricant basestock) with ethanol was carried out using the optimum conditions obtained from the epoxidation process. The rubber seed oil, epoxide and lubricant basestock were characterized in terms of physico-chemical properties using standard methods and in terms of functional groups using Fourier Transform Infrared (FTIR) spectroscopy. Maximum epoxide content of 4.85% and maximum conversion of 71% of rubber seed oil to epoxide was achieved at a temperature of 50􀀀 , reaction time of 180 mins and 1: 0.39 mol/mol of hydrogen peroxide to acetic acid. The predicted values of the epoxidation process reasonably agreed with the experimental ones and model R-squared value of about 95% showed that response surface method can reasonably predict the epoxidation process using a quadratic polynomial model. There was 75% conversion of the epoxide to polyhydroxylated oil (biolubricant basestock), which represents a very high yield. The formation of epoxides and polyhydroxylated oil lead to modification (improvement) in the properties of rubber seed oil as confirmed by the physico-chemical properties and FTIR spectra analysis of the oil, epoxide and lubricant basestock. The study showed that chemical derivatives of rubber seed oils are an attractive, renewable, and ecofriendly alternative to mineral oils for lubricant formulations.

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